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Preservation of Antibody Selectivity on Graphene by Conjugation to a Tripod Monolayer

Jason A. Mann、Thomas Alava、Harold G. Craighead 等 4 位作者2013-02-05Angewandte Chemie International Edition

Three is a magic number: Antibodies adsorbed on bare graphene lose their ability to recognize antigens. However, this obstacle can be overcome by the conjugation of these antibodies to self-assembled monolayers of a tripodal compound (see picture).

Graphene research and applicationsAdvanced biosensing and bioanalysis techniquesGraphene and Nanomaterials Applications

Structure and morphology of magnetron sputtered W films studied by x-ray methods

Krešimir Salamon、O. Milat、Nikola Radić 等 6 位作者2013-02-05Journal of Physics D Applied Physics

The structural and morphological studies of a number of tungsten (W) thin films were carried out using grazing incidence x-ray diffraction, x-ray reflectivity and grazing incidence small-angle x-ray scattering. The W films were prepared by magnetron sputtering in an Ar atmosphere at various pressures and with differen…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchHigh-Temperature Coating Behaviors

Femtosecond Dynamics of Excitons and Hole-Polarons in Composite P3HT/PCBM Nanoparticles

Scott N. Clafton、David M. Huang、William R. Massey 等 4 位作者2013-02-05The Journal of Physical Chemistry B

The dynamics of charge separation in aqueous suspensions of regioregular P3HT nanoparticles containing PCBM were investigated for the first time using femtosecond transient absorption spectroscopy. This investigation is supported by the recently reported use of regioregular P3HT/PCBM nanoparticles as charge trapping a…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Corrosion Behavior of Candidate Materials in Molten LiCl-KCl Salt Under Argon Atmosphere

A. Ravi Shankar、K. Thyagarajan、U. Kamachi Mudali2013-02-05CORROSION

Pyrochemical reprocessing involves the use of molten LiCl-KCl (lithium chloride-potassium chloride) eutectic salt at 773 K for the recovery of uranium and plutonium from spent metallic fuel of fast breeder reactors. The materials selected for such corrosive environments should withstand high temperatures and at the sa…

Metallurgical Processes and ThermodynamicsNuclear Materials and PropertiesMolten salt chemistry and electrochemical processes

Comparative Study on the Performance of Five Different Hall Effect Devices

Maria-Alexandra Pãun、Jean-Michel Sallèse、Maher Kayal2013-02-05Sensors

Five different Hall Effect sensors were modeled and their performance evaluated using a three dimensional simulator. The physical structure of the implemented sensors reproduces a certain technological fabrication process. Hall voltage, absolute, current-related, voltage-related and power-related sensitivities were ob…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Field Sensors Techniques

Pt Band Formation Enhances the Stability of Fuel Cell Membranes

Natalia Macauley、Lida Ghassemzadeh、Chan Lim 等 8 位作者2013-02-05ECS Electrochemistry Letters

Enhancing the durability of fuel cells for the transportation sector requires a better understanding of the fundamental processes that cause degradation. Field-operated PEMFCs have been shown to develop a thin parallel band of Pt inside the membrane. Reports on the effect of the Pt band on membrane durability are cont…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Deactivation Pathways of the Catalytic Activity of Metal–Organic Frameworks in Condensation Reactions

Maksym Opanasenko、Amarajothi Dhakshinamoorthy、Jiřı́ Čejka 等 4 位作者2013-02-05ChemCatChem

Abstract In the present study we have selected three different condensation reactions as model reactions, namely the hydroxylalkylation of anisole by paraformaldehyde to bis(methoxyphenyl)methane, the Pechmann condensation of phenols with ethyl acetoacetate (EAA) to coumarins and the Knoevenagel condensation of two al…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Type II Kinase Inhibitors Show an Unexpected Inhibition Mode against Parkinson’s Disease-Linked LRRK2 Mutant G2019S

Min Liu、Samantha Bender、Gregory D. Cuny 等 6 位作者2013-02-05Biochemistry

A number of well-known type II inhibitors (ATP-noncompetitive) that bind kinases in their DFG-out conformation were tested against wild-type LRRK2 and the most common Parkinson's disease-linked mutation, G2019S. We found that traditional type II inhibitors exhibit surprising variability in their inhibition mechanism b…

Protein Structure and DynamicsParkinson's Disease Mechanisms and TreatmentsEnzyme Structure and Function

Spin- and Angle-Resolved Photoemission of Strongly Spin–Orbit Coupled Systems

Taichi Okuda、A. Kimura2013-02-05Journal of the Physical Society of Japan

In this review article, we present recent studies of peculiar Rashba spin-split energy band structures appearing at surfaces of metallic and semiconducting substances as well as surfaces of topological insulators utilizing state-of-the-art spin- and angle-resolved photoemission spectroscopy. It is shown in this articl…

Quantum and electron transport phenomenaTopological Materials and PhenomenaElectronic and Structural Properties of Oxides

Insight into the Melting Behavior of Au–Pt Core–Shell Nanoparticles from Atomistic Simulations

Rao Huang、Yu‐Hua Wen、Guifang Shao 等 4 位作者2013-02-05The Journal of Physical Chemistry C

Comprehensive understanding of thermodynamic properties of metallic nanoparticles is of significance for their utility in catalysis. In this article, we have employed molecular dynamics simulations with quantum Sutton–Chen many-body potentials to examine the thermal stability of Au–Pt core–shell nanoparticles with dif…

Material Dynamics and PropertiesAdvanced Thermodynamics and Statistical Mechanicsnanoparticles nucleation surface interactions

5,10-Dihydroindolo[3,2-b]indole-Based Copolymers with Alternating Donor and Acceptor Moieties for Organic Photovoltaics

Zbyslaw R. Owczarczyk、Wade A. Braunecker、Andrés Garcia 等 8 位作者2013-02-05Macromolecules

A series of new donor–acceptor π-conjugated copolymers incorporating 5,10-dihydroindolo[3,2- b ]indole (DINI) as an electron donating unit have been designed, synthesized, and explored in bulk heterojunction solar cells with diketopyrrolopyrrole and thienopyrroledione as the electron accepting units. A significant eff…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Incorporation of Aggrecan in Interpenetrating Network Hydrogels to Improve Cellular Performance for Cartilage Tissue Engineering

Ganesh Ingavle、Anthony W. Frei、Stevin H. Gehrke 等 4 位作者2013-02-05Tissue Engineering Part A

Interpenetrating network (IPN) hydrogels were recently introduced to the cartilage tissue engineering literature, with the approach of encapsulating cells in thermally gelling agarose that is then soaked in a poly(ethylene glycol) diacrylate (PEGDA) solution, which is then photopolymerized. These IPNs possess signific…

Osteoarthritis Treatment and MechanismsProteoglycans and glycosaminoglycans researchSilk-based biomaterials and applications

Nanoscale imaging and spontaneous emission control with a single nano-positioned quantum dot

Chad Ropp、Zachary Cummins、Sanghee Nah 等 6 位作者2013-02-05Nature Communications

Plasmonic nanostructures confine light on the nanoscale, enabling ultra-compact optical devices that exhibit strong light–matter interactions. Quantum dots are ideal for probing plasmonic devices because of their nanoscopic size and desirable emission properties. However, probing with single quantum dots has remained…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanowire Synthesis and Applications

Kinetic Study on the Coupling of CO2 and Epoxides Catalyzed by Co(III) Complex with an Inter- or Intramolecular Nucleophilic Cocatalyst

Jie Liu、Wei‐Min Ren、Ye Liu 等 4 位作者2013-02-05Macromolecules

Trivalent cobalt complexes of salicylaldimine in the presence of an inter- or intramolecular nucleophilic cocatalyst have proven to be excellent catalysts for the copolymerization of CO 2 and epoxides to selectively afford the corresponding polycarbonates in perfectly alternating nature. Especially, bifunctional cobal…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts

Mechanism of Bacterial Oligosaccharyltransferase

Sabina Gerber、Christian Lizak、Gaëlle Michaud 等 8 位作者2013-02-05Journal of Biological Chemistry

N-Linked glycosylation is an essential post-translational protein modification in the eukaryotic cell. The initial transfer of an oligosaccharide from a lipid carrier onto asparagine residues within a consensus sequon is catalyzed by oligosaccharyltransferase (OST). The first X-ray structure of a complete bacterial OS…

Genomics and Phylogenetic StudiesGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

PLA/PLGA nanoparticles for delivery of drugs across the blood-brain barrier

Jingyan Li、Cristina M. Sabliov2013-02-05Nanotechnology Reviews

Abstract The blood-brain barrier (BBB), which protects the central nervous system (CNS) from unnecessary substances, is a challenging obstacle in the treatment of CNS disease. Many therapeutic agents such as hydrophilic and macromolecular drugs cannot overcome the BBB. One promising solution is the employment of polym…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsGraphene and Nanomaterials Applications

Numerical solution of an inverse diffraction grating problem from phaseless data

Gang Bao、Peijun Li、Junliang Lv2013-02-05Journal of the Optical Society of America A

This paper is concerned with the numerical solution of an inverse diffraction grating problem, which is to reconstruct a periodic grating profile from measurements of the phaseless diffracted field at a constant height above the grating structure. An efficient continuation method is developed to recover the Fourier co…

Optical measurement and interference techniquesAdvanced Measurement and Metrology TechniquesOptical Coatings and Gratings

A Fast Analysis Method to Quantify Nanoparticle Uptake on A Single Cell Level

Adriano A. Torrano、Julia Blechinger、Christian Osseforth 等 8 位作者2013-02-05Nanomedicine

AIM: This study examines the absolute quantification of particle uptake into cells. METHODS: We developed a novel method to analyze stacks of confocal fluorescence images of single cells interacting with nano-and micro-particles. Particle_in_Cell-3D is a freely available ImageJ macro. During the image analysis routine…

Nanoparticle-Based Drug DeliveryAdvanced Fluorescence Microscopy TechniquesCell Image Analysis Techniques

Silicon-Naphthalo/Phthalocyanine-Hybrid Sensitizer for Efficient Red Response in Dye-Sensitized Solar Cells

Bogyu Lim、George Y. Margulis、Jun‐Ho Yum 等 8 位作者2013-02-05Organic Letters

Introduction of a naphthalocyanine moiety to phthalocyanine allows for a gradual red shift of the absorption spectrum in the resulting chromophore. Using silicon as a core atom allows for the introduction of additional siloxane side chains which mitigate dye aggregation. A dye-sensitized solar cell with this hybrid se…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis

Chemical and structural properties of conducting nanofilaments in TiN/HfO2-based resistive switching structures

P. Calka、E. Martínez、V. Delaye 等 11 位作者2013-02-05Nanotechnology

Structural, chemical and electronic properties of electroforming in the TiN/HfO(2) system are investigated at the nanometre scale. Reversible resistive switching is achieved by biasing the metal oxide using conductive atomic force microscopy. An original method is implemented to localize and investigate the conductive…

Advanced Memory and Neural ComputingElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices