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π-Conjugated multiporphyrin box via self-assembly of an ethynylene-bridged zinc porphyrin dimer

Akihiko Tsuda、Haifeng Hu、Reiko Watanabe 等 4 位作者2003-05-01Journal of Porphyrins and Phthalocyanines

An ethynylene-bridged zinc porphyrin dimer bearing metal-coordinating groups, such as bis[{5-(4-pyridyl)-15-(3,5-didodecyloxyphenyl)porphyrinato}zinc] Z2, self-assembles in CHCl 3 to form a rectangular-shaped supramolecular nano box, in which all the Z2 units preferentially adopt a planar conformation with a syn-paral…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

The Application of Shape Memory Actuators in Anthropomorphic Upper Limb Prostheses

Christian Mariani Lucas dos Santos、Fransérgio Leite da Cunha、Vladimir Ivanovitch Dynnikov2003-05-01Artificial Organs

In recent years, single crystal Cu-Al-Ni alloys with shape memory behavior (SMB) became generally commercialized. They achieved the level of extended application, including upper limb human prosthesis with anthropomorphic characteristics. An actuator based in single crystal Cu-Al-Ni alloy was tested as a prototype for…

Shape Memory Alloy Transformations

Borocookeite, a new member of the chlorite group from the Malkhan gem tourmaline deposit, Central Transbaikalia, Russia

V.Ye. Zagorsky、I. S. Peretyazhko、Anatoliy N. Sapozhnikov 等 5 位作者2003-05-01American Mineralogist

Borocookeite, ideally Li 1+3x Al 4-x (BSi 3 )O 10 (OH,F) 8 (where “x” varies in the range 0.00-0.33 apfu), in which [4] Al is replaced by B relative to cookeite, occurs as a late-stage pocket mineral in the Sosedka and Mokhovaya pegmatite veins, Malkhan gem tourmaline deposit, Chikoy district, Chita oblast, Russia. Bo…

Geological and Geochemical AnalysisCrystal Structures and PropertiesRadioactive element chemistry and processing

Structural Aspects of the β‐Polymorph of (E)‐4‐Formylcinnamic Acid: Structure Determination Directly from Powder Diffraction Data and Elucidation of Structural Disorder from Solid‐State NMR

S. Meejoo、Benson M. Kariuki、Simon J. Kitchin 等 6 位作者2003-05-01Helvetica Chimica Acta

Abstract Among the derivatives of ( E )‐cinnamic acid for which the solid‐state photochemical properties have been studied, ( E )‐4‐formylcinnamic acid ( 1 ) has already received much attention. Given the inability to prepare single crystals of the β ‐polymorph of 1 that are of suitable size and quality for structural…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Copper losses of flyback transformer: search for analytical expressions

Chérif Larouci、J.P. Keradec、J.P. Ferrieux 等 5 位作者2003-05-01IEEE Transactions on Magnetics

Because analytical expressions are required to run optimization software, this subject is very topical. This work uses equivalent permeability to homogenize the winding structure and approximations for the window field. A progressive approach leads to the needed expressions for a transformer built around a gapped ferr…

Silicon Carbide Semiconductor TechnologiesMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Polymeric Drug for Antimicrobial Activity Studies: Synthesis and Characterization

A. Arun、B. S. R. Reddy、M. Rajkumar2003-05-01Journal of Bioactive and Compatible Polymers

In this study, 2′,4-dichloro-5′-fluoro-1-ene-2-(4-hydroxyphenyl)phenone (EHP) was synthesized using 4-hydroxybenzaldehyde and 2, 4-dichloro-5-fluoro acetophenone (DFA); 4-[3-(2,4-dichloro-5-fluorophenyl)-3-oxoprop-1-en-1-yl]phenyl acrylate (EAP) was prepared by reacting EHP with acryloyl chloride. Poly(EAP) was prepar…

Click Chemistry and ApplicationsSynthesis and properties of polymersPhosphorus compounds and reactions

The size effect on the phase stability of nanograined Fe 12Ni powders and the magnetic separation of face-centred-cubic body-centred-cubic phases

Hongbin Wang、Qizheng Liu、Jihua Zhang 等 4 位作者2003-05-01Nanotechnology

The phase stability of nanograined Fe–12Ni powders is studied by means of both experiment and theoretical calculations. By means of a magnetic field accompanied by an ultrasonic vibration dispersal, the nanograined Fe–12Ni powders synthesized by the gas condensation were successfully separated into a face-centred-cubi…

Microstructure and mechanical propertiesMetallic Glasses and Amorphous AlloysAdvanced materials and composites

Nitric oxide release from the S-nitrosothiol zinc phthalocyanine complex by flash photolysis

Jeane Cristina Gomes Rotta、Claure N. Lunardi、Antônio Cláudio Tedesco2003-05-01Brazilian Journal of Medical and Biological Research

The photogeneration of nitric oxide (NO) using laser flash photolysis was investigated for S-nitroso-glutathione (GSNO) and S-nitroso-N-acetylcysteine (NacySNO) at pH 6.4 (PBS/HCl) and 7.4 (PBS). Irradiation of S-nitrosothiol with light (lambda = 355 nm followed by absorption spectroscopy) resulted in the homolytic de…

Nitric Oxide and Endothelin EffectsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Microstructural characterization of INCOLOY alloy MA 956

Márcio Ferreira Hupalo、Maysa Terada、Andréa Madeira Kliauga 等 4 位作者2003-05-01Materialwissenschaft und Werkstofftechnik

Abstract Oxide dispersion strengthened (ODS) ferritic materials obtained by mechanical alloying (MA) display particular microstructure and texture. In this paper a microstructural characterization of an INCOLOY MA 956 alloy in the recrystallized (zone annealed) condition is presented. The alloy exhibits a highly aniso…

Fusion materials and technologiesHigh-Temperature Coating BehaviorsNuclear Materials and Properties

34.5L: Late‐News Paper: High Transmittance Pixel Design of In‐Plane Switching TFT‐LCDs for TVs

Yoshiaki Nakayoshi、Naho Kurahashi、Junji Tanno 等 6 位作者2003-05-01SID Symposium Digest of Technical Papers

Abstract Design architecture of realizing high performance IPS‐LCDs with a 30% improved transmittance, less color shifting, and faster response time of less than ms 16 in the grayscales was represented. The newly developed pixel structure, consisting of transparent electrodes arranged on organic insulator, improved th…

Liquid Crystal Research AdvancementsOrganic Light-Emitting Diodes ResearchThin-Film Transistor Technologies

Chemical Composition Distribution of Multicomponent Copolymers

Siripon Anantawaraskul、João B. P. Soares、Paula M. Wood‐Adams2003-05-01Macromolecular Theory and Simulations

Abstract The number and weight chemical composition distributions in random terpolymers were derived using a statistical approach. The solution was then generalized to comprise higher multicomponent copolymers. The analytical solution was verified with Monte Carlo simulations and by considering limiting cases. Chemica…

Asphalt Pavement Performance EvaluationPolymer Nanocomposites and PropertiesAdsorption, diffusion, and thermodynamic properties of materials

Dependence of Sorption Properties of Fibrous Assemblies on Their Fabrication and Material Characteristics

Seong Hun Kim、Jae‐Hyung Lee、Dae Young Lim 等 4 位作者2003-05-01Textile Research Journal

To characterize the sorption behavior of a fibrous assembly, an experimental method must measure the sorption rate and the capacity in conditions similar to those found in the real state. The gravimetric absorbency testing system (GATS) has advantages in that it can dynamically observe the spontaneous transplanar upta…

Natural Fiber Reinforced CompositesTextile materials and evaluationsMaterial Properties and Processing

Electrochemical behaviour of an archaeological bronze alloy in various aqueous media: New method for understanding artifacts preservation

Nabil Souissi、Latifa Bousselmı、S. Khosrof 等 4 位作者2003-05-01Materials and Corrosion

Abstract The aim of this work is to investigate the electrochemical behaviour of an archaeological bronze in several aqueous electrolytes (Na 2 SO 4 , NaCl, KOH, NaHCO 3 and Na 3 PO 4 ) at 0.01 M. The anodic polarization revealed the dissolution of the material independently from the corrosive medium, but the damaging…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisBuilding materials and conservation

Surface and Mechanical Property Measurements of H Technology Needle-Punched Nonwovens

C. Roedel、Seshadri Ramkumar2003-05-01Textile Research Journal

The H 1 technology needle-punching process is a patented invention from Fehrer, AG. H 1 technology machinery is used to develop a set of polyester/cotton blended nonwoven substrates. A suitable protocol is developed to clean, process, and blend cotton with polyester fibers suitable for needle-punching on the needle-lo…

Textile materials and evaluationsVibration and Dynamic AnalysisMaterial Properties and Processing

Electronic and Magnetic Properties of Organic Conductors (DMET)2MBr4 (M = Fe, Ga)

Kengo Enomoto、Jun‐ichi Yamaura、Akira Miyazaki 等 4 位作者2003-05-01Bulletin of the Chemical Society of Japan

Abstract (DMET)2MBr4 (M = Fe, Ga) are isostructural organic conductors whose crystal structure consists of an alternate stacking of quasi one-dimensional chain-based donor layers and anion square lattices. The resistivity, ESR, magnetic susceptibility, magnetization, and magnetoresistance of these salts were investiga…

Physics of Superconductivity and MagnetismPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

Directed Crystallisation of Synthetic Polymers by Low‐Molar‐Mass Self‐Assembled Templates

Aurora Nogales、R. H. Olley、Geoffrey R. Mitchell2003-05-01Macromolecular Rapid Communications

Abstract A novel and powerful method of microstructure control in polyolefins is presented. By dispersing tiny amounts of sorbitol derivatives in the polymer, the subsequent crystal growth can be controlled with modest prior flow‐fields; in particular high levels of preferred orientation are generated in the resultant…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer composites and self-healing

Normal-mode anisotropic liquid-crystal gels

Yun‐Hsing Fan、Hongwen Ren、Shin‐Tson Wu2003-05-01Applied Physics Letters

A normal-mode anisotropic liquid-crystal (LC) gel is demonstrated. In the absence of an electric field, the light polarized along the rubbing direction is scattered. In the voltage-on state, the gel is highly transparent and is independent of polarization. Such a normal mode LC gel exhibits a modest contrast ratio, re…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Materials and Mechanics

NIR Dyes Based on [M(R,R′timdt)2] Metal‐Dithiolenes: Additivity of M, R, and R′ Contributions To Tune the NIR Absorption (M = Ni, Pd, Pt; R,R′timdt = Monoreduced Form of Disubstituted Imidazolidine‐2,4,5‐trithione)

M. Carla Aragoni、Massimiliano Arca、T. Cassano 等 13 位作者2003-05-01European Journal of Inorganic Chemistry

Abstract With the aim of preparing new dyes for Q‐switching and/or mode‐locking Nd‐based lasers, such as Nd:YLF and Nd:YAG (emission wavelengths 1053 and 1064 nm, respectively), the syntheses of about 30 new neutral dithiolenemetal complexes belonging to the class [M(R,R′timdt) 2 ] have been carried out [M = Ni ( 4a −…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchOrganometallic Compounds Synthesis and Characterization

COCCONEISEHRENBERG ANDPSAMMOCOCCONEISGARCIA (BACILLARIOPHYTA) FROM THE GULF OF SAN MATÍAS, PATAGONIA, ARGENTINA

Eugenia A. Sar、Oscar E Romero、Inés Sunesen2003-05-01Diatom Research

The morphology and taxonomy of species of the genera Cocconeis Ehrenberg and Psammococconeis Garcia from the Gulf of San Matías (Patagonia, Argentina) is documented in the present study. A total of 16 taxa of Cocconeis and one species of Psammococconeis were found in surface net hauls taken in shallow coastal waters o…

Marine Biology and Ecology ResearchDiatoms and Algae ResearchCephalopods and Marine Biology

Effects of Various Home Laundering Practices on the Dimensional Stability, Wrinkling, and Other Properties of Plain Woven Cotton Fabrics

L. Higgins、S.C. Anand、D. A. Holmes 等 5 位作者2003-05-01Textile Research Journal

For a systematic study of the effect of laundering on plain woven cotton fabrics, specimens of poplin and sheeting fabrics (with and without a DMDHEU wrinkle resistant finish) are laundered under regimes designed to evaluate the effect of five common home laundering variables: use of detergent, rinse cycle softener, o…

Mechanical Behavior of CompositesDyeing and Modifying Textile FibersTextile materials and evaluations