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The influence of the amount of hardener on the tensile mechanical behavior of an epoxy system

José Roberto Moraes d’Almeida、Sérgio Neves Monteiro1998-03-01Polymers for Advanced Technologies

The tensile mechanical behavior of an epoxy/amine system, with varying amounts of hardener, was evaluated. The results showed that a brittle to ductile transition occurs as the amount of hardener is increased. This behavior was associated with the change in the number of molecular segments that present mobility in the…

Mechanical Behavior of CompositesCorrosion Behavior and InhibitionEpoxy Resin Curing Processes

Main structural subdivisions and structural formulas of sulphate minerals

作者信息未提供1998-03-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract Main structural subdivisions of sulphate minerals and synthetic compounds were considered in the frame of a new structural classification of minerals, based on the strength distribution and directional character of the bonds. The specific features of their crystal chemistry were expressed by the corresponding…

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Phase Diagram for the 0.4Pb(Ni 1/3 ,Nb 1/3 )O 3 –0.6Pb(Zr,Ti)O 3 Solid Solution in the Vicinity of a Morphotropic Phase Boundary

Gilles Robert、Marlyse Demartin、Dragan Damjanović1998-03-01Journal of the American Ceramic Society

A phase diagram based on dielectric‐permittivity‐versus‐temperature measurements and high‐temperature X‐ray diffractometry was proposed for 0.4Pb(Ni 1/3 ,Nb 1/3 )O 3 ‐ x PbZrO 3 ‐(0.6‐ x )PbTiO 3 (0.2 lessthan equal to x lessthan equal to 0.32) relaxor‐ferroelectric solid solution, and a morphotropic phase boundary th…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Phase behavior of liquid crystals confined to controlled porous glass studied by deuteron NMR

Samo Kralj、Aleksander Zidanšek、G. Lahajnar 等 5 位作者1998-03-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The phase behavior of pentylcyanobiphenyl (5CB) and octylcyanobiphenyl (8CB) liquid crystals confined to controlled porous glass of different characteristic void sizes $R$ is studied using deuteron NMR. In samples with the 5CB liquid crystal the discontinuous isotropic-nematic $(I\ensuremath{-}N)$ transition becomes g…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPhotonic Crystals and Applications

In Situ Raman Spectroscopy of Li x V 2 O 5 in a Lithium Rechargeable Battery

Xulong Zhang、Roger Frech1998-03-01Journal of The Electrochemical Society

In situ Raman spectra of were recorded using a specially constructed spectroelectrochemical cell. A 1 M solution of in propylene carbonate‐dimethyl carbonate was used as the electrolyte and lithium foil as the anode. Three phases, γ', γ, and , are observed with increasing lithium content. The evolution of the Raman sp…

Transition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

Urea hard segment morphology in flexible polyurethane foam

Raymond Neff、Adeyinka Adedeji、Christopher W. Macosko 等 4 位作者1998-03-01Journal of Polymer Science Part B Polymer Physics

A series of flexible polyurethane slabstock foam samples were prepared with varying water content and studied using transmission electron microscopy (TEM), video-enhanced optical microscopy (VEM), and small-angle X-ray scattering (SAXS). A new TEM sample preparation technique was developed in which the foam is impregn…

Polymer composites and self-healingCarbon dioxide utilization in catalysisPolymer Foaming and Composites

Host-associated luminescence from YAG optical ceramics under gamma and optical excitation

Eugeniusz Zych、C. Brecher、H. Lingertat1998-03-01Journal of Luminescence

The host-associated luminescence of highly dense transparent YAG ceramic material is characterized and compared to that of a single crystal. The UV emission from the ceramic shows a red shift of almost 100 nm from its position in the single crystal, along with major differences in excitation spectrum. The disparities…

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsRadiation Detection and Scintillator Technologies

Reduction of NO x From Combustion Flue Gases by Corona Discharge Activated Methane Radical Injections

J.S. Chang、K. Urashima、M. Arquilla 等 4 位作者1998-03-01Combustion Science and Technology

An experimental investigation has been conducted to reduce NOx from combustion flue gases by means of corona discharge activated methane radical injection methods. Two types of corona radical injectors, the hollow needle type and the multihole type, are used in the present investigations. Experiments are conducted for…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials SciencePlasma Applications and Diagnostics

Microstructure and Stability of Polymer-Derived Ceramics; the Si–C–N System

Hans‐Joachim Kleebe1998-03-01physica status solidi (a)

Monolithic polymer-derived Si–C–N ceramics were processed by blending 70 vol% of both crosslinked and pyrolyzed Si–C–N powder particles with an oligomeric Si–C–N precursor (liquid polysilazane). The respective Si–C–N powder particles were prepared from the same liquid precursor, however, pre-heated at 300 and 1000 °C.…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Topological and geometrical properties of crack patterns produced by the thermal shock in ceramics

W. Korneta、Sushil Kumar Mendiratta、J. Menteiro1998-03-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We study the crack patterns produced by thermal shock in ceramic tableware. Cracks produced at sufficiently high-temperature gradients partition the surface plane of a ceramic material into cells forming a random two-dimensional space-filling cellular structure. The topological and geometrical properties of these stru…

Theoretical and Computational Physics3D Shape Modeling and AnalysisTextile materials and evaluations

Defective and amorphous structure of carbon nitride

J. E. Lowther1998-03-01Physical review. B, Condensed matter

There has been enormous interest in preparing the superhard material ${\mathrm{C}}_{3}{\mathrm{N}}_{4}$, with the large nitrogen concentration being one factor limiting preparation. Using an ab initio supercell approach we simulate the electronic structure about a N vacancy and investigate the effect it has on the bul…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Chemistry, diffusion and cluster formation at metal-polymer interfaces

Thomas Strunskus、Michael Kiene、R. Willecke 等 6 位作者1998-03-01Materials and Corrosion

This paper shows how structure and formation of metal-polymer interfaces depend strongly on the preparation process and the interfacial chemistry. Emphasis is placed on results obtained from transmission electron microscopy (TEM), X-ray photo electron spectroscopy (XPS), radiotracer measurements and computer simulatio…

Electron and X-Ray Spectroscopy Techniquesnanoparticles nucleation surface interactionsElectrostatics and Colloid Interactions

High frequency shear modulus of polymerically stabilized colloids

Stacey Elliott、William B. Russel1998-03-01Journal of Rheology

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation S. L. Elliott, W. B. Russel; High frequency shear modulus of polymerically stabilized colloids. J…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsElectrostatics and Colloid Interactions

Radioactive Materials in Recycled Metals-An Update

Joel O. Lubenau、James G. Yusko1998-03-01Health Physics

In April 1995, Health Physics published a review paper titled "Radioactive Materials in Recycled Metals." At that time, 35 accidental meltings of radioactive sources in metal mills were reported, including 22 in the U.S., along with 293 other events in the U.S. where radioactive material was found in metals for recycl…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Mechanism of Alloy Corrosion and Consequences on Sealed Nickel—Metal Hydride Battery Performance

P. Leblanc、Christian Jordy、B. Knosp 等 4 位作者1998-03-01Journal of The Electrochemical Society

The degradation mechanism of hydrogen storage alloy in nickel‐metal hydride (Ni‐MH) sealed batteries and effects of corrosion on cell performance during cycling are investigated. A general equation for the corrosion of AB 5 alloy is derived from analyses of corrosion products in cycled electrodes and measurements of n…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Opalescent Cholesteric Networks from Chiral Polyisocyanates in Polystyrene

Georg Maxein、Harald Keller、Bruce M. Novak 等 4 位作者1998-03-01Advanced Materials

The cholesteric polymer films described here, i.e., the “locked in” chiral nematic phase of polymer liquid crystals, have several advantages as materials for optical applications. The Figure shows schematically a cholesteric network based on a chiral isocyanate terpolymer in styrene in which the cholesteric liquid-cry…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsMolecular spectroscopy and chirality

Effect of sample preparation on the magnetic and magnetocaloric properties of amorphous Gd70Ni30

M. Földeáki、Richard Chahine、B. R. Gopal 等 6 位作者1998-03-01Journal of Applied Physics

Certain applications of magnetic materials require the knowledge of the magnetocaloric effects, i.e., the adiabatic change of temperature or the isothermal change of the entropy upon application or removal of magnetic field. While the isothermal magnetic entropy change can be calculated from magnetic data only, the ca…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsMagnetic Properties of Alloys

Proton dynamics and the tautomerization potential in benzoic acid crystals

Marcus A. Neumann、S. Craciun、A. Corval 等 7 位作者1998-03-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract Two‐proton exchange along the two hydrogen bonds mediates the tautomerization in benzoic acid (BA) dimers. Optical spectroscopy and quasi‐elastic neutron scattering (QENS) have been employed to characterize the proton dynamics in doped and pure BA crystals. The proton motion in BA is governed by a multidimens…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyQuantum, superfluid, helium dynamics

Low Overvoltage Mechanism of High Ionic Conducting Cathode for Solid Oxide Fuel Cell

Akira Endo、Sachiko Wada、Ching-ju Wen 等 5 位作者1998-03-01Journal of The Electrochemical Society

Electrochemical characteristics of three types of (LSC) and (LSM) electrodes, (dense, porous, and porous/dense double layer) were measured. The dense layers of LSC and LSM were prepared by a laser ablation method and the porous layers were prepared by a tape‐casting method. Electrochemical measurements (ac impedance a…

Perovskite Materials and ApplicationsAdvancements in Solid Oxide Fuel CellsGas Sensing Nanomaterials and Sensors