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Kinetic and ultraviolet spectroscopic studies of active-site mutants of .DELTA.5-3-ketosteroid isomerase

Athan Kuliopulos、Albert S. Mildvan、David Shortle 等 4 位作者1989-01-10Biochemistry

delta 5-3-Ketosteroid isomerase (EC 5.3.3.1) of Pseudomonas testosteroni promotes the highly efficient isomerization of delta 5-3-ketosteroids to delta 4-3-ketosteroids by means of a direct and stereospecific transfer of the 4 beta-proton to the 6 beta-position, via an enolic intermediate. An acidic residue responsibl…

Enzyme Structure and FunctionChemical Reaction MechanismsFree Radicals and Antioxidants

Synthesis, photochemistry, and biological activity of a caged photolabile acetylcholine receptor ligand

Tracy Milburn、Norio Matsubara、Andrew P. Billington 等 9 位作者1989-01-10Biochemistry

A biologically inert photolabile precursor of carbamoylcholine has been synthesized; it is photolyzed to carbamoylcholine, a well-characterized acetylcholine analogue, with a half-time of 40 microseconds at pH 7.0 and a quantum yield of 0.8. The compound, N-(alpha-carboxy-2-nitrobenzyl)carbamoylcholine, was synthesize…

Chemical Synthesis and AnalysisClick Chemistry and ApplicationsPhotochromic and Fluorescence Chemistry

LEED intensity analysis of the clean W(100) c(2 2) surface reconstruction

H. Landskron、N. Bickel、K. Heinz 等 5 位作者1989-01-09Journal of Physics Condensed Matter

A LEED structure analysis is performed for the W(100) c(2*2) surface reconstruction. Models with pure vertical displacements of the surface atoms can be clearly ruled out while others with predominant lateral displacements in the (11) and (01) directions result in a very good agreement with the experimental curves. Ho…

Metal and Thin Film MechanicsFusion materials and technologiesElectron and X-Ray Spectroscopy Techniques

Correlation of the optical gaps and Raman spectra of hydrogenated amorphous carbon films

M. A. Tamor、J. A. Haire、C. H. Wu 等 4 位作者1989-01-09Applied Physics Letters

The Raman and infrared absorption spectra, optical gaps, and electron spin densities of amorphous carbon films deposited from hydrocarbon plasmas have been systematically studied as a function of deposition conditions and Raman probe wavelength. Although all other probes are consistent with a monotonic increase in int…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

The brittle-ductile transition in silicon. II. Interpretation

P. B. Hirsch、Steve Roberts、Jonathan Samuels1989-01-09Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract A dynamic crack tip shielding model has been developed to describe the brittle-ductile transition (BDT) of precracked crystals in constant strain-rate tests. Dislocations are emitted from a discrete number of sources at or near the crack tip. At the BDT the dislocations are emitted and move sufficiently rapid…

Microstructure and mechanical propertiesSilicon and Solar Cell TechnologiesHigh-Velocity Impact and Material Behavior

Addition polyimides. II. Synthesis and characterization of bisitaconimide prepolymers

K. N. Ninan、Rene George、K. Krishnan 等 4 位作者1989-01-05Journal of Applied Polymer Science

Abstract N , N ′‐bis(3,3′‐itaconimidophenyl) sulfone has been synthesized by reacting itaconic anhydride with 3,3′‐diamino diphenyl sulfone. The bisitaconimides and the intermediates were characterized by chemical analysis, IR, NMR, TG, and GPC. The degree of polymerization (DP) of the prepolymers of the bisitaconimid…

Inorganic and Organometallic ChemistrySynthesis and properties of polymersThermal and Kinetic Analysis

Characterization of poly(3,3‐bisethoxymethyl oxetane) and poly(3,3‐bisazidomethyl oxetane) and their block copolymers

Elizabeth Murphy、T. Ntozakhe、Charles J. Murphy 等 6 位作者1989-01-05Journal of Applied Polymer Science

Abstract The homopolymers, poly(3,3‐bisethoxymethyl oxetane) (polyBEMO), poly(3,3‐bisazidomethyl oxetane) (polyBAMO), and triblock copolymers based on these homopolymers and a statistical copolymer center block composed of BAMO and 3‐azidomethyl‐3‐methyl oxetane AMMO were synthesized and characterized by differential…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesRecycling and Waste Management Techniques

Immobilization of poly(ethylene oxide) on poly(ethylene terephthalate) using a plasma polymerization process

Wayne R. Gombotz、W. Guanghui、Amnon Hoffman1989-01-05Journal of Applied Polymer Science

Abstract Poly(ethylene oxide) (PEO) has been covalently immobilized on poly(ethylene terephthalate) (PET) films using a radio frequency glow discharge polymer deposition process, followed by chemical coupling. Amino or hydroxyl groups were introduced onto the surface of the PET by exposing the films to allylamine and…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrohydrodynamics and Fluid Dynamics

Shear breakage of nylon membrane microcapsules in a turbine reactor

Denis Poncelet、Ronald J. Neufeld1989-01-05Biotechnology and Bioengineering

The breakage of nylon membrane microcapsules is proposed as a new method to study and quantify shear effects in biological systems. A critique of this method shows that a narrower particle size distribution may be an important improvement in the breakage study as well as breakage control in many bioreactor and biotech…

Membrane Separation TechnologiesProteins in Food SystemsPickering emulsions and particle stabilization

Thermal degradation of cellulose‐containing composites during processing

S. Sapieha、Jessica Pupo、H. P. Schreiber1989-01-05Journal of Applied Polymer Science

Abstract The strength properties of composites made of untreated cellulose fibers and linear low density polyethylene were investigated as a function of processing parameters. Studies have shown that the strength properties of composites increase with processing time and temperature. The increase in strength is accomp…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesMaterial Properties and Applications

Elastic Anomaly and Phase Transition of BaTiO3

Takeo Ishidate、S. Sasaki1989-01-02Physical Review Letters

The acoustic-phonon velocities of a single crystal of BaTi${\mathrm{O}}_{3}$ have been measured as a function of pressure up to 8 GPa, including the transition pressure ${p}_{c}=2.35$ GPa, by means of Brillouin scattering technique. Only one elastic eigenmode shows an anomalous decrease on approaching ${p}_{c}$ and th…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMechanical and Optical Resonators

Line Narrowing in Photoemission by Coincidence Spectroscopy

E. Jensen、R. A. Bartynski、Steven L. Hulbert 等 5 位作者1989-01-02Physical Review Letters

We present photoemission spectra from the $3p$ level of Cu(100) obtained in coincidence with the ${M}_{3}\mathrm{VV}$ Auger line. The $3p$ level is narrowed from its 2.2-eV core-lifetime-broadened width to 1.0 eV, representing the intrinsic width of the $^{1}G$ Auger final state. The core line changes its energy withi…

Advanced Chemical Physics StudiesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Instability in a Sand Heap

P. Évesque、Jean Rajchenbach1989-01-02Physical Review Letters

When a bead heap is submitted to low-frequency ($\frac{\ensuremath{\omega}}{2\ensuremath{\pi}}=10\ensuremath{-}1000$ Hz) vertical vibrations at a large enough amplitude $a$, its horizontal free surface becomes unstable and a stationary state is reached. This one is characterized firstly by a free surface which is incl…

Granular flow and fluidized bedsFluid Dynamics and Heat TransferPickering emulsions and particle stabilization

A Comparison between Industrial and Laboratory Beating with Regard to Fibre Development

Ulla-Britt Mohlin、Cecilia Alfredsson、Ulla Jansson1989-01-01OpenAlex

The effect of industrial beating on tensile strength properties has been compared with laboratory beating and the differences observed have been explained in terms of fibre properties. Tensile strength development is less pronounced for industrial beating than for laboratory PFI-mill beating. Beating in the laboratory…

Advanced Cellulose Research StudiesFiber-reinforced polymer compositesMaterial Properties and Processing

Nonlinear optical studies of semiorganic crystals

Tallis Y. Chang、M. D. Ewbank、R. A. Vazquez 等 5 位作者1989-01-01Annual Meeting Optical Society of America

We invoke the term semiorganic to describe a new class of nonlinear optical compounds composed of part organic and part inorganic constituents. The recently reported crystal 1-arginine phosphate (LAP) is one such material where organic 1-arginine molecules form cations and crystallize with inorganic phosphate anions.…

Nonlinear Optical Materials ResearchPhotorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallography

Radiological accident of cesium-137 in Brazil. Activities of surveillance and decontamination.

Toshiyuki Nakajima1989-01-01Journal of the Atomic Energy Society of Japan / Atomic Energy Society of Japan

In 1987, a serious radiological accident occurred in Goiania, Brazil. Four inhabitants died and about 250 persons were internally or externally contaminted with 137Cs released from a removed and then broken source vessel. In this report, outline of the accident and, activities on surveillance of contamination and work…

Radioactive contamination and transferGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Application of one-sided welding to field girth joint of large scale penstock

Ryo Shimoda、Toshihiko Matsuura、Yukiomi Nishigami 等 4 位作者1989-01-01Welding International

(1989). Application of one-sided welding to field girth joint of large scale penstock. Welding International: Vol. 3, No. 12, pp. 1046-1050.

Metal Forming Simulation TechniquesMetal Alloys Wear and PropertiesMechanical and Thermal Properties Analysis

Deuterium NMR and Water Adsorption Studies of the Effect of Beating on the Water-cellulose Interaction

Li Tie-Qiang、Ulf Henriksson、Jan Christer Eriksson 等 4 位作者1989-01-01OpenAlex

The interaction between water and cellulose has been studied by deuterium NMR and water sorption isotherm measurements for a bleached kraft pulp and an unbleached liner board pulp beaten to various degrees. Measurements of 2H quadrupole splittings, spin lattice relaxation rates and half height line width shave been ca…

Advanced Cellulose Research StudiesPower Transformer Diagnostics and InsulationMaterial Properties and Processing

Effect of an air layer on thermal insulation of clothing materials.

Takako Fujimoto、Masako Niwa、N. Seki1989-01-01Sen i Kikai Gakkaishi (Journal of the Textile Machinery Society of Japan)

目的 : 被服の保温性能を決める上で, 被服材料と空気層との相互作用は重要な要素であるので, 多様な被服材料について, 空気中に水平に設置した熱板から被服材料および介在する空気層を通して大気への熱損失を測定し, 自然対流による熱輸送が支配的な極低風速のもとでの, 布および空気層からなる系の伝熱特性を調べた.成果 : 多様な材料のうち, とくに, サージ, モスリン, フラノ, レザーの典型的な4種類の材料については, 測定結果を布/大気, 空気層/布/大気の伝熱モデルと比較することによって, 各構成要素の熱輸送への寄与を分離し, 空気層, 布, 大気, 各々の熱通過率, および, 布のみで被覆した場合の布と熱板との接触抵抗にっいて…

Surface Modification and SuperhydrophobicityTextile materials and evaluationsHeat Transfer Mechanisms