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Clay dispersion effects on excimer laser ablation of polymer–clay nanocomposites

I‐Ta Chang、Erol Sancaktar2013-05-22Journal of Applied Polymer Science

ABSTRACT The ablation behavior of polystyrene‐organically modified montmorillonite (OMMT) nanocomposites was evaluated by measuring the weight loss induced by KrF excimer laser irradiation of the nanocomposite specimens under air atmosphere. The characteristic values of ablation, ablation threshold fluence, and effect…

Diamond and Carbon-based Materials ResearchLaser Material Processing TechniquesPolymer Nanocomposite Synthesis and Irradiation

The Balance between Diffusional and Surface Reaction Kinetic Models: A Theoretical Study

Krzysztof Nieszporek2013-05-22Separation Science and Technology

In this work we considered the factors determining the rate of adsorption. By assuming the balance between the surface reaction and diffusional mechanisms we discussed the possibility to conclude which model is the rate-controlling step. By using the pseudo first-order Lagergren equation we showed the theoretical inte…

Adsorption and biosorption for pollutant removalGraphene research and applicationsnanoparticles nucleation surface interactions

Experimental characterization and computational simulations of the low‐velocity impact behaviour of polypropylene

Juan Pablo Torres、Patricia M. Frontini、L. Aretxabaleta2013-05-22Polymer International

Abstract The objective of this work is to validate predictive models for the simulation of the mechanical response of polypropylene undergoing impact situations. The transferability of material parameters deduced from a particular loading scenario (uniaxial loading) to a different loading situation (multiaxial loading…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

MesoDyn modeling study of the phase morphologies of miktoarm poly(ethylene oxide)‐ b ‐poly(methyl methacrylate) copolymers doped with nanoparticles

Dan Mu、Jian-Quan Li、Shengyu Feng2013-05-22Polymer International

Abstract Earlier studies have shown that poly(ethylene oxide) ( PEO ) and poly(methyl methacrylate) ( PMMA ) blocks are compatible at 270 and 298 K, and that their Flory–Huggins interaction parameters have the same blending ratio dependence at both temperatures. At a much higher temperature (400 K), the behavior of PE…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

Carbonates

Carlos Rodríguez‐Navarro、Encarnación Ruíz-Agudo2013-05-22Mineralogical Society of Great Britain and Ireland eBooks

The first transmission electron microscope (TEM) was built in the 1930s for which the inventor Ernst Ruska received a Nobel prize for Physics in 1986. Since those early years, Mineralogy has played an important role in the development of TEM methods and technology. In the beginning, early specimens included natural sa…

Paleontology and Stratigraphy of FossilsHydrocarbon exploration and reservoir analysisCalcium Carbonate Crystallization and Inhibition

Clays in low-temperature environments

Blanca Bauluz2013-05-22Mineralogical Society of Great Britain and Ireland eBooks

The first transmission electron microscope (TEM) was built in the 1930s for which the inventor Ernst Ruska received a Nobel prize for Physics in 1986. Since those early years, Mineralogy has played an important role in the development of TEM methods and technology. In the beginning, early specimens included natural sa…

Soil and Unsaturated FlowClay minerals and soil interactionsGeotechnical and construction materials studies

Non-stoichiometry, defects and superstructures in sulfide and oxide minerals

F. Langenhorst、Dennis Harries、Kilian Pollok2013-05-22Mineralogical Society of Great Britain and Ireland eBooks

The first transmission electron microscope (TEM) was built in the 1930s for which the inventor Ernst Ruska received a Nobel prize for Physics in 1986. Since those early years, Mineralogy has played an important role in the development of TEM methods and technology. In the beginning, early specimens included natural sa…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsX-ray Diffraction in Crystallography

Scaling behavior of universal pinch-off in two-dimensional foam

Chin-Chang Kuo、Michael Dennin2013-05-22Physical Review E

We study the power-law scaling behavior and pinch-off morphology of two-dimensional bubble rafts under tension. As a function of pulling speed, we observe two distinct pinch-off morphologies that have been observed in other fluid systems: long threads (LT) and double-cone (DC). At any given pulling speed, there is a n…

Computer Graphics and Visualization TechniquesFluid Dynamics and Heat TransferPickering emulsions and particle stabilization

Photodegradation by a Heterogeneous Mixture of Micro‐Sized Anatase and Truncated Rhomboid Anatase Hollow Spheres

Min‐Han Yang、Min‐Chiao Tsai、Yuan‐Wei Chang 等 6 位作者2013-05-22ChemCatChem

Abstract Highly uniform hollow spheres were assembled from truncated rhomboid anatase TiO2 nanoparticles (HS), which were synthesized from the hydrothermal treatment of a NaF solution by using amorphous TiO2 spheres as a precursor and template. The submicron hollow spheres with highly photocatalytic active surfaces ex…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications

Trigonal prismatic bicyclocalixaromatics, synthesis and structures

Li Wang、Lanxi Zheng、Ming‐Liang Ma 等 8 位作者2013-05-22Supramolecular chemistry

Two trigonal prismatic bicyclooxacalixarenes 1 and 2 were obtained by condensation reaction of 1,3,5-tri(p-hydroxyphenyl)benzene and 2,4,6-tri(p-hydroxyphenyl)triazine, respectively, with 1,5-difluoro-2,4-dinitrobenzene. Single crystal structural analysis revealed that the bicyclooxacalixarene 1 adopts a distorted tri…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Humidity sensing of an epoxy/MWCNT composite by electrical conductivity measurements

Heinz C. Neitzert、Andrea Sorrentino、Luigi Vertuccio2013-05-22Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

An epoxy/CNT composite material with a low concentration of multiwall carbon nanotubes (0.5wt%) in a diglycidilether bisphenol-A based epoxy matrix has been shown to be applicable, when maintained at a constant temperature, as humidity sensing element. An almost linear decrease of the electrical conductivity with incr…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Sculpture preparation of crystalline mesoporous carbons from nanoshell-containing carbon

Naokatsu Kannari、Yutaka Nakamura、Jun‐ichi Ozaki2013-05-22Carbon

Crystalline mesoporous carbon was prepared from nanoshell-containing carbon (NSCC) by a sculpturing technique, i.e., the selective oxidation of amorphous carbon moieties (ACM) in NSCC using hydrogen peroxide (H2O2) treatment. The carbon structures of the NSCC and the H2O2-treated NSCC were characterized by transmissio…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

Molecular dynamics simulations of the Hras‐GTP complex and the Hras‐GDP complex

Takeshi Miyakawa、Ryota Morikawa、Masako Takasu 等 8 位作者2013-05-22International Journal of Quantum Chemistry

We study the structures of the Hras‐GTP complex and the Hras‐GDP complex in water to investigate the mechanism of GTP hydrolysis of the Hras‐GTP complex. We performed molecular dynamics simulations of these complexes to investigate the structures of these complexes using the potential parameters of AMBER ff03 and our…

Ion Transport and Channel RegulationEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Properties of a Graphene Oxide-Balofloxacin Composite and Its Effect on Bacteriostasis

Fuqin Li、Chuanxiao Yang、Bin Liu 等 4 位作者2013-05-22Analytical Letters

A novel graphene oxide-balofloxacin nanocomposite was synthesized, and the loading and release behavior of fluorescent antibacterial balofloxacin on graphene oxide was investigated. The surface morphologies of the nanocomposite were evaluated using transmission electron microscopy and fluorescence microscopy, and the…

Nanoparticle-Based Drug DeliveryPharmacological Effects and Toxicity StudiesGraphene and Nanomaterials Applications

Effects of OH radicals and the silicon network on the lifetime of Eu^3+-doped sodium silicate glasses

Rodrigo Ferreira de Morais、Elias Oliveira Serqueira、Noélio O. Dantas2013-05-22Optical Materials Express

A set of sodium silicate glass matrices were synthesized to study the influence of Na2O concentration on the optical properties of Eu3+. The samples were characterized by optical absorption (OA), time and energy resolved photoluminescence and Fourier Transform Infrared (FTIR). We observed that decreasing sodium oxide…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhotorefractive and Nonlinear Optics

Morphological control of porous ethylene‐vinyl acetate copolymer membrane obtained from a co‐continuous ethylene‐vinyl acetate copolymer/poly(ϵ‐caprolactone) blend

Defeng Wu、Jie Zhang、Weidong Zhou 等 7 位作者2013-05-22Polymer International

Abstract Ethylene‐vinyl acetate copolymer ( EVA )/poly(ϵ‐caprolactone) ( PCL ) blend (50/50 w/w) with co‐continuous morphology was prepared via melt mixing for fabricating microporous EVA membrane materials through selective solvent extraction. Shear flow and quiescent annealing techniques were employed to control co‐…

Advanced Polymer Synthesis and CharacterizationMembrane Separation and Gas TransportBlock Copolymer Self-Assembly

Facile one‐pot method of initiator fixation for surface‐initiated atom transfer radical polymerization on carbon hard spheres

Muhammad Ejaz、Bhanukiran Sunkara、Lakhinder Kamboj 等 7 位作者2013-05-22Journal of Polymer Science Part A Polymer Chemistry

ABSTRACT An efficient and novel one‐pot process is developed to immobilize the atom transfer radical polymerization (ATRP) initiators onto the surface of fully pyrolyzed carbon hard spheres (CHSs) via a radical trapping process from the in situ thermal decomposition of bis(bromomethylbenzoyl)peroxide. The CHSs do not…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Surface Interaction Studies

Dynamics of acetone photooxidation on TiO2(110): State-resolved measurements of methyl photoproducts

Matthew D. Kershis、Daniel Wilson、Michael G. White2013-05-22The Journal of Chemical Physics

State-resolved laser techniques were used to study the internal state distributions of gas phase methyl radicals which are produced during the photooxidation of acetone on TiO2(110). This approach was used as a means of understanding the nature of the bimodal kinetic energy distributions for these radicals. Specifical…

TiO2 Photocatalysis and Solar CellsAtmospheric chemistry and aerosolsCatalytic Processes in Materials Science

The use of nitriding to enhance wear resistance of cast irons

Zaidao Yang、D. O. Northwood、Xian Ping Sun 等 6 位作者2013-05-22WIT transactions on engineering sciences

This research is focused on using nitriding to enhance the wear resistance of austempered ductile iron (ADI), ductile iron (DI), and gray iron (GI). Three gas nitriding processes, namely "Gas nitriding + nitrogen cooled down to 800 o F" (Blue), "Gas nitriding + cooled down to 300 o F" (Gray), and "Gas nitriding + oil…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchMetal Alloys Wear and Properties

Sustainability of nuclear energy with regard to decommissioning and waste management

Staffan Lindskog、Bea Labor、Rolf Sjöblom2013-05-22International Journal of Sustainable Development and Planning

Sustainability aspects of nuclear power are analysed with regard to such environmental liabilities that are associated with decommissioning of nuclear facilities and with nuclear waste management. Sustainability is defi ned and evaluated based on information searches that also include energy from combustion of coal. I…

Risk Perception and ManagementGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies