Materials Literature
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Two new heterometallic cubane molecules have been synthesized. High-frequency electron paramagnetic resonance and magnetization measurements indicate that [Mn(3)Ni(hmp)(3)O(N(3))(3)(C(7)H(5)O(2))(3)] (1) displays a well-isolated S = 5 ground state (DeltaE > 120 K), with g = 2.0, D = -0.23 cm(-1), and ferromagnetic Mn-…
Mixed-valent Mn/O dinuclear and polynuclear molecular compounds containing MnIII are almost without exception trapped valence. Large differences between the strengths of the exchange interactions within MnIIMnIII, MnIIIMnIII and MnIIIMnIV pairs lead to situations where MnIIIMnIV interactions, the strongest of the thre…
Cobalt-substituted manganese oxide one-dimensional (1D) nanowires have been synthesized through one-pot hydrothermal treatment of the ion pair solution of Co 2+ and MnO 4 -, along with their three-dimensional (3D) hierarchically assembled microspheres. The stabilization of cobalt ion in the manganese sites of α- and δ…
Reaction between CdX2 and 1-alkyl-2-(phenylazo)imidazole (RaaiR') has isolated complexes of composition Cd(RaaiR')2X2 in MeOH or MeCN. Crystallization of Cd(RaaiR')2I2 from N,N-dimethylformamide (DMF) has separated [Cd(RaaiR')I2.DMF], while Cd(RaaiR')2X2 (X = Cl and Br) remains unchanged in its composition upon crysta…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTPolyaniline Hierarchical Structures Synthesized in Aqueous Solution: Micromats of NanofibersChuanqiang Zhou, Jie Han, Genping Song, and Rong GuoView Author Information School of Chemistry and Chemical Engineering, Yangzhou Universit…
The effect of accidental drops on MEMS sensors are examined within the frame-work of a multi-scale finite element approach. With specific reference to a polysilicon MEMSaccelerometer supported by a naked die, the analysis is decoupled into macro-scale (at dielength-scale) and meso-scale (at MEMS length-scale) simulati…
We report the directed assembly of single-walled carbon nanotubes (SWCNTs) at lithographically defined positions on gate oxide surfaces, allowing for the high yield ( approximately 90%) and parallel fabrication of SWCNT device arrays. SWCNTs were first chemically functionalized through diazonium chemistry with a hydro…
For a large class of fluids exhibiting ultrasoft bounded pair potentials, particles form crystals consisting of clusters located in the lattice sites, with a density-independent lattice constant. Here we present an investigation on the dynamic features of a representative example of this class. It is found that partic…
The in-plane thermal conductivity kappa of the layered superconductor CuxTiSe2 was measured down to temperatures as low as Tc/40, at x=0.06 near where the charge-density-wave order vanishes. The absence of a residual linear term at T-->0 is strong evidence for conventional s-wave superconductivity in this system. This…
Like fluorescence sensing techniques, methods to manipulate proteins with light have produced great advances in recent years. Ion channels have been one of the principal protein targets of photoswitched manipulation. In combination with fluorescence detection of cell signaling, this has enabled non-invasive, all-optic…
Transition metal oxides, such as the mixed-valent rare-earth manganites Ln(1-x)AxMnO3 (Ln, rare-earth ion, and A, alkaline-earth ion), show a variety of electronic orders with spatially correlated charge, spin and orbital arrangements, which in turn give rise to many fascinating phenomena and properties. These materia…
The thermal conductivity of the amorphous phase of polyamide-6,6 is investigated by nonequilibrium molecular dynamics simulations. Two different algorithms are used, reverse nonequilibrium molecular dynamics and the dual-thermostat method. Particular attention is paid to the force field used. Four different models are…
Sodium−niobium borophosphate glasses have been thermally poled and studied in the mid- and far-infrared range to probe their possible structural rearrangements and to correlate them with the measured nonlinear optical (NLO) response. The infrared analysis of thermally poled and depoled glasses has revealed systematic…
We performed small-angle X-ray scattering (SAXS) measurements on crystallization processes of polyethylene blends of low molecular weight and ultrahigh molecular weight components with various blending ratios in order to clarify effects of ultrahigh molecular component on shish-kebab structure formation. Anisotropic s…
Planar honeycomb-like coordination network {[Ni(cyclam)]3[W(CN)8]2}n (cyclam = 1,4,8,11-tetraazacyclotetradecane) was obtained in the self-assembly reaction of [Ni(cyclam)]2+ and [W(CN)]83-. Its structure is characterized by void channels along the a axis. The compound shows reversible water adsorption in the temperat…
Reactive impingement mixing was employed to produce polymer-protected nanoparticles. Amphiphilic block copolymer was formed in situ by reactive coupling of hydrophobic and hydrophilic blocks. Simultaneously, a hydrophobic compound and the copolymer coprecipitated to form nanoparticles in the range of 100 nm. Specifica…
Abstract A novel flame retardant (DVN) containing silicon, phosphorus, and nitrogen has been synthesized from the reaction of 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO), vinylmethyldimethoxy silane (VMDMS) and N ‐β‐(aminoethyl)‐γ‐aminopropyle methyl dimethoxy silane (NMDMS), then incorporated into polyc…
Since the publication of the bestselling first edition, there have been numerous advances in the field of nuclear science. In medicine, accelerator based teletherapy and electron-beam therapy have become standard. New demands in national security have stimulated major advances in nuclear instrumentation.An ideal intro…
Rate constants for acid-catalyzed butanol dehydration on Keggin-type polyoxometalate clusters H8−nXn+W12O40 (X=P, Si, Al, Co) increase as the oxidation state of the central atom increases and the number of cluster protons concurrently decreases (see diagram). These trends reflect the lower deprotonation enthalpies of…
X-ray absorption fine structure (XAFS) is used to determine the structure of the rhodium cluster present during the catalyzed dehydrocoupling of amine boranes under operando conditions. We show how a variety of XAFS strategies can be used in combination with other analytical methods to differentiate homogeneous from h…