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Revealing the dual nature of magnetism in iron pnictides and iron chalcogenides using x-ray emission spectroscopy

H. Gretarsson、A. Lupascu、Jungho Kim 等 21 位作者2011-09-22Physical Review B

We report a Fe K$\ensuremath{\beta}$ x-ray emission spectroscopy study of local magnetic moments in various iron-based superconductors in their paramagnetic phases. Local magnetic moments are found in all samples studied: PrFeAsO, $\mathrm{Ba}{(\mathrm{Fe},\mathrm{Co})}_{2}{\mathrm{As}}_{2}$, LiFeAs, Fe${}_{1+x}$(Te,S…

Iron-based superconductors researchRare-earth and actinide compounds

Crossover from antiferromagnetic to ferromagnetic ordering in the semi-Heusler alloys Cu1−xNixMnSb with increasing Ni concentration

Madhumita Halder、S. M. Yusuf、Amit Kumar 等 5 位作者2011-09-22Physical Review B

The magnetic properties and transition from an antiferromagnetic (AFM) to a ferromagnetic (FM) state in semi-Heusler alloys Cu${}_{1\ensuremath{-}x}$Ni${}_{x}$MnSb, with x 0.3 have been investigated in detail by dc magnetization, neutron diffraction, and neutron depolarization. We observe that for x 0.05, the system C…

Heusler alloys: electronic and magnetic propertiesShape Memory Alloy TransformationsMagnetic and transport properties of perovskites and related materials

Predicting dislocation climb: Classical modeling versus atomistic simulations

Emmanuel Clouet2011-09-22Physical Review B

The classical modeling of dislocation climb based on a continuous description of vacancy diffusion is compared to recent atomistic simulations of dislocation climb in body-centered cubic iron under vacancy supersaturation [Phys. Rev. Lett. 105, 095501 (2010)]. A quantitative agreement is obtained, showing the ability…

Microstructure and Mechanical Properties of SteelsHigh Temperature Alloys and CreepMicrostructure and mechanical properties

The interaction of Fe thin layers between MgO(100)-MgO and MgO(100)-Ag surfaces

I. Dézsi、Cs. Fetzer、F. Tanczikó 等 5 位作者2011-09-22arXiv

The atomic interaction and magnetic properties of ultrathin Fe films grown on cleaved and polished MgO(100) surfaces were studied by conversion electron Mössbauer spectroscopy (CEMS) in broad temperature range. Fe with different layer thickness was deposited on MgO substrates. The layers were formed on polished and cl…

Materials Science

The role of oxygen and surface reactions in the deposition of silicon oxide like films from HMDSO at atmospheric pressure

R. Reuter、K. Rügner、D. Ellerweg 等 6 位作者2011-09-22arXiv

The deposition of thin SiO$_x$C$_y$H$_z$ or SiO$_x$H$_y$ films by means of atmospheric pressure microplasma jets with admixture of Hexamethyldisiloxane (HMDSO) and oxygen and the role of surface reactions in film growth are investigated. Two types of microplasma jets, one with a planar electrodes and operated in heliu…

Materials Sciencephysics.plasm-ph

Tayloring neutron optical performance of Fe/Si multilayers

D. G. Merkel、L. Bottyán、B. Nagy 等 6 位作者2011-09-22arXiv

Reflected neutron beam originating from a crystal monochromator contains higher order wavelength contribution. Creating multilayer mirror structures with custom reflectivity curves including a monochromatic polarized neutron beam is a challenge in modern neutron optics. In this work we present the study of three types…

physics.ins-detMaterials Science

Ion association in low-polarity solvents: comparisons between theory, simulation, and experiment

Chantal Valeriani、Philip J. Camp、Jos W. Zwanikken 等 5 位作者2011-09-22arXiv

The association of ions in electrolyte solutions at very low concentration and low temperature is studied using computer simulations and quasi-chemical ion-pairing theory. The specific case of the restricted primitive model (charged hard spheres) is considered. Specialised simulation techniques are employed that lead…

Materials ScienceSoft Condensed MatterChemical Physics

Ironsilicide formation by high temperature codeposition of Fe-2Si with different thicknesses on Si (111)

I. Dézsi、Cs. Fetzer、F. Tanczikó 等 7 位作者2011-09-22arXiv

Fe and 2Si were co-deposited on Si (111) surface at 853 K. The formation of silicides was investigated by Mossbauer spectroscopy and electron microscopy. Depending on the thickness of the deposited films different phases were formed. At low thickness, stable $ε$-FeSi (B20) and metastable [CsCl]-Fe$_{1-x}$Si (B2) phase…

Materials Science

Self-Diffusion of Iron in L10 FePd film - as revealed by reflectometric methods

D. G. Merkel、L. Bottyán、Sz. Sajti 等 10 位作者2011-09-22arXiv

L10 (CuAu(I)-type) ordered FePd as well as FePt and CoPt, due to their high magnetic anisotropy, are candidate materials for future ultra-high density magnetic recording. Atomic diffusion governs the structural relaxation and associated changes in the physical and magnetic properties in these alloys. Such processes in…

Materials Science

Self-Diffusion of Iron in L10 FePd films Upon He-irradiation (alternative title: An alternative for diffusion studies in isotopic FePd multilayers)

D. G. Merkel、L. Bottyán、F. Tanczikó 等 9 位作者2011-09-22arXiv

The continuous need towards improving the capacity of magnetic storage devices requires materials with strong perpendicular magnetic anisotropy. FePd, CoPd and their Co(Fe)Pt counterparts very attractive candidate for such purposes. The magnetic properties of these films are largely dependent on the orientation and lo…

Materials Science

CO2 adsorption on TiO2(101) anatase: A dispersion-corrected density functional theory study

Dan C. Sorescu、W. A. Al-Saidi、Kenneth D. Jordan2011-09-22The Journal of Chemical Physics

Adsorption, diffusion, and dissociation of CO(2) on the anatase (101) surface were investigated using dispersion-corrected density functional theory. On the oxidized surface several different local minima were identified of which the most stable corresponds to a CO(2) molecule adsorbed at a five-fold coordinated Ti si…

Catalysis and Oxidation ReactionsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

London penetration depth in iron-based superconductors

R Prozorov、V G Kogan2011-09-22Reports on Progress in Physics

Measurements of London penetration depth are a sensitive tool to study multi-band superconductivity and it has provided several important insights to the behavior of Fe-based superconductors. We first briefly review the "experimentalist - friendly" self-consistent Eilenberger model that relates the measurable superflu…

Electronic and Structural Properties of OxidesIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Using Si and Ge Nanostructures as Substrates for Surface-Enhanced Raman Scattering Based on Photoinduced Charge Transfer Mechanism

Lin Guo、Wensheng Shi、Guangwei She 等 4 位作者2011-09-22Journal of the American Chemical Society

The possibility of utilizing the Si and Ge nanostructures to promote surface-enhanced Raman scattering (SERS) is discussed. The vibronic coupling of the conduction band and valence band states of Si or Ge with the excited and ground states of the target molecule during the charge transfer (CT) process could enhance th…

Nanocluster Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesGold and Silver Nanoparticles Synthesis and Applications

Combined excitation-emission spectroscopy of bismuth active centers in optical fibers

Sergei Firstov、V. F. Khopin、I. A. Bufetov 等 6 位作者2011-09-22Optics Express

For the first time, 3-dimensional luminescence spectra (luminescence intensity as a function of the excitation and emission wavelengths) have been obtained for bismuth-doped optical fibers of various compositions in a wide spectral range (450-1700 nm). The bismuth-doped fibers investigated have the following core comp…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsGlass properties and applications

In-plane electronic anisotropy of underdoped ‘122’ Fe-arsenide superconductors revealed by measurements of detwinned single crystals

I R Fisher、L Degiorgi、Z X Shen2011-09-22Reports on Progress in Physics

The parent phases of the Fe-arsenide superconductors harbor an antiferromagnetic ground state. Significantly, the Néel transition is either preceded or accompanied by a structural transition that breaks the four-fold symmetry of the high-temperature lattice. Borrowing language from the field of soft condensed matter p…

Rare-earth and actinide compoundsIron-based superconductors researchTopological Materials and Phenomena

Dual Phase‐Controlled Synthesis of Uniform Lanthanide‐Doped NaGdF4 Upconversion Nanocrystals Via an OA/Ionic Liquid Two‐Phase System for In Vivo Dual‐Modality Imaging

He Meng、Peng Huang、Chunlei Zhang 等 8 位作者2011-09-22Advanced Functional Materials

Abstract A novel OA/ionic liquid two‐phase system combining the merits of thermal decomposition method, the IL‐based strategy, and the two‐phase approach is introduced to synthesize high‐quality lanthanide‐doped NaGdF 4 upconversion nanocrystals with different crystal‐phases in OA‐phase and IL‐phase through a one‐step…

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsInorganic Fluorides and Related Compounds

Zirconia based ceramic coating on a metal with plasma electrolytic oxidation

Takashi Akatsu、Tadashi Kato、Yutaka Shinoda 等 4 位作者2011-09-21IOP Conference Series Materials Science and Engineering

We challenge to fabricate a thermal barrier coating (TBC) made of ZrO 2 based ceramics on a Ni based single crystal superalloy with plasma electrolytic oxidation (PEO) by incorporating metal species from electrolyte into the coating. The PEO process is carried out on the superalloy galvanized with aluminium for 15min…

Magnesium Alloys: Properties and ApplicationsCorrosion Behavior and InhibitionHigh-Temperature Coating Behaviors

Influence of the Secondary Raw Materials on the Mechanical Properties of Multilayer Films

Rimantas Didžiokas、Jolanta Janutėnienė、Marius Gintalas 等 4 位作者2011-09-21Key engineering materials

Recycling and usage of secondary raw materials in production is one of the most topical issues. Usage of secondary raw materials is one of the most topical issues in both economic and ecological (environmental) sense. Such a layered film on the market has lower price because secondary raw material prices is significan…

Material Properties and ProcessingMaterial Properties and ApplicationsTextile materials and evaluations

Reversible Control in Surface Plasmon Resonance Wavelength of Gold Nanoparticles by Using Polydimethylsiloxane (PDMS)

Yushi Tsutsui、Hiroshi Fudouzi、Tomokatsu Hayakawa 等 4 位作者2011-09-21IOP Conference Series Materials Science and Engineering

In this paper, we demonstrate reversible control in surface plasomon resonance (SPR) wavelength of gold nanoparticles (GNPs) by changing their interparticle distance, which is dependent on the length of alkyl chain of alkanethiol adsorbed on GNPs and the swelling effect of polydimethylsiloxane (PDMS) used as a host ma…

Nonlinear Optical Materials StudiesGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Applying a rigid band model to the XYB14crystal family

Liwen F. Wan、Scott P. Beckman2011-09-21IOP Conference Series Materials Science and Engineering

The compounds AlMgB 14 , AlLiB 14 and MgMgB 14 belong to the same space group, Imma, and share similar structural properties. It is predicted that the rigid band model accurately describes the electronic states of these orthorhombic borides. The position of the Fermi level within the states depends on the metal site c…

MXene and MAX Phase MaterialsSuperconductivity in MgB2 and AlloysBoron and Carbon Nanomaterials Research