Materials Literature
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The diffusivities of methane in single-walled carbon nanotubes (SWNTs) are investigated at various temperatures and pressures using classical molecular dynamics (MD) simulations complemented with grand canonical Monte Carlo (GCMC) simulations. The carbon atoms at the nanotubes are structured according to the (m, m) ar…
Abstract Bromide-containing impurities were found to decrease the thermal stability of quaternary alkyl ammonium-modified layered silicates. Improved purification procedures completely removed bromide and led to a 20°C to >100°C increase in organic modified layered silicate thermal stability. Using mass spectrometr…
Investigation results of dielectric and ultrasonic properties of layered CuInP2S6 crystals are presented. At low frequencies, dielectric spectra are highly influenced by the high ionic conductivity with the activation energy of 7357.4 K (0.635 eV). The high-frequency part of the spectra is determined by relaxational s…
Laboratory tests have been performed to determine how climatic parameters, e.g., relative humidity, temperature, and the amount of sodium chloride (NaCl), influence the corrosion rate of magnesium alloys AZ91D (UNS M11916) and AM50 (UNS M10500). The effect of the surface state also has been investigated. The exposures…
Efficient hydrolysis of native poly(3-hydroxybutyrate) (nPHB) granules in vitro by soluble PHB depolymerase of Rhodospirillum rubrum requires pretreatment of nPHB with an activator compound present in R. rubrum cells (J. M. Merrick and M. Doudoroff, J. Bacteriol. 88:60-71, 1964). Edman sequencing of the purified activ…
Thermal transitions and morphological changes in Cloisite organoclays were investigated by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, and in situ simultaneous small-angle X-ray scattering (SAXS) and wide-angle X-ray diffraction (WAXD) over…
The adsorption of small molecules $({\mathrm{N}}_{2},$ ${\mathrm{O}}_{2},$ CO, ${\mathrm{CO}}_{2},$ ${\mathrm{H}}_{2}\mathrm{O},$ and HF) in model ropes of carbon nanotubes has been studied to determine the main parameters (stable adsorption sites, potential barriers, $\dots{})$ which define the ability of carbon nano…
We found a new method for the preparation of gold nanorod and nanosphere films. The nanoparticle films could be formed at the liquid-liquid interface between aqueous and hexane solutions and were almost monolayers. Surface-enhanced Raman scattering (SERS) spectra of rhodamine 6G under the nonresonance condition were m…
The dissolution and precipitation rates of rhombohedral carbonate minerals, such as CaCO 3 , ZnCO 3 , MnCO 3 , FeCO 3 , and MgCO 3 , affect the alkalinity and redox state of natural waters. In the current study, the rates and mechanisms of carbonate dissolution are investigated utilizing an atomic force microscope/flo…
The effect of Y 2 O 3 content on the flexure strength of melt‐grown Al 2 O 3 –ZrO 2 eutectics was studied in a temperature range of 25°–1427°C. The processing conditions were carefully controlled to obtain a constant microstructure independent of Y 2 O 3 content. The rod microstructure was made up of alternating bands…
Cu(OH) 2 nanowires have been successfully synthesized at the organic−aqueous interface by the interaction of the copper−bis(2-ethylhexyl) phosphate complex in the organic layer with NaOH in aqueous layer. The nanowires have an average length of 4 μm and are several nanometers in width. CuO nanowires and short wiskers…
Gephyrin is an essential and instructive molecule for the formation of inhibitory synapses. Gephyrin binds directly to the large cytoplasmic loop located between transmembrane helices three and four of the beta-subunit of the glycine receptor and to microtubules, thus promoting glycine receptor (GlyR) anchoring to the…
To prepare novel 2-methacryloyloxyethyl phosphorylcholine (MPC)-polymeric nanoparticle (MPC-PNP), water-soluble amphiphilic phospholipid polymer, poly [MPC-co-n-butyl methacrylate (BMA)-co-p-nitrophenyloxycarbonyl poly(ethylene glycol) methacrylate (MEONP) (PMBN)], which has active ester groups for bioconjugation on t…
Nanoparticles with a modified surface are prepared from nanodiamonds produced in Russia. The properties of modified nanodiamonds and their hydrosols and organosols are investigated by biophysicists with the aim of preparing nanoparticles with controlled properties for solving biological problems.
In situ tissue engineering using shear-stress preconditioning and adhesive biomolecules is a new approach to autologous tissue engineering. In the present study, novel tissue-engineering grafts (TEGs) were preconditioned within an in vitro pulsatile flow circuit, with and without the addition of fibronectin (FN), to e…
A structural experiment at the National Center for Asphalt Technology (NCAT) test track was warranted to advance mechanistic-empirically based (M-E) design and analysis. The objectives of the structural experiment at the NCAT test track are as follows: 1. Validate mechanistic pavement models. 2. Develop transfer funct…
The latest process for producing large quantities of single-walled carbon nanotubes (SWNTs) to emerge from the Rice University, dubbed HiPco, is living up to its promise. The current production rates approach 450 mg/h (or 10 g/day), and nanotubes typically have no more than 7 mol % of iron impurities. Second-generatio…
ZnSe nanoribbons have been synthesized using sputter-coated gold films as catalysts via metalorganic chemical vapor deposition on Si (100) substrates. Both x-ray and selected area electron diffractions determine that they have the zinc-blende structure. High-resolution transmission electron microscopic investigations…
The main theoretical aspects of detonation decomposition of powerful mixed explosives with a negative oxygen balance accompanied by the formation of nanodiamonds (ultrafine-dispersed diamonds, UDDs) are described. The basic UDD synthesis parameters are considered, and the expediency of using trotyl-hexogen alloys is s…
ABSTRACT Water solubility, hermal properties, tensile strength, percent elongation, oxygen permeability (OP), water‐vapor permeability (WVP) of cross‐linked glycerol plasticized whey protein isolate films were studied to determine the effect of cross‐linkers (glutaraldehyde, formaldehyde, dialdehyde starch, carbonyldi…