Materials Literature
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We demonstrate a tunneling and rectification behavior in bilayer graphene. A stepped dielectric top gate creates a spatially modulated electric field, which opens the band gap in the graphene and produces an insulating region at the p-n interface. A current-voltage relationship exhibiting differential resistance peak…
Advancements in the synthesis of faceted nanoparticles and colloids have spurred interest in the phase behavior of polyhedral shapes. Regular tetrahedra have attracted particular attention because they prefer local symmetries that are incompatible with periodicity. Two dense phases of regular tetrahedra have been repo…
Thermoelectric effects enable the direct conversion between thermal and electrical energy and provide an alternative route for power generation and refrigeration. The clathrate Ba8Ga16Ge30 has the highest figure of merit (ZT ~ 1) among other members in the family of type-I inorganic clathrates. Enhancement of the ther…
We present a new fully self-aligned single-electron memory with a single pair of nano floating gates, made of different materials (Si and Ge). The energy barrier that prevents stored charge leakage is induced not only by quantum effects but also by the conduction-band offset that arises between Ge and Si. The dimensio…
We introduce an advanced material system for the production and spectroscopy of single silicon vacancy (SiV) color centers in diamond. We use microwave plasma chemical vapor deposition to synthesize heteroepitaxial nanodiamonds of approximately 160 nm in lateral size with a thickness of approximately 75 nm. These orie…
The ordering of the classical Heisenberg model on the pyrochlore lattice with the antiferromagnetic nearest-neighbor interaction J1 and the ferromagnetic next-nearest-neighbour interaction J2 is investigated by means of a mean-field analysis and a Monte Carlo simulation. For a moderate J2/J1-value, the model exhibits…
By means of first principles calculations we demonstrate an effective method to tailor the local spin configuration of graphene on Co(0001) surface through nitrogen doping. Two different site occupancies of the N impurities are discussed with the focus on structural, electronic and magnetic properties. N induces oppos…
The electron transfer series of complexes [Cr((t)bpy)(3)](n)(PF(6))(n) (n = 3+, 2+, 1+, 0 (1-4)) has been synthesized and the molecular structures of 1, 2, and 3 have been determined by single-crystal X-ray crystallography; the structure of 4 has been investigated using extended X-ray absorption fine structure (EXAFS)…
A new class of monolayer-protected Au clusters with Au-C covalent bonds (organogold clusters) was synthesized by ligating phenylacetylene (PhC≡CH) to PVP-stabilized Au clusters. Matrix-assisted laser desorption ionization mass spectrometry revealed for the first time a series of stable compositions of the organogold (…
The study discussed the synthesis of silica sol using the sol-gel method, doped with two different amounts of Cu nanoparticles. Cotton fabric samples were impregnated by the prepared sols and then dried and cured. To block hydroxyl groups, some samples were also treated with hexadecyltrimethoxysilane. The average part…
Stable and biocompatible: The chemical composition of synthesized cationic thiolate-monolayer-protected gold nanorods was precisely determined. In vitro cell culture experiments showed no cytotoxicity of these nanorods, and the number of nanorods that were taken up by each cancer cell exceeded two million particles (s…
Transformer oil-based nanofluids with TiO2 semiconductive nanoparticles exhibit substantially higher AC and positive impulse breakdown voltage levels than that of pure transformer oils. Thermally stimulated current method (TSC) and pulse electroacoustic technique (PEA) have been used to measure charge trap and transpo…
We report a general method for the synthesis of noble metal nanorods, including Au, Ag, Pt, and Pd, based on their seeded growth in silica nanotube templates. The controlled growth of the metals occurs exclusively on the seeds inside the silica nanotubes, which act as hard templates to confine the one-dimensional grow…
Flexoelectric effect, which is defined as strain gradient–induced polarization or electric gradient–induced strain in crystalline solids, can be presented as a fourth-rank tensor. The symmetry of the flexoelectric coefficients in matrix form is studied. The results indicate that the direct flexoelectric coefficients s…
We systematically investigate the magnetic and electronic properties of graphene adsorbed with diluted 3$d$ transition and noble-metal atoms using first-principles calculation methods. We find that most transition-metal atoms (i.e., Sc, Ti, V, Mn, Fe) favor the hollow adsorption site, and the interaction between magne…
A significant enhancement of thermoelectric performance in layered oxyselenides BiCuSeO was achieved. The electrical conductivity and Seebeck coefficient of BiCu(1-x)SeO (x = 0-0.1) indicate that the carriers were introduced in the (Cu(2)Se(2))(2-) layer by Cu deficiencies. The maximum of electrical conductivity is 3…
Graphene subject to a spatially uniform, circularly polarized electric field supports a Floquet spectrum with properties akin to those of a topological insulator. The transport properties of this system, however, are complicated by the nonequilibrium occupations of the Floquet states. We address this by considering tr…
Covalent organic frameworks (COFs) are a class of important porous materials that allow atomically precise integration of building blocks to achieve pre-designable pore size and geometry; however, pore surface engineering in COFs remains challenging. Here we introduce pore surface engineering to COF chemistry, which a…
π-Conjugated organic molecules represent an attractive platform for the design and fabrication of a wide range of nano- and microstructures for use in organic optoelectronics. The desirable optical and electrical properties of π-conjugated molecules for these applications depend on their primary molecular structure an…
We report here the UV-VIS study of CdS nanoparticles synthesized via Chemical precipitation in aqueous medium, the UV-VIS of CdS in aqueous medium shows an excitonic peak at 230 nm, while that of CdS quantum dots in solid form shows an absorption maximum at 480 nm. This bleaching of band gap may be attributed to Moss–…