Materials Literature
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A metal-semiconductor heterojunction material was fabricated by photocatalytically depositing Au nanoparticles (NPs) inside titania nanotubes, and have been applied, for the first time, to the surface enhanced Raman (SER) scattering detection of polycyclic aromatic hydrocarbons (PAHs). Due to the nanotubular structure…
Transparent conducting Ga : ZnO films were synthesized directly on glass substrates via a low-temperature aqueous route for application in dye-sensitized solar cells. Preliminary electrical and optical characterization of the films showed that 85% transparency across the optical range with sheet resistances as low as…
Dual-frequency relaxation-assisted two-dimensional infrared (RA 2DIR) spectroscopy was used to investigate energy transport in polyethylene glycol (PEG) oligomers of different length, having 0, 4, 8, and 12 repeating units and end-labeled with azido and succinimide ester moieties (azPEGn). The energy transport initiat…
This paper reports the development of a simple and effective way to prepare novel soluble porous polymer nanospheres (PPSs) by A3B2 catalytic emulsion polymerization using a Suzuki reaction as a one-step, surfactant-free process. The PPSs chemical structures are characterized by Fourier transform infrared spectroscopy…
We present a self-consistent field theoretical study of phase separation in binary polymer brushes physisorbed on cylindrical surfaces under good solvent conditions. In agreement with earlier simulation and experimental work, we find that macrophase separation occurs for two immiscible polymers of the same length, whi…
Three-dimensional (3-D) flower-like shape (FLS) Fe3O4 and Fe particles were successfully synthesized using FLS precursor particles that are prepared through a facile microwave-assisted reaction. The mechanism underlying the self-assembly process and shape evolution of FLS particles was systematically investigated by c…
An investigation into the catalyst-free growth of highly crystalline zinc oxide nanowires from metallic zinc powder on Si (100) substrate was investigated through the vapor solid (VS) process at 900°C in a tube furnace. The effect of substrate position on the morphology, structure and photoluminescence (PL) properties…
The use of the interaction of two hydrides is a well-known concept used to increase the hydrogen equilibrium pressure of composite mixtures in comparison to that of pure systems. The thermodynamics and reaction kinetics of such hydride composites are reviewed and experimentally verified using the example NaBH(4) + MgH…
Six 3D architectures based on lanthanide-substituted polyoxometalosilicates, KLn[(H(2)O)(6)Ln](2)[(H(2)O)(4)LnSiW(11)O(39)](2)·nH(2)O (Ln = La 1, n = 42; Ce 2, n = 40), H[(H(2)O)(6)Nd](2)[(H(2)O)(7)Nd][(H(2)O)(4)NdSiW(11)O(39)][(H(2)O)(3)NdSiW(11)O(39)]·13H(2)O (3), H(2)K(2)[(Hpic)(H(2)O)(5)Ln](2)[(H(2)O)(4)LnSiW(11)O…
An approach to the evaluation of carbon catalysts suitable for the industrial manufacture of phosgene is described. Relative reactivity and the oxidative stability of catalysts have been measured in laboratory microreactors. Comparison of the performance of full size catalyst pellets versus that of crushed catalyst al…
A novel mesoporous α-Co(OH)2/ITO NWs heterostructure has been successfully synthesized via a new method of combining chemical vapor deposition (CVD) on a titanium substrate and electrodeposition through a hexagonal lyotropic liquid crystalline (LLC) phase for electrochemical energy storage application. Electrochemical…
The corrosion behavior of the Ti-33.5Nb-5.7Ta alloy (Ti-Nb-Ta) as a biocompatible β-type Ti alloy during long-term immersion in simulated body fluid was investigated. Like pure Ti, pitting corrosion did not occur on Ti-Nb-Ta during anodic polarization. Thus, alloying of Ti with Nb and Ta did not change the chloride-io…
Layered double hydroxide supported Prussian blue nanocomposites (denoted as LDH-PB) were successfully prepared via chemical method and characterized by Fourier transform IR, X-ray diffraction, transmission electron microscope (TEM) and cyclic voltammetry. With polyaniline, polystyrene sulfonate and LDH-PB the composit…
We introduce a model of diffusion of nanoparticles in solutions of flexible, polydisperse polymers. The model takes into account the effect of depletion layer with soft boundaries. The presence of depletion layer leads to nonlinear dependence of the mean square displacement (MSD) on time. Our model may be an alternati…
This paper describes the creation of and tests petformed on knit structures of three types (left-right stitch (I), double-layer (II), and double-layer with additional fillings (III)), which contain ferromagnetic materials and electroconductive materials and are designed for individual protection against occupational h…
Two novel unsymmetrical phenanthroline-fused phthalocyanine derivatives, namely metal free 2,3,9,10,16,17-hexakis(n-butyloxy)-22,25-diaza(1,10-phenanthrolino)[5,6-c1]phthalocyanine H2[Pc(OC4H9)6(dicqn)] (1) and its zinc complex Zn[Pc(OC4H9)6(dicqn)] (2), were designed, synthesized, and characterized by a series of spe…
INTRODUCTION: Polyamidoamine (PAMAM) dendrimers are a unique family of dendritic polymers with numerous pharmaceutical and biomedical applications. One major problem with these polymers is their cytotoxicity. The purpose of this study was to synthesize novel dendrimers with aldehyde terminal groups and compare their c…
Up-conversion nanoparticles (UCNPs) that emit high-energy photons upon excitation by low-energy near-infrared (NIR) radiation are emerging as new optical nanoprobes useful in biomedicine. Herein, the one pot facile synthesis of mesoporous silica-coated NaYF4:Yb/Er nanoparticles has been achieved successfully. The as-p…
Mesoporous silica films with large spherical mesopores are synthesized using new laboratory-made polystyrene-block-polybutadiene-block-polystyrene based triblock copolymers in which the polystyrene block is functionalized with hydrophilic sulfonic groups. When the relative weight of the copolymer to silica source is i…
The trans-[Cu(2)L(2)Cl(2)] (1), and cis-[Cu(2)L(2)Cl(2)]·H(2)O (2) isomers of a diphenoxido bridged Cu(2)O(2) core have been synthesized using a tridentate reduced Schiff base ligand 2-[(2-dimethylamino-ethylamino)-methyl]-phenol. The geometry around Cu(II) is intermediate between square pyramid and trigonal bipyramid…