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Thermodynamics of the Solubility of KF in N,N-Dimethyl Ethanolamine, Pyridine, Diethanolamine, and Sulfolane from 308.73 to 367.37 K

Hua Li、Juan Liu、Xiaoshuang Chen 等 4 位作者2012-03-27Industrial & Engineering Chemistry Research

The solubilities of potassium fluoride (KF) in the different nonproton polar solvents N, N -dimethyl ethanolamine, pyridine, diethanolamine, and sulfolane have been determined using a dynamic method at temperatures ranging from 308.73 to 367.37 K. The experimental data were correlated with the modified Apelblat equati…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsChemical Thermodynamics and Molecular Structure

Processing and Mechanical Properties of Starch and PCL Composite Reinforced by Nano-SiO<sub>2</sub>

Wen Yong Liu、Yi Chen、Long Ouyang 等 5 位作者2012-03-27Advanced materials research

The thermoplastic processing and mechanical properties of starch and polycaprolactone (PCL) composites reinforced by nano-silica (nano-SiO 2 ) were studied. The results showed that the mechanical properties of the starch/PCL blends improved significantly with the increase of PCL. After the addition of nano-SiO 2 , the…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Nanoscale Structural and Mechanical Characterization of MWCNT-Reinforced Polymer Composites

Wyatt Leininger、Xinnan Wang、X. W. Tangpong 等 4 位作者2012-03-27Journal of Engineering Materials and Technology

In this study, the elastic modulus of 1 wt. % multiwalled carbon nanotube (MWCNT) reinforced epoxy composite was characterized using an in-house designed micro/nano tensile load stage in conjunction with an atomic force microscope (AFM). The surface of the nanocomposite was scanned by the AFM during intermittent tensi…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsTribology and Wear Analysis

Micromechanical Modeling of the Effective Viscoelastic Response of Polyamide-6-Based Nanocomposites Reinforced with Modified and Unmodified Montmorillonite Clay

K. Anoukou、Fahmi Zaïri、M. Naït‐Abdelaziz 等 5 位作者2012-03-27Materials science forum

A micromechanics-based approach using a self-consistent scheme based on the double-inclusion model is adopted to develop a pertinent model for describing the viscoelastic response of polymer/clay nanocomposites. The relationship between the intercalated nanostructure and the effective nanocomposite stiffness is constr…

Structural Behavior of Reinforced ConcretePolymer Nanocomposites and PropertiesTribology and Wear Analysis

Electrical and Mechanical Properties of Ethylene Vinyl Acetate Based Composites

Klaudia Czaníková、Zdenko Špitálský、Igor Krupa 等 4 位作者2012-03-27Materials science forum

In this study various composites based on the commercial ethylene vinyl acetate polymer matrix and multiwalled carbon nanotubes were prepared by casting from solution in the form of thick films. The degree of dispergation of carbon nanotubes in the polymer matrix was examined by scanning electron microscopy. Electrica…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Influence of the degree of exfoliation on the thermal conductivity of polypropylene nanocomposites

Stephan Laske、Ivica Ðuretek、Andreas Witschnigg 等 6 位作者2012-03-27Polymer Engineering and Science

Abstract The aim of this study was to determine the influence of exfoliated silicate layers on the thermal conductivity of polypropylene nanocomposites. The correlation of thermal conductivity with the degree of exfoliation is examined and compared to common mineral fillers like talcum. The results clearly show that n…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Filler reaggregation and network formation time scale in extruded high‐density polyethylene/multiwalled carbon nanotube composites

Frank Yepez Castillo、Brian P. Grady2012-03-27Polymer Engineering and Science

Abstract A high‐density polyethylene (HDPE) masterbatch containing 20.2 wt% multiwalled carbon nanotubes (MWNTs) was melt diluted with neat HDPE using two different methods: a twin screw microcompounder and a single‐screw extruder. The electrical properties of these composites were assessed using bulk electrical condu…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesConducting polymers and applications

Rheological properties and morphological evolutions of polypropylene/ethylene‐butene copolymer blends

Xianming Zhang、Hao Li、Wen‐Xing Chen 等 4 位作者2012-03-27Polymer Engineering and Science

Abstract This work aims at studying the extensional rheological behavior of polypropylene (PP), ethylene‐butene copolymer (PEB) and their blends in the melt. The weight fraction of the PEB in the blend is 20 and 40%, respectively. Dynamic mechanical analysis shows that these two blends exhibit two tanδ peaks correspon…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

A study on the transverse edge effect of an eddy current brake with a solid steel secondary

Yasuaki Sakamoto、Takayuki Kashiwagi、Hitoshi Hasegawa 等 5 位作者2012-03-27IEEJ Transactions on Electrical and Electronic Engineering

Abstract The eddy current brake is a type of braking system used for railway vehicles. Because rail heating is a problem in this type of brakes, they have not been put to practical use in Japan. Therefore we proposed using a linear induction motor (LIM) for dynamic braking in the eddy current brake systems. In this pa…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

A multilayered approach of Si/SiO to promote carrier transport in electroluminescence of Si nanocrystals

Li Ding、Yongbin Chen、Yong Ren 等 6 位作者2012-03-27Nanoscale Research Letters

The electroluminescence (EL) and photoluminescence of Si nanocrystals (Si-nc) from multilayered samples of Si/SiO are investigated. Si-nc are formed within Si and SiO layers after furnace annealing. It is found that the presence of Si interlayers creates extra carrier paths for EL emission. A comparative study is furt…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

The Mechanical and Thermal Properties of Polyoxymethylene (POM)/Organically Modified Montmorillonite (OMMT) Engineering Nanocomposites Modified with Thermoplastic Polyurethane (TPU) Compatibilizer

Agnieszka Leszczyńska、Krzysztof Pielichowski2012-03-27Materials science forum

In this work the effect of macromolecular polyurethane compatibilizer on the structure, mechanical and thermal properties of polyoxymethylene/organically modified montmorillonite (POM/OMMT) nanocomposites was investigated. The thermal stability of obtained systems was significantly enhanced by compatibilizer both in o…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Atomistic simulations of liquid crystal mixtures of alkoxy substituted phenylpyrimidines 2PhP and PhP14

Fangyong Yan、David J. Earl2012-03-27The Journal of Chemical Physics

We study liquid crystal mixtures of alkoxy substituted phenylpyrimidines 2-[4-(butyloxy)phenyl]-5-(octyloxy)pyrimidine (2PhP) and 2-[4-(tetradecyloxy)phenyl]-5-(tetradecyloxy)pyrimidine (PhP14) using molecular dynamics simulations at the all atom level. The molecular length of PhP14 is 1.8 times that of 2PhP, resultin…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Effect of short‐chain branching on melt fracture behavior of metallocene and conventional poly(ethylene/α‐olefin) copolymers

Emilia Garofalo、Loredana Incarnato、Luciano Di Maio2012-03-27Polymer Engineering and Science

Abstract A phenomenon that can represent a great problem in melt processing is extrudate distortion. This effect can range in intensity from a loss of gloss to gross distortion and is the factor that limits the production rate in certain processes such as the blown film extrusion of linear low‐density polyethylene (LL…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Hybrid Assemblies of Eu‐Containing Polyoxometalates and Hydrophilic Block Copolymers with Enhanced Emission in Aqueous Solution

Jie Zhang、Yang Liu、Yang Li 等 5 位作者2012-03-27Angewandte Chemie

Kern-Schale-Nanostrukturen eines photolumineszierenden Eu-Polyoxometallats (Eu-POM) mit dem doppelt-hydrophilen neutral-kationischen Blockcopolymer PEO114-b-PDMAEMA16 wurden durch elektrostatisch getriebene Selbstorganisation in wässriger Lösung hergestellt (siehe Schema; neutraler Block blau, kationischer Block rot).…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Evaluation of the structure of polypropylene/montmorillonite nanocomposite by in‐line light extinction and color measurements during multiple extrusions

Kelen Cristina dos Reis、Sebastião V. Canevarolo2012-03-27Polymer Engineering and Science

Abstract This work extends the method to follow in real time the reduction of the clay particle size by light extinction measurements (turbidity), obtained via an in‐line optical detector fitted at the extruder die exit, to monitor multiple extrusions of PP/MMT nanocomposites. The optical detector was calibrated and s…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Numerical Modeling of the Failure of Magnesium Tubes Under Compressive Loading

Jonathan Rossiter、Kaan Inal、Raja K. Mishra2012-03-27Journal of Engineering Materials and Technology

A new finite element (FE) specific failure criterion utilizing hardening rates to quantify bending stress is implemented into the MAT_124 material model in the commercial software LS-DYNA to simulate fracture of extruded AZ31 and cast AM60 magnesium alloy tubes. The simulations are performed by requiring element erosi…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Stability of Porous Platinum Nanoparticles: Combined In Situ TEM and Theoretical Study

Shery L. Y. Chang、Amanda S. Barnard、Christian Dwyer 等 9 位作者2012-03-27The Journal of Physical Chemistry Letters

Porous platinum nanoparticles provide a route for the development of catalysts that use less platinum without sacrificing catalytic performance. Here, we examine porous platinum nanoparticles using a combination of in situ transmission electron microscopy and calculations based on a first-principles-parametrized therm…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials Sciencenanoparticles nucleation surface interactions

Phase structure of monolayer graphene from effective U(1) gauge theory on honeycomb lattice

Yasufumi Araki2012-03-27Physical Review B

Phase structure of monolayer graphene is studied on the basis of a U(1) gauge theory defined on the honeycomb lattice. Motivated by the strong coupling expansion of U(1) lattice gauge theory, we consider on-site and nearest-neighbor interactions between the fermions. When the on-site interaction is dominant, the subla…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Thermodynamic Discrimination in the Formation of Tetranuclear Lanthanide Helicates

Soumaila Zebret、Céline Besnard、Gérald Bernardinelli 等 4 位作者2012-03-27European Journal of Inorganic Chemistry

Abstract The complexation of lanthanide cations with a tripodal ligand bearing terminal ester functions was investigated. Thermodynamic speciation was achieved by a combination of different physicochemical methods, and the stability constants of the related complexes were determined spectrophotometrically. The formati…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The Elasticity of PLA Fiber Blended Yarn

Qing Yang2012-03-27Advanced materials research

In order to describe the relation between the elasticity and the blended ratio of PLA fiber blended yarn, the elasticity of different kinds of blended ratio of PLA/Modal and PLA/cotton blended yarn was measured. The relation between the elasticity and the blended ratio of blended yarn is determined. The optimum blende…

Textile materials and evaluations