Materials Literature
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Herein we describe the surface modification of gold nanorods via the postpolymerization immobilization of polymers prepared by reversible addition−fragmentation chain transfer (RAFT). Gold nanorods have been synthesized via a three-step seed-mediated process and then subsequently modified with RAFT-preformed poly(2-(d…
Electrospinning has recently emerged as a leading technique for the formation of nanofibrous structures made of synthetic and natural extracellular matrix components. In this study, nanofibrous scaffolds were obtained by electrospinning a combination of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and type-I co…
We present a photolithographic route to form colloidal particles of uniform size and nonspherical shape. We demonstrate the induction of tunable, shape-selective interactions among these particles based on depletion, van der Waals, and electrostatic forces in aqueous dispersions. Under appropriate conditions, the part…
Following excitation in the range 370-405 nm, the emission spectrum of a cell permeable macrocyclic Eu(III) complex incorporating an N-methylsulfonamide moiety changes form with pH, allowing ratiometric pH measurements in the range 6 to 8.
Interpenetrating polymer networks (IPNs) were prepared by the modification of a segmented polyurethane (SPU) with a cross-linked sulfobetaine methacrylate (SBMA) polymer. The IPN films that were prepared can effectively resist nonspecific protein adsorption when the distribution of SBMA units within the SPU film is we…
We employ the density functional theory to study a structural transition of MnO from B1 (rocksalt) to B8 (NiAs) structures that was observed experimentally at pressures around 100 GPa. We utilize all-electron description as well as norm-conserving pseudopotentials and demonstrate that these two approaches can signific…
Abstract Polyols synthesized by ozonolysis and hydrogenation from canola oil were reacted with aliphatic 1,6‐hexamethylene diisocyanates (HDI) to produce polyurethane (PU) elastomers. The properties of the materials were examined by dynamic mechanical analysis (DMA), thermomechanical analysis (TMA), modulated differen…
Poly(L-lactic acid)/hydroxyapatite hybrid nanofibrous scaffolds were prepared via electrospinning. The structure and morphology of the scaffolds were investigated using scanning electron microscopy, differential scanning calorimetry and Fourier transform infrared spectroscopy. The experimental results showed that the…
Novel flowerlike nanostructures consisting of Cu 2 O nanopetals were successfully synthesized by a facile wet chemical method for the first time. The synthesized products were systematically studied by X-ray powder diffraction, scanning electron microscopy, and transmission electron microscopy. The results showed that…
Alloy disorder in II-VI diluted magnetic semiconductors (DMS) is typically reduced when the local magnetic spins align in an applied magnetic field. An important and untested expectation of current models of alloy disorder, however, is that alloy fluctuations in many DMS compounds should increase again in very large m…
Electron spin decoherence caused by elastic spin-phonon processes is investigated comprehensively in a zero-dimensional environment. Specifically, a theoretical treatment is developed for the processes associated with the fluctuations in the phonon potential as well as in the electron procession frequency through the…
We present a comprehensive study relating the nanostructure of ${\mathrm{Ge}}_{0.95}{\mathrm{Mn}}_{0.05}$ films to their magnetic properties. The formation of ferromagnetic nanometer-sized inclusions in a defect-free Ge matrix fabricated by low-temperature molecular beam epitaxy is observed down to substrate temperatu…
This work verifies the applicability of two‐stage sintering as a means of suppressing the final stage grain growth of submicrometer alumina. The first heating step should be short at a relatively high‐temperature (1400°–1450°C) in order to close porosity without significant grain growth. The second step at temperature…
Iijima's observation in 1991 of fullerene-like materials by high-resolution transmission electron microscopy heralded the beginning of the carbon nanotube (CNT) era. A wealth of theoretical predictions and experimental verifications about CNTs have disclosed remarkable size- and structure-dependent properties that are…
Ring-contracted porphyrins: meso-Aryl subporphyrins were synthesized by using a method in which tripyrrolylborane acts as a template for the Adler method. This study demonstrates that, although the subporphyrins retain porphyrinic properties, ring contraction has a significant impact on the electronic structure. The p…
In this paper, we report the development of rod-shaped semiconductor nanocrystals (quantum rods) as fluorescent biological labels. Water-soluble biocompatible quantum rods have been prepared by surface silanization and applied for nonspecific cell tracking as well as specific cellular targeting. Quantum rods are brigh…
The atomic and electronic structure of a set of pristine single wall SiC nanotubes as well as Si-substituted carbon nanotubes and a SiC sheet was studied by the local-density approximation (LDA) plane wave band structure calculations. Consecutive substitution of carbon atoms by Si leads to a gap opening in the energet…
A history is given of the applications of the simple expression generalized from the surmise by Wigner and also by Ibach to extract the strength of the interaction between steps on a vicinal surface, via the terrace width distribution (TWD). A concise guide for use with experiments and a summary of some recent extensi…
The switching probability of a single-domain ferromagnet under spin-current excitation is evaluated using the Fokker-Planck equation(FPE). In the case of uniaxial anisotropy, the FPE reduces to an ordinary differential equation in which the lowest eigenvalue $λ_1$ determines the slowest switching events. We have calcu…
The band gaps, longitudinal and transverse effective masses, and deformation potentials of ScN in the rock-salt structure have been calculated employing ${G}_{0}{W}_{0}$-quasiparticle calculations using exact-exchange Kohn-Sham density-functional theory one-particle wave functions and energies as input. Our quasiparti…