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Graphene and Graphene Oxide Can “Lubricate” Ionic Liquids based on Specific Surface Interactions Leading to Improved Low‐Temperature Hypergolic Performance

Parker D. McCrary、Preston A. Beasley、Spencer A. Alaniz 等 6 位作者2012-09-05Angewandte Chemie

Weltraumtaugliche Schmiermittel: Graphen und Graphenoxid (r-GO) können das Tieftemperaturverhalten hypergolischer ionischer Flüssigkeiten drastisch verbessern, indem sie deren Viskosität reduzieren. Entscheidend dabei ist, dass die Art des Graphens auf die spezifische Funktionalität der IL abgestimmt wird.

Graphene research and applicationsSupercapacitor Materials and FabricationIonic liquids properties and applications

4‐Phosphatephenyl Covalently Modified Glassy Carbon Electrode for Real‐Time Electrochemical Monitoring of Paracetamol Release from Electrospun Nanofibers

Guocheng Yang、Lu Wang、Yingshu Yang 等 7 位作者2012-09-05Electroanalysis

Abstract A glassy carbon electrode (GCE) was covalently modified by 4‐phosphatephenyl (4‐PP). Sensing paracetamol (PCT) via linear sweep voltammetry in sulfuric buffer solution of pH 1.02 at 36.8 °C, the 4‐PP‐modified GCE showed high electrochemical sensitivity and long reusability. PCT‐loaded poly(vinyl alcohol) (PVA…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Programming and Projection of Near IR Images Using ${\rm VO}_{2}$ Films

Noraica Dávila、Rafmag Cabrera、Nelson Sepúlveda2012-09-05IEEE Photonics Technology Letters

This letter reports the use of programmed optical states in a vanadium dioxide (VO2) thin film for the projection of near infrared (NIR) images. The optical states are programmed by photothermal actuation from scanning a focused red laser on localized regions of the VO2thin film. The abrupt change in transmissivity of…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsPhotoacoustic and Ultrasonic Imaging

Predicting the Net Heat of Combustion of Organosilicon Compounds from Molecular Structures

Yong Pan、Juncheng Jiang、Yinyan Zhang2012-09-05Industrial & Engineering Chemistry Research

The net heat of combustion is one of the most important properties of flammable substances that can be used to estimate the potential fire hazards of chemicals once they ignite and burn. This study proposed a quantitative structure–property relationship model to predict the net heat of combustion of 308 organosilicon…

Computational Drug Discovery MethodsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Exploring the CdTe Quantum Dots in Ionic Liquids by Employing a Luminescent Hybrid of the Two

Kotni Santhosh、Anunay Samanta2012-09-05The Journal of Physical Chemistry C

Poor solubility of the semiconductor quantum dots (QDs) severely restricts studies on these substances in room temperature ionic liquids (ILs). It also limits applications, which require both these promising classes of materials. In this work, a simple method employing a task-specific thiol-capped imidazolium ionic li…

Quantum Dots Synthesis And PropertiesIonic liquids properties and applicationsElectronic and Structural Properties of Oxides

Half-metallicity in graphene nanoribbons with topological defects at edge

Joydeep Bhattacharjee2012-09-05The Journal of Chemical Physics

We report first principles studies of zigzag edged graphene nanoribbons (ZGNR) with one edge partially covered by topological defects. With increasing coverage of an edge by pentagons and heptagons, which are two of the simplest topological defects possible in a graphenic lattice, ZGNRs evolve from a magnetic semicond…

Advancements in Battery MaterialsGraphene research and applicationsQuantum and electron transport phenomena

Mathematical modelling of elastoplasticity at high stress

P. D. Howell、H. Ockendon、J. R. Ockendon2012-09-05Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences

This study describes a simple mathematical model for one-dimensional elastoplastic wave propagation in a metal in the regime where the applied stress greatly exceeds the yield stress. Attention is focused on the increasing ductility that occurs in the over-driven limit when the plastic wave speed approaches the elasti…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorMaterial Properties and Failure Mechanisms

Optical properties of nanostructured tungsten in near infrared range

Shin Kajita、N. Ohno、Takanori Yokochi 等 7 位作者2012-09-05Plasma Physics and Controlled Fusion

In nuclear fusion devices, infrared (IR) imaging diagnostics have been widely used for the temperature measurement of in-vessel surfaces. For the diagnostics, variations of the optical emittance and reflectance of wall materials will be an essential issue to measure the temperature correctly. In this study, variations…

Laser-Plasma Interactions and DiagnosticsHigh-pressure geophysics and materialsFusion materials and technologies

Thermally activated plastic flow in the presence of multiple obstacle types

Y Dong、W.A. Curtin2012-09-05Modelling and Simulation in Materials Science and Engineering

The rate- and temperature-dependent plastic flow in a material containing two types of thermally activatable obstacles to dislocation motion is studied both numerically and theoretically in a regime of relative obstacle densities for which the zero-temperature stress is additive. The numerical methods consider the low…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepNuclear Materials and Properties

Thickness and stacking geometry effects on high frequency overtone and combination Raman modes of graphene

Dongfei Li、Da Zhan、Jiaxu Yan 等 8 位作者2012-09-05Journal of Raman Spectroscopy

We investigate two high frequency Raman overtone and combination modes of graphene named 2D' and 2D + G bands, and located at ~3240 and ~ 4260 cm –1 , respectively. The graphene thickness and stacking geometry effects for these two modes are systematically studied. The features of the 2D' band, which arises from intra…

Graphene research and applicationsPlasmonic and Surface Plasmon ResearchDiamond and Carbon-based Materials Research

Effects of shape and composition on the properties of CdS nanocrystals

Soumendu Datta、Mukul Kabir、Tanusri Saha‐Dasgupta2012-09-05Physical Review B

Using first-principles electronic structure calculations, we studied the relative stability between hexagonal wurtzite (WZ) and cubic zinc-blende (ZB) structures and the electronic properties of the CdS nanocrystals of varying shape and surface composition. Our study shows substantial enhancement of the stability of t…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Effect of ionizing radiation on the properties of acrylonitrile butadiene rubber/clay nanocomposites

HA Youssef、Zain Ali、KF El-Nemr 等 4 位作者2012-09-05Journal of Elastomers & Plastics

The effects of electron beam irradiation dose (50–150 kGy) and the concentration of montmorillonite (MMT) clay (3–10 parts per hundred part of rubber (phr)) on the properties of acrylonitrile butadiene rubber (NBR) have been investigated. The dispersion of the layered silicates was assessed by x-ray diffraction and tr…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry

Dynamic scaling for anomalous transport in supercooled liquids

Akira Furukawa、Hajime Tanaka2012-09-05Physical Review E

The anomalous mesoscopic transport in supercooled liquids was investigated using three-dimensional molecular dynamics simulation. We show that the dynamic correlation length, ξ, can be identified as a crossover length between the microscopic and macroscopic transports. We also find that in highly supercooled states, w…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

The Impact of Niobium Surface Segregation on Charge Separation in Niobium-Doped Titanium Dioxide

L. R. Sheppard、Thomas Dittrich、M. K. Nowotny2012-09-05The Journal of Physical Chemistry C

The present investigation has studied the impact of Nb surface segregation on charge carrier separation in polycrystalline Nb-doped (0.65 at % Nb) TiO 2 . By use of secondary ion mass spectrometry, the effect of applied processing conditions (temperature and oxygen activity) on the segregation of Nb has been obtained…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Vibrational spectroscopy of self‐assembling aromatic peptide derivates

Wiwat Nuansing、Amaia Rebollo、José M. Mercero 等 5 位作者2012-09-05Journal of Raman Spectroscopy

Peptides can assemble to supramolecular structures, of which fibers are of special biochemical and medical relevance. We employed Raman and infrared spectroscopy to elucidate the chemical integrity of fibers built from peptides and peptide derivates that contain the aromatic side groups fluorenyl and phenyl. Because t…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Micro-Emulsion Synthesis, Surface Modification, and Photophysical Properties of ${\rm Zn}_{1-x}~{\rm Mn}_{\rm x} {\rm S}$ Nanocrystals for Biomolecular Recognition

Elham Mohagheghpour、Fathollah Moztarzadeh、Mohammad Rabiee 等 8 位作者2012-09-05IEEE Transactions on NanoBioscience

In this research, we mainly focused on the micro-emulsion synthesis of biotinylated ZnS (zinc sulfide) nanocrystals for avidin recognition. Various samples of Zn(1-x)Mn(x) S, with x = 0.0001, 0.007, 0.02, 0.03, 0.055, 0.09 and 0.13, prepared by quaternary W/O (water-in-oil) microemulsion system. Cyclohexane was used a…

Electrochemical sensors and biosensorsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Optical Scattering Artifacts Observed in the Development of Multiplexed Surface Enhanced Raman Spectroscopy Nanotag Immunoassays

James E. Noble、Simon Attree、Adrian Horgan 等 7 位作者2012-09-05Analytical Chemistry

Here we describe scattering based signal suppression artifacts encountered while developing multiplex lateral flow (LF) immunoassay using surface enhanced Raman spectroscopy (SERS) "nanotags" as analyte labels. Using these SERS nanotags, we have produced a quantitative test for inflammation biomarkers that is transfer…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionAdvanced Biosensing Techniques and Applications

Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffraction

Loïc Le Dréau、Carmelo Prestipino、Olivier Hernandez 等 9 位作者2012-09-05Inorganic Chemistry

We report a combined synchrotron X-ray and neutron diffraction study on as-grown La(2)CoO(4.14) single-crystal from 10 to 470 K. Unprecedented structural features in terms of a (3 + 2)D incommensurate modulation have been detected and characterized in the Low Temperature Orthorhombic (LTO) phase already at room temper…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Drop Motion Induced by Repeated Stretching and Relaxation on a Gradient Surface with Hysteresis

Jonathan E. Longley、Erin E. Dooley、Douglas M. Givler 等 6 位作者2012-09-05Langmuir

The motion of a droplet can be induced by periodically compressing and extending it between two similar gradient surfaces possessing significant wetting hysteresis. The shape fluctuation of the drop during repeated compression-extension cycles leads to its ratchetlike motion toward the region of higher wettability. A…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferElectrowetting and Microfluidic Technologies