Materials Literature
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The most common partner of the Zn-bound His is the Asp/Glu carboxylate side chain in catalytic Zn sites and the backbone (Bkb) carbonyl group in structural Zn sites. To elucidate the factors governing the selection of the second-shell partner of the Zn-bound His in structural/catalytic Zn sites, systematic studies usi…
Abstract In this work, three alipharomatic polyesters—poly(propylene terephthalate) (PPT), poly(propylene isophthalate) (PPI), and poly(propylene naphthalate) (PPN)—were prepared and studied with the aliphatic diol 1,3‐propanediol and the corresponding aromatic diacids. Their synthesis was performed by the two‐stage m…
Laser evaporation of MoS 2 nanoflakes gives negatively charged magic number clusters of compositions Mo 13 S 25 and Mo 13 S 28, which are shown to have closed-cage structures. The clusters are stable and do not show fragmentation in the post-source decay analysis even at the highest laser powers. Computations suggest…
Abstract Defatted soy flour (DSF) is an abundant renewable commodity and is more economically favorable then soy protein isolate or soy protein concentrate. DSF contains soy protein, soy carbohydrate, and soy whey. The aqueous dispersion of DSF was blended with styrene‐butadiene latex to form elastomer composites. The…
Abstract The catalytic oxidation of phenol with hydrogen peroxide using a synthetic copper(II)–Schiff base complex as catalyst has been investigated in phosphate buffer at pH 7 and 25 °C. In order to further investigate the reaction pathway, the catalytic oxidation of hydroquinone, p ‐benzoquinone and catechol were al…
Polyaniline nanofibers with ramose structues have been synthesized through a templateless and surfactantless method. The diameters of polyanilinie nanofibers decrease with decreasing the concentrations of p-aminobenzenesulfonic acid. These nanofibers can form a porous film associated with the open nanostructures, whic…
The internal configurational entropy of point defect clusters in crystalline silicon is studied in detail by analyzing their potential energy landscapes. Both on-lattice and off-lattice calculation approaches are employed to demonstrate the importance of off-lattice configurational states that arise due to a large num…
Magnetic properties of Mn-doped ZnO (Zn0.98Mn0.02O) bulk materials prepared by the solid-state reaction method were investigated by measuring magnetization as functions of temperature and magnetic field. The special feature of our sample preparation was the low-temperature processing. When high-temperature (T>7…
We have studied the nonlinear optical (NLO) properties of some donor–acceptor molecules with stilbene and azobenzene molecules as backbone. We have used the nitro group as the acceptor and azaphosphane (R3P=N–) as the donor group. To study the effect of variation of NLO properties, we have replaced the substituents (R…
Sulfatases are a family of enzymes essential for the degradation of sulfate esters. Formylglycine is the key catalytic residue in the active site of sulfatases and is generated from a cysteine residue by FGE, the formylglycine-generating enzyme. Inactivity of FGE owing to inherited mutations in the FGE gene results in…
The polarization switching fatigue of ABO3-perovskite ferroelectric thin-film Pb(Zr0.52Ti0.48)O3 (PZT) prepared by metalorganic decomposition (MOD) and Pb0.75La0.25TiO3 (PLT) prepared by pulsed laser deposition (PLD), are investigated. The temperature as a degree of freedom is employed to modulate the switching fatigu…
The internal stress in anode-supported solid-oxide fuel cells (SOFCs) was evaluated by in situ measurement using high-energy x-ray synchrotron radiation. The oxidized cell had a compression of ∼400MPa in the c-ScSZ electrolyte thin film and a tension of 50–100 MPa in the NiO-YSZ anode substrate at room temperature. Th…
Abstract Cellulose fiber waste from the white cellulose pulp purification process produced by the company Nipo Cellulose‐Brazil (CENIBRA) was used in the preparation of composites with polyurethane. An elastomeric polyurethane based on polyether poly(tetramethylene glycol) and 4,4‐diphenylmethane diisocyanate was used…
In discrete systems the number density, defined as the number of particles per unit volume, is subject to fluctuations depending on the size and location of the sampling volume. Fluctuations in the local density or pair distribution function as determined from x-ray or neutron diffraction experiments, die out quickly…
NiTi-wire shape memory alloy (SMA) dampers, which utilize NiTi SMA wires to simultaneously damp tension, compression, and torsion, have been developed for structural control implementation in this study. First, three reduced-scale NiTi-wire SMA dampers were constructed. Then, mechanics analysis of the NiTi-wire SMA da…
Owing to the limited experimental resolution of data in macromolecular crystallography, ab initio phasing is successful only when atomic or quasi-atomic resolution data are available. It is shown that extrapolating the moduli and phases of non-measured reflections beyond and behind the experimental resolution limit ma…
Twisted-nematic liquid-crystal devices having high spatial resolution are suitable for spatial light modulators. Phase-modulation characteristics of the devices have been widely studied, but the phase delay calculated using a conventional Jones-matrix model is slightly different from that measured using an interferome…
Abstract A previous study has shown that the adhesion between the film and substrate of film‐insert injection‐molded poly(propylene) (PP) film/PP substrate was evident with the increases in barrel temperature and injection holding pressure. In this second part of the research work, the crystallinity at the interfacial…
We apply RISM (reference interaction site model) and PRISM (polymer-RISM) theories to calculate the site–site pair structure and the osmotic equation of state of suspensions of circular or hexagonal platelets (lamellar colloids) over a range of ratios of the particle diameter over thickness Dσ. Despite the neglect of…
Mass spectrometry, in particular MALDI-MS, has often been used as a valuable means to characterize dendritic molecules with respect to their molecular masses. Also, it is a valuable tool for analyzing potential defects in their structure which result from incomplete synthetic steps. This article presents a comparison…