Materials Literature
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ZnO nanorod and nanoprism arrays have been directly synthesized on a large-area zinc substrate via a convenient solution method. The products were characterized with XRD, SEM, HRTEM, and photoluminescence (PL) spectroscopy. The influence of the solvent and the concentration of NaOH on the size and shapes of the as-pre…
[reaction: see text] A stepwise route to unsymmetrical tetraarylazadipyrromethenes by a condensation of 2,4-diaryl-5-nitroso-pyrroles with 2,4-diarylpyrroles is described. This modular building-block approach allows for the introduction of up to four different aryl substituents on the azadipyrromethene and is tolerant…
Previous work testing density functionals for use in calculating high-spin-low-spin energy differences, deltaE(HL), for iron(II) spin-crossover transitions has tended to conclude that only properly reparametrized hybrid functionals can predict deltaE(HL) since it seems to depend critically on a correct description of…
In a Luttinger liquid phase of one-dimensional molecular matter the strength of zero-point motion can be characterized by dimensionless De Boer's number quantifying the interplay of quantum fluctuations and two-body interactions. Selecting the latter in the Morse form we show that dissociation of the Luttinger liquid…
Granular materials exhibit a strongly nonlinear behaviour affecting the propagation of information in the medium. Dynamically self-organized strongly nonlinear solitary waves are the main information carriers in granular chains. Here we report the first experimental observation of the dramatic change of reflectivity f…
Strained Pr$_{0.5}$Ca$_{0.5}$MnO$_3$/La$_{0.5}$Ca$_{0.5}$MnO$_3$/Pr$_{0.5}$Ca$_{0.5}$MnO $_3$ trilayers were grown on (001)-SrTiO$_3$ substrates using the pulsed-laser deposition technique. The coupling at the interfaces of several trilayers has been investigated from magnetization and electronic transport experiments…
We investigate theoretically the efficiency of the Rashba effect, i.e. the spin splitting resulting from an electric field. This is the mechanism behind the Datta-Das spin transistor. In the research efforts so far the carriers have usually been taken to be electrons. Here we demonstrate remarkable improvements by sev…
The pressure dependence of electronic structure, exchange interactions, and Curie temperature in the ferromagnetic Heusler alloy ${\mathrm{Ni}}_{2}\mathrm{MnSn}$ has been studied theoretically within the framework of the density-functional theory. The calculation of the exchange parameters is based on the frozen-magno…
The effects of metal coating on the near-band-edge emission of ZnO thin films have been studied by photoluminescence and atomic force microscopy. Large enhancement in emission intensity has been observed from ZnO films when they are capped by Ag while negligible effect is seen on Au-coated films. In addition, the enha…
Phonons, i.e., quanta of lattice vibrations, manifest themselves practically in all electrical, thermal and optical phenomena in semiconductors and other material systems. Reduction of the size of electronic devices below the acoustic phonon mean free path creates a new situation for phonon propagation and interaction…
Mesoscale objects with unusual structural features may serve as the analogues of atoms in the design of larger-scale materials with novel optical, electronic or mechanical behaviour. In this paper we investigate the structural features and the equilibrium dynamics of micron-scale spherical crystals formed by polystyre…
Analytic expressions for strains in carbon nanotubes of all chiralities in lateral and axial directions have been obtained. These expressions have been related to bond angle and bond length flexibilities. This finally results in obtaining very generalized results for Poisson ratio of all chirality and all diameter car…
It has been puzzling that the Raman optical modes shift to lower frequency (or termed as optical mode softening) associated with creation of Raman acoustic modes that shift to higher energy (or called as acoustic hardening) upon nanosolid formation and size reduction. Understandings of the mechanism behind the size-in…
We discuss recent specific heat data in high magnetic fields on URu2Si2 and 4% Rh-doped URu2Si2 as well as previously published de Haas-van Alphen data at lower magnetic fields in pure URu2Si2; both of which are consistent with quasiparticle bands formed from a hybridization between 5f-electron Gamma5 doublets and reg…
We have studied photoluminescence (PL) properties of Eu-doped ZnO (ZnO:Eu) nanorods fabricated by a microemulsion method. The ZnO:Eu nanorods have a hexagonal crystal structure and exhibit a sharp luminescence due to the intra-4f transitions of Eu3+ ions. The excitation energy and temperature dependence of the PL inte…
Grand canonical Monte Carlo simulations are performed to study the adsorption of water in single-walled (6:6), (8:8), (10:10), (12:12), and (20:20) carbon nanotubes in the 248-548 K temperature range. At room temperature the resulting adsorption isotherms in (10:10) and wider single-walled carbon nanotubes (SWCNs) are…
The long-range correction (LC) scheme for the exchange functional of density-functional theory (DFT) was combined with the coupled-perturbed Kohn-Sham (CPKS) method to calculate nonlinear optical response properties. By using this LC-CPKS method, we calculated the hyperpolarizabilities of typical molecules and the dip…
Fiber-shaped H-aggregates with lengths of up to 300 microm are synthesized by self-assembly of thiacyanine (TC) dye molecules in solution. Photoluminescence (PL) images and spatially resolved PL spectra of the fibers that are transferred onto a glass substrate reveal that the fibers act as single-mode optical waveguid…
Reversible addition−fragmentation chain transfer polymerization (RAFT) was used to prepare polymer brushes grafted onto silica nanoparticles. Novel RAFT-silane agents were prepared that contained both an active RAFT moiety and a silane coupling agent. RAFT agents were anchored to silica nanoparticles by the functional…
Current knowledge of toughening mechanisms in zirconia ceramics is reviewed, with particular emphasis on the transformation toughening of yttria-stabilised polycrystalline tetragonal zirconia (Y-TZP). The physics and mechanics of transformation toughening are discussed, but the main aim is to provide a comprehensive u…