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Synthesis of New Thiophene‐Substituted 3,3‐Diphenyl‐3H‐naphtho[2,1‐b]pyrans by Cross‐Coupling Reactions, Precursors of Photomodulated Materials

Michel Frigoli、Corinne Moustrou、André Samat 等 4 位作者2003-07-15European Journal of Organic Chemistry

Abstract 3,3‐Diphenyl‐3 H ‐naphtho[2,1‐ b ]pyrans linked to one, two, or three thiophene nuclei in different positions of the naphthalene moiety (5, 6, 8, and 9) by a covalent bond have been prepared in good yields. A Suzuki cross‐coupling reaction was used with two possible strategies: chromenization before the coupl…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistryOxidative Organic Chemistry Reactions

((PS)nPS)m Star-Shaped Polystyrene with Star-Shaped Branches at the Terminal Chain Ends by Convergent Living Anionic Polymerization

Daniel M. Knauss、Tianzi Huang2003-07-15Macromolecules

Radially linked star- block -linear polystyrenes, star-shaped polymers with star-shaped branching at the ends of each arm, were synthesized by the convergent living anionic polymerization method. These novel structurally modified polymers were synthesized by sequential addition of a specific coupling agent, 4-(chlorod…

Advanced Polymer Synthesis and CharacterizationFuel Cells and Related MaterialsDendrimers and Hyperbranched Polymers

Nanoscale solid-state quantum computing

Arzhang Ardavan、M. Austwick、Simon C. Benjamin 等 22 位作者2003-07-15Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

Most experts agree that it is too early to say how quantum computers will eventually be built, and several nanoscale solid-state schemes are being implemented in a range of materials. Nanofabricated quantum dots can be made in designer configurations, with established technology for controlling interactions and for re…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Photoemission Study of Mixed-Valent Tm-monochalcogenides: Evidence of Electron-Correlation Effect in Different Tm-Core Levels

Krishna G. Nath、Y. Ufuktepe、Shin‐ichi Kimura 等 9 位作者2003-07-15Journal of the Physical Society of Japan

Systematic results of the photoemission spectra for different core levels such as, Tm 4 p , 5 p and 3 d in the mixed valent Tm-monochalcogenides (TmS, TmSe and TmTe) obtained by both experimentally and theoretically are reported. The effects of the electron–electron correlation due to the interaction between core-hole…

Advanced Chemical Physics StudiesIron-based superconductors researchInorganic Chemistry and Materials

X-ray Diffraction Study of Short-range Order and Long-range Ordered Structure in Cu–87.5 at.% Pt Alloy

Dilip Kumar Saha、Toetsu Shishido、Hiroshi Iwasaki 等 4 位作者2003-07-15Journal of the Physical Society of Japan

X-ray diffraction study was performed for the atomic arrangements in Pt-rich (87.5 at.%) Cu–Pt alloy with the cubic structure both in the disordered and ordered states using single crystal samples. In the disordered state obtained by quenching from temperatures above 800°C, short-range order (SRO) diffuse scattering i…

Intermetallics and Advanced Alloy PropertiesAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Effect of silane monomer on the improvement of mechanical and degradable properties of photografted jute yarn with acrylamide

M. Masudul Hassan、M. Rabiul Islam、Moyeenuddin Ahmad Sawpan 等 4 位作者2003-07-15Journal of Applied Polymer Science

Abstract UV radiation was used to graft acrylamide (AA) to jute yarn in order to improve the mechanical properties. The physicomechanical properties of the grafted jute yarn were investigated. A series of solutions of different AA concentrations in methanol along with photoinitiator (Irgacure‐907, 2%) were prepared. T…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesTextile materials and evaluations

Phthalimides: Supramolecular Interactions in Crystals, Hypersensitive Solution 1H-NMR Dynamics and Energy Transfer to Europium(III) and Terbium(III) States

Robertha C. Howell、Selvin H. Edwards、A.S. Gajadhar-Plummer 等 8 位作者2003-07-15Molecules

Detailed crystal structures and 1H-NMR characteristics of some alkylaminephthalimides, including dendritic polyphthalimides, are reported. These investigations were undertaken in order to obtain a better understanding of the relationship between solid-state supramolecular interactions, their persistence in solution an…

Supramolecular Chemistry and ComplexesLanthanide and Transition Metal ComplexesCoordination Chemistry and Organometallics

Physical and Barrier Properties of Plasma-Enhanced Chemical Vapor Deposited α-SiC:H Films from Trimethylsilane and Tetramethylsilane

Chiu-Chih Chiang、Mao‐Chieh Chen、Chung-Chi Ko 等 6 位作者2003-07-15Japanese Journal of Applied Physics

Physical and Barrier Properties of Plasma-Enhanced Chemical Vapor Deposited α-SiC:H Films from Trimethylsilane and Tetramethylsilane, Chiang, Chiu-Chih, Chen, Mao-Chieh, Ko, Chung-Chi, Wu, Zhen-Cheng, Jang, Syun-Ming, Liang, Mong-Song

Advanced ceramic materials synthesisSilicon Carbide Semiconductor TechnologiesCopper Interconnects and Reliability

Dimensional Crossover and Charge Order in Half-Doped Manganites and Cobaltites

Oron Zachar、Igor Zaliznyak2003-07-15Physical Review Letters

We propose a generic model for understanding the effect of quenched disorder on charge-ordering in half-doped manganese and cobalt oxides with different crystal structures. Current experimental observations are explained in the light of the global phase diagram of the model.

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Self-Organized Periodic Photonic Structure in a Nonchiral Liquid Crystal

Lizhen Ruan、J. R. Sambles、Iain W. Stewart2003-07-15Physical Review Letters

A hybrid-aligned cell of the smectic A liquid material 8CB gives two stable director configurations, one of which is periodic and gives strong diffraction of light. This photonic lattice director profile arises from "frustration" caused by conflicting constraints imposed by the boundary conditions and the constant amp…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsMolecular spectroscopy and chirality

Liquid crystal behavior of the Kihara fluid

Alejandro Cuetos、Bruno Martı́nez−Haya、S. Lago 等 4 位作者2003-07-15Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The liquid crystal phases of the Kihara fluid have been studied in computer simulations. The work focuses on the isotropic-nematic-smectic-A triple point region, especially relevant for the understanding of the properties and the design of real mesogens with specific phase diagrams. The Kihara interaction resembles mo…

Liquid Crystal Research AdvancementsPhase Equilibria and ThermodynamicsMaterial Dynamics and Properties

Crystal Structure of Form II of Isotactic Poly(4-methyl-1-pentene)

Claudio De Rosa2003-07-15Macromolecules

The crystal structure of form II of isotactic poly(4-methyl-1-pentene) is presented. Samples of isotactic poly(4-methyl-1-pentene) in the pure form II have been obtained by crystallization from tetramethyltin solutions. The crystal structure has been determined by using X-ray powder diffraction data and packing energy…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Effective-Mass Theory of Electron Correlations in Band Structure of Semiconducting Carbon Nanotubes

Hideaki Sakai、Hidekatsu Suzuura、Tsuneya Ando2003-07-15Journal of the Physical Society of Japan

The band gap, the single-particle energy, and the effective mass are calculated for semiconducting carbon nanotubes in a random-phase approximation within a k · p scheme. The energy gaps are shown to be strongly enhanced due to the Coulomb interaction, while effects on the effective mass along the axis direction are s…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Linear Electrooptic Properties of Pb(Mg1/3Nb2/3)O3–PbTiO3Single Crystals at Compositions Near the Morphotropic Phase Boundary

Dae‐Yong Jeong、Lu Yu、Varun Sharma 等 5 位作者2003-07-15Japanese Journal of Applied Physics

The linear electrooptic coefficients of Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 (PMN–PT) single crystals in the rhombohedral and tetragonal phases were characterized at a wavelength of 632.8 nm. Large electrooptic responses were observed. The tetragonal 0.62PMN–0.38PT single crystals poled along the <001> direction (the sponta…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Evidence for Spin Coating Electrostatic Self-Assembly of Polyelectrolytes

Seung-Sub Lee、Ki Bong Lee、Jong‐Dal Hong2003-07-15Langmuir

The influence of molecular mass on the formation of polyelectrolyte multilayers on an oppositely charged surface of a rotating substrate was explored for a combination of strong cationic and anionic polyelectrolytes, such as poly(1-( N -benzylpyridinio-2-yl)ethylene bromide) (PVP-2B) and ι-carrageenan. UV/visible spec…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Effect of thermal aging on the biodegradation of PCL, PHB‐V, and their blends with starch in soil compost

Derval dos Santos Rosa、Túlio César Rodrigues、Cristina das Graças Fassina Guedes 等 4 位作者2003-07-15Journal of Applied Polymer Science

Abstract Different proportions of starch were blended with poly(β‐hydroxybutyrate)‐ co ‐poly(β‐hydroxyvalerate) (PHB‐V) or poly(ε‐caprolactone) (PCL) by extrusion, and the mechanical (maximum tensile strength, elongation at break and Young's modulus) and thermal properties (by differential scanning calorimetry) were d…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

High-Quality Double-Walled Carbon Nanotube Super Bundles Grown in a Hydrogen-Free Atmosphere

Houjin Huang、Hisashi Kajiura、Shigemitsu Tsutsui 等 5 位作者2003-07-15The Journal of Physical Chemistry B

High-quality double-walled carbon nanotube (DWNT) super bundles were selectively grown above a bowl-like cathode by arc discharge in a hydrogen-free atmosphere. These DWNTs can resist high-temperature (up to 720 °C) oxidation in air without additional annealing even after acid treatment, which is due to an in-situ def…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Residual Stress Effect on Self-Annealing of Electroplated Copper

Changhee Lee、Chong-Ook Park2003-07-15Japanese Journal of Applied Physics

The remarkable feature of electroplated film was grain growth at room temperature and this phenomenon was named `self-annealing'. The driving force of self-annealing was expected as highly increased defect and surface energy, but the exact mechanism was unknown. In this work, residual stress effect on self-annealing w…

Metal and Thin Film MechanicsElectronic Packaging and Soldering TechnologiesCopper Interconnects and Reliability

Paracrystalline Lattice Distortion in the Near-Surface Region of Melt-Crystallized Polyethylene Films Evaluated by Synchrotron-Sourced Grazing-Incidence X-ray Diffraction

Hirohiko Yakabe、Sono Sasaki、Osami Sakata 等 5 位作者2003-07-15Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTParacrystalline Lattice Distortion in the Near-Surface Region of Melt-Crystallized Polyethylene Films Evaluated by Synchrotron-Sourced Grazing-Incidence X-ray DiffractionHirohiko Yakabe, Sono Sasaki, Osami Sakata, Atsushi Takahara,…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisElectron and X-Ray Spectroscopy Techniques

Properties of regenerated cellulose films plasticized with α‐monoglycerides

Chaobo Xiao、Zhenjun Zhang、Jinhua Zhang 等 5 位作者2003-07-15Journal of Applied Polymer Science

Abstract Regenerated cellulose (RC) films were plasticized with glycerol, glycerin α‐monobutyrate, glycerin α‐monocaproate, glycerin α‐monocaprylate, and glycerin α‐monocaprate. The structure and properties of the films were investigated by using Fourier transform IR, wide‐angle X‐ray diffraction, differential scannin…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesPolymer Science and PVC