Materials Literature
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A number of phosphatidyl choline derivatives containing trans -azobenzene units in the fatty ester backbone have been synthesized and studied in aqueous dispersions both pure and in the presence of saturated and unsaturated phospholipids. The structures of the assemblies formed have been investigated by microcalorimet…
There have been significant developments in the pillaring of lamellar ionic materials, and the resulting zeolite-like pillared derivatives have built a large family of microporous materials. This review focuses on the host−guest reactions involved in the preparative procedures. Furthermore, approaches to the modificat…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTExact Linear Analogs of Dendritic Polyether Macromolecules: Design, Synthesis, and Unique PropertiesCraig J. Hawker, Eva E. Malmström, Curtis W. Frank, and J. Patrick KampfView Author Information Center for Polymeric Interfaces and Macromolecular Assemblies IBM Almaden…
Swollen and highly ordered MCM-41 type materials with varied pores sizes, but with similar wall thicknesses, have been directly synthesized in the absence of auxilliary organics by controlling the preparation conditions. The most important parameter in the synthesis in order to control the pore opening is the cetyltri…
Ti−MCM41 catalysts prepared by anchoring titanocene onto the inner walls of MCM-41 exhibit high catalytic performance in the epoxidation of cyclohexene and in oxidation of bulky cyclic and aromatic compounds because of the presence, as revealed by means of XANES and EXAFS spectroscopy, of a high concentration of acces…
The structures, phase transformations, and dielectric properties of pyrochlore ceramics containing bismuth were studied. The relation between the orthorhombic and cubic pyrochlores in the Bi 2 O 3 ‐ZnO‐Nb 2 O 5 (BZN) system has been investigated. The effect of bismuth in distorted cubic pyrochlore structures is discus…
A model based on grain-boundary sliding control of the flow process of nano-crystalline materials is proposed. It is demonstrated that the agreement between the theory and the experimental results concerning both nanocrystalline metals and ceramics is quite satisfactory.
The vibrational properties of models of vitreous silica constructed by molecular-dynamics simulation with different interatomic potentials have been investigated. The static and dynamical structure factors of the model systems are in good agreement with experimental data. Partial and total vibrational densities of sta…
The atomic pair-density function of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3}$ $(0<~x<~0.4)$ obtained by pulsed neutron diffraction indicates that their local atomic structure significantly deviates from the average structure, and that the local Jahn-Teller (JT) distortion persists eve…