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Poole–Frenkel effect in sputter-deposited CuAlO2+xnanocrystals

Arghya Narayan Banerjee、Sang Woo Joo2013-03-27Nanotechnology

Field-assisted thermionic emission within a sputter-deposited, nanocrystalline thin film of CuAlO2.06 is observed for the first time, and explained in terms of the Poole-Frenkel model. The presence of adsorbed oxygen ions as trap-states at the grain boundary regions of the nanostructured thin film is considered to man…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Computed microtomography in the analysis of fiber migration in yarn

M. Toda、Katarzyna Ewa Grabowska2013-03-27Autex Research Journal

Abstract This study is a short analysis of the use of computer microphotography in fiber migration testing as a modern nondestructive testing method. Microtomography operates similarly to X-ray computed tomography systems used in medicine, but with much better resolution owing to the use of a smaller radiation spot. T…

Mechanical Behavior of CompositesComposite Material MechanicsTextile materials and evaluations

Building capacity for ecological assessment using diatoms in UK rivers

Martyn Kelly2013-03-27Journal of Ecology and Environment

Diatoms have become an integral part of the UK's freshwater monitoring strategy over the past two decades, mostly in response to increasingly stringent European Union (EU) legislation. The use of diatoms is based on strong correlations between diatom assemblages and environmental variables, and from knowledge of the "…

Freshwater macroinvertebrate diversity and ecologyDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Cu/Ba/bauxite: an Inexpensive and Efficient Alternative for Pt/Ba/Al2O3 in NOx Removal

Xiuyun Wang、Zhilin Chen、Yongjin Luo 等 5 位作者2013-03-27Scientific Reports

Cu/Ba/bauxite possesses superior NOx storage and reduction (NSR) performances, high thermal stability, strong resistance against SO₂ poisoning and outstanding regeneration ability in comparison with Pt/Ba/Al₂O₃. It can serve as a cheap and promising alternative for traditional Pt/Ba/Al₂O₃ in NOx removal from lean-burn…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Amelioration of Blood Compatibility and Endothelialization of Polycaprolactone Substrates by Surface-Initiated Atom Transfer Radical Polymerization

Shaojun Yuan、Gordon M. Xiong、Ariel Roguin 等 5 位作者2013-03-27InTech eBooks

Amelioration of Blood Compatibility and Endothelialization of Polycaprolactone Substrates by Surface-Initiated Atom Transfer Radical Polymerization

Advanced Polymer Synthesis and CharacterizationElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Self-construction of Magnetic Hollow La0.7Sr0.3MnO3 Microspheres with Complex Units

Xuefeng Chu、Keke Huang、Mei Han 等 4 位作者2013-03-27Inorganic Chemistry

Perovskite structure La0.7Sr0.3MnO3 magnetic hollow microspheres with complex units were prepared via the hydrothermal route without hard and soft templates. The formation of hollow microspheres follows the self-construction mechanism involving oriented attachment, dissolution, and recrystallization processes. It exhi…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Observations on Hippodonta (Bacillariophyceae) in selected ancient lakes

Aleksandar Pavlov、Zlatko Levkov、David M. Williams 等 4 位作者2013-03-27Phytotaxa

This study provides an evaluation of the diversity and distribution of taxa belonging to the genus Hippodonta (Bacillariophyceae) in selected ancient lakes from different geographical regions of the world. The lakes considered are: Lakes Ohrid, Prespa and Dojran fromMacedonia,Lake Tanganyika,Tanzania,Lake Turkana,Keny…

Aquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae ResearchMarine and environmental studies

Luminescent gelatin nanospheres by encapsulating CdSe quantum dots

Longyan Chen、Adrienne Willoughby、Jin Zhang2013-03-27Luminescence

Quantum dots (QDs) have been encapsulated within gelatin nanoparticles (GNPs), which gives GNPs fluorescent properties and improves the biocompatibility of QDs. Hydrophilic CdSe QDs were produced through thermodecomposition following the ligand-exchange method, and were then encapsulated in GNPs. The results of high-r…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

YAG:Ce nanoparticle lightsources

Bruno Masenelli、Oriane Mollet、Olivier Boisron 等 9 位作者2013-03-27Nanotechnology

We investigate the luminescence properties of 10 nm yttrium aluminum garnet (YAG) nanoparticles doped with Ce ions at 0.2%, 4% and 13% that are designed as active probes for scanning near-field optical microscopy. They are produced by a physical method without any subsequent treatment, which is imposed by the desired…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNear-Field Optical Microscopy

A study on the assessment of DNA strand-breaking activity by silver and silica nanoparticles

Ali R. Vahdati、Babak Sadeghi2013-03-27Journal of nanostructure in chemistry

We measured the DNA strand-breaking activity of nanoparticle by agarose gel electrophoresis. Plasmid DNA was mixed with nanosilver and nano-silica powders in an aqueous solution. Then the mixture was applied to 1% of agarose gel electrophoresis at 75 V for 30 min. We used 300 nm of UV irradiation in order to visualize…

Nanoparticles: synthesis and applicationsAdvanced biosensing and bioanalysis techniquesRNA Interference and Gene Delivery

Photomechanical Bending of Azobenzene-Based Photochromic Molecular Fibers

Hideyuki Nakano、Ryoji Ichikawa、Riku Matsui2013-03-27Micromachines

Microfibers composed of azobenzene-based photochromic amorphous molecular materials, namely low molecular-mass photochromic materials with a glass-forming property, could be fabricated. These fibers were found to exhibit mechanical bending motion upon irradiation with a laser beam. In addition, the bending direction c…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryAdvanced Materials and Mechanics

Blocking the butyrate-formation pathway impairs hydrogen production in Clostridium perfringens

Ruisong Yu、Ruofan Wang、Ting Bi 等 5 位作者2013-03-27Acta Biochimica et Biophysica Sinica

Inactivating competitive pathways will improve fermentative hydrogen production by obligate anaerobes, such as those of genus Clostridium. In our previous study, the hydrogen yield of Clostridium perfringens W13 in which l-lactate dehydrogenase was inactivated increased by 44% when compared with its original strain W1…

Microbial Metabolic Engineering and BioproductionMetabolism and Genetic DisordersEnzyme Structure and Function

On the analogy between photoluminescence and carrier-type reversal in Bi- and Pb-doped glasses

Mark Hughes、R. Gwilliam、K.P. Homewood 等 11 位作者2013-03-27Optics Express

Reaction order in Bi-doped oxide glasses depends on the optical basicity of the glass host. Red and NIR photoluminescence (PL) bands result from Bi(2+) and Bin clusters, respectively. Very similar centers are present in Bi- and Pb-doped oxide and chalcogenide glasses. Bi-implanted and Bi melt-doped chalcogenide glasse…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

Elastic transition thresholds in Ge–As(Sb)–Se glasses

Ting Wang、Wen‐Hou Wei、Xiang Shen 等 6 位作者2013-03-27Journal of Physics D Applied Physics

We prepared several groups of Ge x As y Se 1− x − y and Ge x Sb y Se 1− x − y glasses with a fixed y at 10 at%, 15 at% and 20 at%, respectively, and measured their density and elastic moduli with the aim of understanding the correlation between the chemical compositions, the mean coordination numbers (MCNs) and the ph…

Glass properties and applicationsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Strength Enhancement in Miscible Blends of Butyl Rubber and Polyisobutylene

Carl B. Giller、C. M. Roland2013-03-27Macromolecules

The thermodynamic miscibility of polyisobutylene (PIB) with butyl rubber (IIR), a copolymer of isobutene and a few mole % isoprene, was established through observation of spontaneous interdiffusion of the polymers. Networks were prepared from their blend, in which only the IIR component was cross-linked (PIB cannot be…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Mechanical, thermal and degradation properties of jute fabric – reinforced polypropylene composites: Effect of potassium permanganate as oxidizing agent

Jahangir Khan、Mubarak A. Khan、Rabiul Islam2013-03-27Polymer Composites

Abstract Mechanical properties of jute fabrics‐reinforced polypropylene composites were measured with reference to fiber loading and found highest at 45% by the weight of jute fabrics. Jute fabrics were treated with potassium permanganate in acid (oxalic acid and sulphuric acid) and alkaline (KOH) media in order to in…

Nanocomposite Films for Food PackagingPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Direct observation of morphological development during the spin‐coating of polystyrene–poly(methyl methacrylate) polymer blends

Daniel T. W. Toolan、Ehtsham Ul Haq、Alan D. F. Dunbar 等 7 位作者2013-03-27Journal of Polymer Science Part B Polymer Physics

ABSTRACT We present results of the direct observation, in real‐space, of the phase separation of high molecular weight polystyrene and poly(methyl methacrylate) fromortho‐xylene using our newly developed technique of high speed stroboscopic interference microscopy. Taking a fixed concentration (3 wt % ino‐xylene) at a…

Force Microscopy Techniques and ApplicationsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Novel polyfuran/functionalized multiwalled carbon nanotubes composites with improved conductivity: Chemical synthesis, characterization, and antioxidant activity

Ehsan Nazarzadeh Zare‬、Moslem Mansour Lakouraj、Peyman Najafi Moghadam 等 4 位作者2013-03-27Polymer Composites

Abstract Novel composites containing very small quantities of functionalized multiwalled carbon nanotubes (MWCNTs‐COOH; 0.025, 0.050, and 0.075 g), and furan were synthesized via in situ chemical oxidative polymerization. The polymerization was carried out in nitromethane at room temperature using anhydrous iron (III)…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

l -Tyrosinatonickel(II) Complex: Synthesis and Structural, Spectroscopic, Magnetic, and Biological Properties of 2{[Ni( l -Tyr)2(bpy)]}·3H2O·CH3OH

Agnieszka Wojciechowska、Anna Gągor、Marek Duczmal 等 5 位作者2013-03-27Inorganic Chemistry

The complex 2{[Ni(L-Tyr)2(bpy)]}·3H2O·CH3OH [1, where L-Tyr = L-tyrosine; bpy = 2,2'-bipyridine (2,2'-bpy)] was obtained in crystalline form and characterized by X-ray and spectroscopic (FT-IR, NIR-vis-UV, and HFEPR) and magnetic methods. The complex crystallized in the hexagonal system with a = b = 12.8116(18) Å, c =…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Time‐Resolved Evolution of Short‐ and Long‐Range Order During the Transformation of Amorphous Calcium Carbonate to Calcite in the Sea Urchin Embryo

Chantel C. Tester、Ching‐Hsuan Wu、Minna R. Krejci 等 10 位作者2013-03-27Advanced Functional Materials

Abstract Use of amorphous precursors is a widespread strategy in biomineralization. In sea urchin embryos, controlled transformation of amorphous calcium carbonate (ACC) to calcite results in smoothly curving and branching single crystals. However, the mechanism of the disorder‐to‐order transformation remains poorly u…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition