Materials Literature
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To utilize a new conformation-dependent backbone-geometry library (CDL) in protein refinements at atomic resolution, a script was written that creates a restraint file for the SHELXL refinement program. It was found that the use of this library allows models to be created that have a substantially better fit to main-c…
The success of nanoparticle-based devices will need reliable fabrication methods for well-defined, defect-free self-assembled structures of nanoparticles (NPs). NP self-assembly is a process governed by an interplay between many inter-particle interactions, such as core-core van der Waals and dipolar attractions, as w…
The electrical resistivity, crystalline structure, and electronic properties calculated from the experimentally measured atomic positions of the compound SmFeAsO${}_{0.81}$F${}_{0.19}$ have been studied up to pressures \ensuremath{\sim}20 GPa. The correlation between the pressure dependence of the superconducting tran…
Abstract A series of efficient zinc catalysts supported by sterically bulky benzotriazole phenoxide ( BTP ) ligands are synthesized and structurally characterized. The reactions of diethyl zinc (ZnEt 2 ) with CMe2Ph BTP ‐H, t‐Bu BTP ‐H, and TMCl BTP ‐H yield monoadduct [(μ‐ BTP )ZnEt] 2 ( 1 – 3 ), respectively. Bisadd…
Two distinct morphologies of hexylselenophene-hexylthiophene rod-rod block copolymer films can be prepared depending on the molecular weight of the sample (see picture: left M(n) =12.9, right M(n) =3.9 kg mol(-1)). These polymers can be used to organize spherical CdSe nanocrystals (yellow) into either dispersed or ali…
A nanocomposite composed of NbTi nanowires uniformly embedded in NiTi matrices was fabricated, which exhibits an ultrahigh mechanical-damping capability. The absorption energy measured under an applied 8% strain is up to 54 MJ/m3, which is over three times higher than that (∼16 MJ/m3) found in the well-known Ni-Ti all…
We study inelastic energy relaxation in graphene for low energies to find out how electrons scatter with acoustic phonons and other electrons. By coupling the graphene to superconductors, we create a strong dependence of the measured signal, i.e., critical Josephson current, on the electron population on different ene…
Shape memory alloys (SMAs) are well known for their unique shape memory effect (SME) and superelasticity (SE) behavior. The SME and SE have been extensively investigated in past decades due to their potential use in many applications, especially for smart materials. The unique effects of the SME and SE originate from…
A fast-response and scattering-free polymer network liquid crystal (PNLC) light modulator is demonstrated at λ = 1.06 μm wavelength. A decay time of 117 μs for 2π phase modulation is obtained at 70 °C, which is ∼ 650 × faster than that of the host nematic LCs. The major tradeoff is the increased operating voltage. Pot…
We propose the use of high strength, metal-coated Kevlar yarns to weave flexible, conformal, and load-bearing antennas for an emerging class of applications emphasizing multiple functionality. In particular, here we present a unified, quantitative analysis of multiple properties of conductors as load-bearing materials…
Abstract Natural fiber‐reinforced nanocomposites based on polypropylene/nanoclay/banana fibers were fabricated by melt mixing in a twin‐screw extruder followed by compression molding in this current study. Maleic anhydride polypropylene copolymer (MA‐g‐PP) was used as a compatibilizer to increase the compatibility bet…
Intimal hyperplasia is one of the prominent failure mechanisms for arteriovenous fistulas and arteriovenous access grafts. Human tissue-engineered vascular grafts (TEVGs) were implanted as arteriovenous grafts in a novel baboon model. Ultrasound was used to monitor flow rates and vascular diameters throughout the stud…
We conducted the measurement of the hardness-depth relationship of NiTi shape memory alloy with a sharp Berkovich indenter. Different from most ductile metals, NiTi reacts to the mechanical load of indentation through phase transition underneath the indentation tip. We found that the hardness decreases rapidly with th…
The role of the oxide-metal interface in determining the activity and selectivity of chemical reactions catalyzed by metal particles on an oxide support is an important topic in science and industry. A proposed mechanism for this strong metal–support interaction is electronic activation of surface adsorbates by charge…
Graphene nanohole arrays (GNAs) were fabricated using nanoimprint lithography. The improved optical transmittance of GNAs is primarily due to the reduced surface coverage of graphene from the nanohole fabrication. Importantly, the exposed edges of the nanoholes provided effective sites for chemical doping using thiony…
In this study, ZnO-loaded PA6 nanocomposite preparation and its antibacterial activity are investigated. This work aims to study the effect of the sizes and amount of the ZnO nanofiller on the antibacterial, mechanical, and thermal properties of the PA6/ZnO nanocomposites. The melt intercalation method is applied to p…
A procedure is described for preparing polyamide-6 (PA-6) reinforced with cellulose nanofibres. The cellulose nanofibres were obtained from flax and microcrystalline cellulose (MCC) using combinations of acid hydrolysis, ball milling and ultrasound, then characterised by transmission electron microscopy (TEM) in order…
The moisture transfer and absorption properties of fabrics play an important role in the evaluation of the overall wear comfort of the textile. The location of moisture in the textile influences the skin wetness as well as the skin/textile friction process. In this study, we used X-ray tomography to analyze the transp…
Mesoscale ordering of a Zr-bearing aluminosilicate glass is determined using high-angle annular dark field scanning transmission microscopy, corrected from aberration. This method reveals evidences for the presence of nanometer-size inhomogeneities in a macroscopically isotropic glass, with regions enriched in Zr. The…
The investigation of hydrophobic interactions under confined conditions is of tremendous interdisciplinary interest. It is shown that based on porous capsules of the type {(pentagon)}(12){(linker)}(30) ≡ {(Mo)Mo(5)(12){Mo(2)(ligand)}(30), which exhibit different hydrophobic interiors-achieved by coordinating related l…