Materials Literature
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Two simple models of two-dimensional auxetic (i.e. negative Poisson's ratio) foams are studied by computer simulations. In the first one, further referred to as a Y-model, the ribs forming the cells of the foam are connected at points corresponding to sites of a disordered honeycomb lattice. In the second one, coined…
Naphthyl-substituted ortho-carboranes, which were prepared following the reaction between acetylene and decarborane, showed unique multiple photoluminescence behavior associated with intramolecular charge transfer (see picture). On the basis of theoretical calculations, the photoluminescence is shown to originate fro…
The work describes the mechanical performance of a metal rubber particles (MRP) damper design based on an auxetic (negative Poisson's ratio) cellular configuration. The auxetic damper configuration is constituted by an anti-tetrachiral honeycomb, where the cylinders are filled with the MRP material. The MRP samples ha…
Porous nitrogen-doped carbon nanotubes (PNCNTs) with a high specific surface area (1765 m(2) g(-1)) and a large pore volume (1.28 cm(3) g(-1)) have been synthesized from a tubular polypyrrole (T-PPY). The inner diameter and wall thickness of the PNCNTs are about 55 nm and 22 nm, respectively. This material shows extre…
Herein, we present the novel synthesis of tetrahedrite copper antimony sulfide (CAS) nanocrystals (Cu12Sb4S13), which display strong absorptions in the visible and NIR. Through ligand tuning, the size of the Cu12Sb4S13 NCs may be increased from 6 to 18 nm. Phase purity is achieved through optimizing the ligand chemist…
Artificial all‐surface‐atomic 2D sheets can trigger breakthroughs in tailoring the physical and chemical properties of advanced functional materials. Here, the conceptually new all‐surface‐atomic semiconductors of SnS and SnSe freestanding sheets are realized using a scalable strategy. As an example, all‐surface‐atomi…
The objective of this study was to assess the chemical properties of wood from six clones of Eucalyptus spp. relative to charcoal yield and its properties, determine the correlations between the evaluated parameters and identify a clone of Eucalyptus having the greatest potential for charcoal to steelmaking use. The s…
A facile reactive-template strategy has been developed to fabricate porous SnO2 nanotubes using MnO2 nanorods as the sacrificial template. The formation of nanotubes is based on the redox reaction mechanism, which requires no post-treatment of the MnO2 templates. The morphological and structural characteristics of the…
The development of high-performance Na-ion intercalation electrodes has been required recently because Na-ion batteries hold much promise for inexpensive and efficient energy storage, which can be deployed in a power grid. For both optimization and better understanding of the electrode materials, it is indispensable t…
Discrete three-dimensional (3D) plasmonic nanoarchitectures with well-defined spatial configuration and geometry have aroused increasing interest, as new optical properties may originate from plasmon resonance coupling within the nanoarchitectures. Although spherical building blocks have been successfully employed in…
Herein we report the photocontrol of cucurbit[8]uril (CB[8])-mediated supramolecular polymerization of azobenzene-containing monomers. The CB[8] polymers were characterized both in solution and in the solid state. These host-guest complexes can be reversibly switched between highly thermostable photostationary states.…
Sodium ion (Na(+)) batteries have attracted increased attention for energy storage due to the natural abundance of sodium, but their development is hindered by poor intercalation property of Na(+) in electrodes. This paper reports a detailed study of high capacity, high rate sodium ion energy storage in functionalized…
While the unique optical properties of liquid crystals (LCs) are already well exploited for flat-panel displays, their intrinsic ability to self-organize into ordered mesophases, which are intermediate states between crystal and liquid, gives rise to a broad variety of additional applications. The high degree of molec…
Superior mechanical properties and self-healing are two hot topics in hydrogel science due to their tight relationship with the following potential application scopes. Most of the conventional hydrogels do not possess both features at the same time. Herein, we expand the recently proposed intertwined double-network me…
Detection of early malignant tumors remains clinically difficult; developing ultrasensitive imaging agents is therefore highly demanded. Owing to the unusual magnetic and optical properties associated with f-electrons, rare-earth elements are very suitable for creating functional materials potentially useful for tumor…
All-solid-state secondary batteries that employ inorganic solid electrolytes are desirable because they are potentially safer than conventional batteries. The ionic conductivities of solid electrolytes are currently attracting great attention. In addition to the conductivity, the mechanical properties of solid electro…
The electronic structure of transition metal oxides is frequently studied using density functional theory. Nonetheless, the electronic structure of VO3 has been found to be sensitive to the choice of functional. As a consequence, the basic question of whether or not the ground electronic state exhibits a Jahn-Teller d…
M-type lead hexaferrites with compositions of PbFe12O19 and PbSnZnFe10O19 were synthesized by the citrate sol–gel method. The structural and magnetic properties of resultant particles were investigated by X-ray diffraction (XRD), transmission electron microscope (TEM), vibrating sample magnetometer (VSM) and vector ne…
The paper reports on new results obtained for tetragonal quasi-2D antiferromagnetic Eu2CuO4 at temperatures below 30-40 K. A set of ferromagnetic resonance lines similar to ones obtained earlier for a number of multiferroic manganites (Sanina et al 2012 J. Phys.: Condens. Matter 24 346002), with similar electric polar…
Kern-Schale-Biohybridkapseln (siehe Bild), die flüchtige Verbindungen verkapseln können, entstehen durch Fällung von amorphem Siliciumdioxid in einem Protein-Polyanion-Koazervatgerüst. Dieses Gerüst gibt der Kapselhülle ihre endgültige Form und Struktur und stellt eine acide Mikroumgebung bereit, in der die Hydrolyse…