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Novel high birefringent isothiocyanates based on quaterphenyl and phenylethynyltolane molecular cores

Jakub Herman、Jerzy Dziaduszek、R. Dąbrowski 等 8 位作者2013-06-18Liquid Crystals

We report the synthesis of new laterally alkyl substituted high birefringent quaterphenyl and phenylethynyltolane liquid crystals with isothiocyanate terminal group. The thermal and optical properties such as birefringence are measured and discussed based on their molecular structures. The compounds exhibit birefringe…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsNonlinear Optical Materials Research

Enhancement of the Mechanical Properties of Basalt Fiber-Wood-Plastic Composites via Maleic Anhydride Grafted High-Density Polyethylene (MAPE) Addition

Jinxiang Chen、Yong Wang、Chenglong Gu 等 7 位作者2013-06-18Materials

This study investigated the mechanisms, using microscopy and strength testing approaches, by which the addition of maleic anhydride grafted high-density polyethylene (MAPE) enhances the mechanical properties of basalt fiber-wood-plastic composites (BF-WPCs). The maximum values of the specific tensile and flexural stre…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Enhanced x-ray detection sensitivity in semiconducting polymer diodes containing metallic nanoparticles

C. A. Mills、Hulayel Al-Otaibi、Akarin Intaniwet 等 7 位作者2013-06-18Journal of Physics D Applied Physics

Semiconducting polymer X-radiation detectors are a completely new family of low-cost radiation detectors with potential application as beam monitors or dosimeters. These detectors are easy to process, mechanically flexible, relatively inexpensive, and able to cover large areas. However, their x-ray photocurrents are t…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesPolymer Nanocomposite Synthesis and Irradiation

Reducing the Cytotoxity of Poly(amidoamine) Dendrimers by Modification of a Single Layer of Carboxybetaine

Longgang Wang、Zhen Wang、Guanglong Ma 等 5 位作者2013-06-18Langmuir

The surface primary amines of generation five poly(amido amine) (G5 PAMAM) dendrimer were modified by different amounts of carboxybetaine acrylamide (CBAA). As a result, the fully modified molecules (CBAA-PAMAM-20, obtained from the 20:1 molar ratio of CBAA molecules to amino groups in modification solution) show exce…

RNA Interference and Gene DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Symmetry Lowering in Extreme-Electron-Density Perovskite Quantum Wells

Jack Zhang、Jinwoo Hwang、Santosh Raghavan 等 4 位作者2013-06-18Physical Review Letters

We report on structural distortions in extreme-electron density ($\ensuremath{\sim}6\ifmmode\times\else\texttimes\fi{}{10}^{14}\text{ }\text{ }{\mathrm{cm}}^{\ensuremath{-}2}$) confined quantum wells of ${\mathrm{SrTiO}}_{3}$ embedded in ${\mathrm{GdTiO}}_{3}$. Sr-column displacements are measured using high-angle ann…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Room-Temperature Ferromagnetism in Reduced Rutile TiO2−δ Nanoparticles

M. Parras、Áurea Varela、Raquel Cortés‐Gil 等 6 位作者2013-06-18The Journal of Physical Chemistry Letters

We report a synthesis method to stabilize TiO 2 rutile nanoparticles (around 10 nm) and keep the particle size when reduced down to TiO 1.84 . TiO 2−δ nanoparticles exhibit room-temperature ferromagnetism that becomes stronger for TiO 1.84 . The reduction mechanism to stabilize Magneli phases excludes a relevant influ…

ZnO doping and propertiesCatalytic Processes in Materials ScienceCopper-based nanomaterials and applications

The Hanes‐Woolf linear QUESP method improves the measurements of fast chemical exchange rates with CEST MRI

Edward A. Randtke、Liu Qi Chen、L. René Corrales 等 4 位作者2013-06-18Magnetic Resonance in Medicine

PURPOSE: Contrast agents for chemical exchange saturation transfer MRI often require an accurate measurement of the chemical exchange rate. Many analysis methods have been reported that measure chemical exchange rates. Additional analysis methods were derived as part of this study. This report investigated the accurac…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesAtomic and Subatomic Physics Research

Effect of Strongly Alkaline Electrolyzed Water on Silk Degumming and the Physical Properties of the Fibroin Fiber

Tingting Cao、Yuanjing Wang、Yu‐Qing Zhang2013-06-18PLoS ONE

Strongly alkaline electrolyzed water (SAEW) was prepared by electrolysis of tap water in a laboratory-made water electrolyzer. The pH of stored SAEW was stable for more than one month. The hardness of the electrolyzed water was 30% lower and the Na(+) concentration was 18% higher than those of the tap water. Silkworm…

Insect and Arachnid Ecology and BehaviorSilk-based biomaterials and applicationsSilkworms and Sericulture Research

Humidity-dependent friction mechanism in an ultrananocrystalline diamond film

N. Kumar、Radhika Ramadoss、A. T. Kozakov 等 8 位作者2013-06-18Journal of Physics D Applied Physics

Friction behaviour of an ultrananocrystalline diamond film deposited by the microwave plasma-enhanced chemical vapour deposition technique is studied in a controlled humid atmosphere. The value of friction coefficient consistently decreases while increasing the humidity level during the tribology test. This value is 0…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Quantification of Nanoparticle Dose and Vesicular Inheritance in Proliferating Cells

Huw D. Summers、M. Rowan Brown、Mark D. Holton 等 8 位作者2013-06-18ACS Nano

Assessing dose in nanoparticle-cell interactions is inherently difficult due to a complex multiplicity of possible mechanisms and metrics controlling particle uptake. The fundamental unit of nanoparticle dose is the number of particles internalized per cell; we show that this can be obtained for large cell populations…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Observation of Ferromagnetic Exchange, Spin Crossover, Reductively Induced Oxidation, and Field-Induced Slow Magnetic Relaxation in Monomeric Cobalt Nitroxides

Ian A. Gass、Subrata Tewary、Ayman Nafady 等 13 位作者2013-06-18Inorganic Chemistry

The reaction of [Co(II)(NO3)2]·6H2O with the nitroxide radical, 4-dimethyl-2,2-di(2-pyridyl) oxazolidine-N-oxide (L(•)), produces the mononuclear transition-metal complex [Co(II)(L(•))2](NO3)2 (1), which has been investigated using temperature-dependent magnetic susceptibility, electron paramagnetic resonance (EPR) sp…

Magnetic and transport properties of perovskites and related materialsMagnetism in coordination complexesAdvanced Condensed Matter Physics

Room‐Temperature Tunneling Behavior of Boron Nitride Nanotubes Functionalized with Gold Quantum Dots

Chee Huei Lee、Shengyong Qin、Madhusudan A. Savaikar 等 12 位作者2013-06-18Advanced Materials

One-dimensional arrays of gold quantum dots (QDs) on insulating boron nitride nanotubes (BNNTs) can form conduction channels of tunneling field-effect transistors. We demonstrate that tunneling currents can be modulated at room temperature by tuning the lengths of QD-BNNTs and the gate potentials. Our discovery will i…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Intense white light emission in Tm3+/Er3+/Yb3+ co-doped Y2O3–ZnO nano-composite

Ram Sagar Yadav、Rajesh Verma、Shivam Kumar B2013-06-18Journal of Physics D Applied Physics

The Tm 3+ /Er 3+ /Yb 3+ co-doped Y 2 O 3 –ZnO nano-composite is synthesized using the solution combustion technique. The structural morphology is monitored using x-ray diffraction, transmission electron microscopy and scanning electron microscopy. The Yb 3+ /Tm 3+ co-doped nano-phosphor emits intense blue as well as w…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesLuminescence and Fluorescent Materials

Using the Polymeric Ouzo Effect for the Preparation of Polysaccharide-Based Nanoparticles

Eugen M. Aschenbrenner、Karina Bley、Kaloian Koynov 等 7 位作者2013-06-18Langmuir

The polymeric ouzo effect, a nanoprecipitation process, is used for the preparation of polysaccharide-based nanoparticles. Dextran, pullulan, and starch were esterified with hydrophobic carboxylic acid anhydrides to obtain hydrophobic polysaccharides, which are insoluble in water. The additional introduction of methac…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesElectrowetting and Microfluidic Technologies

Hydrogen Kinetics on Scalable Graphene Growth by Atmospheric Pressure Chemical Vapor Deposition with Acetylene

Mei Qi、Zhaoyu Ren、Yang Jiao 等 9 位作者2013-06-18The Journal of Physical Chemistry C

Acetylene (C 2 H 2 ) and copper foil have been chosen as carbon precursor and catalyst, respectively, for the synthesis of graphene by atmospheric pressure chemical vapor deposition. The effects of hydrogen (H 2 ) concentration on graphene growth have been studied by Raman spectroscopy and transmission electron micros…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

Synthesis and Characterization of Magnetoelectric Nanomaterial Composed of Fe3O4 and Polyindole

M. T. Ramesan2013-06-18Advances in Polymer Technology

ABSTRACT Magnetoelectric polymer nanocomposite is synthesized using conducting polyindole and nano‐sized magnetite (Fe3O4) particles through the in situ polymerization method. The effect of nanoparticles content on the polyindole matrix is studied by Fourier transform infrared (FTIR) and ultraviolet (UV) spectroscopy,…

Conducting polymers and applicationsMultiferroics and related materialsElectromagnetic wave absorption materials

Avoided Quantum Criticality and Magnetoelastic Coupling in BaFe 2 − x Ni x As 2

Xingye Lu、H. Gretarsson、Rui Zhang 等 12 位作者2013-06-18Physical Review Letters

We study the structural and magnetic orders in electron-doped ${\mathrm{BaFe}}_{2\ensuremath{-}x}{\mathrm{Ni}}_{x}{\mathrm{As}}_{2}$ by high-resolution synchrotron x-ray and neutron scatterings. Upon Ni doping $x$, the nearly simultaneous tetragonal-to-orthorhombic structural (${T}_{s}$) and antiferromagnetic (${T}_{N…

Amyloidosis: Diagnosis, Treatment, OutcomesCorporate Taxation and AvoidanceIron-based superconductors research

Modification of Mott Phase Transition Characteristics in VO2@TiO2 Core/Shell Nanostructures by Misfit-Strained Heteroepitaxy

Yamei Li、Shidong Ji、Yanfeng Gao 等 5 位作者2013-06-18ACS Applied Materials & Interfaces

Vanadium dioxide (VO2) is a key material for thermochromic smart windows that can respond to environmental temperature and modulate near-infrared irradiation by changing from a transparent state at low temperature to a more reflective state at high temperature, while maintaining visible transmittance. Here, we demonst…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

One-Pot Controllable Synthesis of Au@Ag Heterogeneous Nanorods with Highly Tunable Plasmonic Absorption

Cuncheng Li、Lin Sun、Yiqiang Sun 等 4 位作者2013-06-18Chemistry of Materials

It generally requires a complex workup procedure for the fabrication of Au@Ag heterogeneous nanostructures with an accurate morphology by the present multistep seed-mediated growth approaches. In this paper, we present a new and straightforward method for the controllable synthesis of uniform Au@Ag heterogeneous nanor…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Graft Copolymers from Natural Polymers Using Free Radical Polymerization

Vijay Kumar Thakur、Manju Kumari Thakur、Raju Kumar Gupta2013-06-18International Journal of Polymer Analysis and Characterization

The present research work deals with the surface modification of natural cellulosic polymers to develop novel materials for different applications. Natural cellulose-graft-poly (methyl acrylate) copolymers were prepared using the free radical induced graft copolymerization technique. Different reaction parameters were…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer Nanocomposite Synthesis and Irradiation