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Denaturation of bovine serum albumin under the action of cetyltrimethylammonium bromide, according to data from fluorescence analysis

И. М. Власова、V. V. Zhuravleva、А. М. Салецкий2013-05-10Russian Journal of Physical Chemistry A

The tryptophan fluorescence of bovine serum albumin (BSA) in solutions with different concentrations of cationic detergent cetyltrimethylammonium bromide (CTAB) at different pH is investigated, providing information on BSA denaturation under the action of CTAB. It is found that BSA denaturation under the action of CTA…

Lanthanide and Transition Metal ComplexesProtein Interaction Studies and Fluorescence AnalysisMethemoglobinemia and Tumor Lysis Syndrome

Fabrication and characterization of poly(methyl methacrylate)/CaCu3Ti4O12 composites

P. Thomas、R. Ravindran、K. B. R. Varma2013-05-10Polymer Engineering and Science

Composites comprising Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) via melt mixing followed by hot pressing were fabricated. These were characterized using X‐ray diffraction, thermo gravimetric, scanning electron microscopy, and Impedance analyzer for their structural, morphology, and dielectric properties.…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsDielectric properties of ceramics

Enthalpies of formation of lactams

Vladimir N. Emel′yanenko、Sergey P. Verevkin、В. В. Туровцев 等 4 位作者2013-05-10Russian Journal of Physical Chemistry A

Combustion calorimetry is used to measure the enthalpies of combustion and formation of azacyclooctan-2-one (I), azacyclononan-2-one (II), and azacyclotridecan-2-one (III) in the crystalline, liquid, and gaseous states. Conformational analysis is conducted, and quantum chemical calculations of the compounds’ enthalpie…

Thermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structurethermodynamics and calorimetric analyses

Acute and subchronic dermal toxicity ofVitex negundoessential oil

Pronobesh Chattopadhyay、Subham Banerjee、Manash Pratim Pathak 等 8 位作者2013-05-10Cutaneous and Ocular Toxicology

Vitex negundo is a common herb in different herbal formulation. The potential acute and sub-chronic dermal toxicities were evaluated as per OECD (Organization for Economic Cooperation and Development) guidelines 402 and 411, respectively. Both sexes of Wistar rats were exposed to Vitex negundo oil of 2000 mg/kg body w…

Ethnobotanical and Medicinal Plants StudiesPhytochemistry and Biological ActivitiesPhytochemistry and Bioactive Compounds

A Comparative Analysis of Austenite-to-Martensite and Austenite-to-Bainite Phase Transformation Kinetics in Steels

Martin Joachim Holzweißig、Mehmet Can Uslu、Hans Lambers 等 5 位作者2013-05-10Materials Research Letters

This paper presents a comparison of the macroscopic transformation strain evolution as a function of the bainite and martensite phase fractions in steels. Specifically, the evolution of anisotropic strain with phase fraction follows a linear trend for the martensitic transformation due to continuous stress-induced var…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMagnetic Properties and Applications

Design and development of reactive injectable and settable polymeric biomaterials

Jonathan Page、Andrew J. Harmata、Scott A. Guelcher2013-05-10Journal of Biomedical Materials Research Part A

Injectable and settable biomaterials are a growing class of therapeutic technologies within the field of regenerative medicine. These materials offer advantages compared to prefabricated implants because of their ability to be utilized as part of noninvasive surgical procedures, fill complex defect shapes, cure in sit…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

Leakage current in high dielectric oxides: Role of defect-induced energies

P. Maleeswaran、Deepthi Nagulapally、R. P. Joshi 等 4 位作者2013-05-10Journal of Applied Physics

Model evaluations of field-dependent leakage currents in the high-k dielectric oxides HfO2 and ZrO2 are presented. The treatment includes a number of competing transport processes on an equal footing. Our simulation results show that trap-assisted-tunneling, though important, is not the most significant contributor. T…

Semiconductor materials and devicesElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

Optical Response of Lorentzian Nanoshells in the Quasistatic Limit

Demet Gülen2013-05-10The Journal of Physical Chemistry B

Recently, plexcitonic systems consisting of a plasmonic nanoshell or a core covered by an excitonic shell are engineered. Such systems hold promise for tunable nanophotonic devices for imaging, chemical sensing, and resonance energy transfer. Their plasmonic response is grasped well, while understanding of their excit…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchStrong Light-Matter Interactions

Electrophoretic liquid crystal displays: how far are we?

Susanne Klein2013-05-10Liquid Crystals Reviews

We are in the middle of another revolution in information processing and distribution. After the invention of script and then print, pictures are taking over again. The number of gadgets with displays is larger than the world population. On average, every single person on earth owns at least one device with a display…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsElectrowetting and Microfluidic Technologies

Radial Microchannel Reactors (RMRs) for Efficient and Compact Steam Reforming of Methane: Experimental Demonstration and Design Simulations

Benjamin A. Wilhite、Luis Breziner、Jacques Mettes 等 4 位作者2013-05-10Energy & Fuels

This paper provides a first report of a novel radial microchannel reactor (RMR) architecture for catalytic steam reforming of methane to hydrogen and/or synthesis gas. A bench-scale RMR prototype with a channel width of 0.700 mm and wash-coated with 0.030 mm of a Ni-based catalyst is operated at 750 °C and 11 bar with…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingHeat Transfer and Optimization

Hybrid Nanocellulosome Design from Cellulase Modules on Nanoparticles: Synergistic Effect of Catalytically Divergent Cellulase Modules on Cellulose Degradation Activity

Hikaru Nakazawa、Do-Myoung Kim、Takashi Matsuyama 等 8 位作者2013-05-10ACS Catalysis

Cellulosomes, which are assemblies of cellulases with various catalytic functions on a giant scaffoldin protein with a carbohydrate-binding module (CBM), efficiently degrade solid cellulosic biomass by means of synergistically coupled hydrolysis reactions. In this study, we constructed hybrid nanocellulosomes from the…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesCatalysis for Biomass Conversion

Simple magneto–optic transition metal models for time–domain simulations

Christian Wolff、Rogelio Rodríguez–Oliveros、Kurt Busch2013-05-10Optics Express

Efficient modelling of the magneto-optic effects of transition metals such as nickel, cobalt and iron is a topic of growing interest within the nano-optics community. In this paper, we present a general discussion of appropriate material models for the linear dielectric properties for such metals, provide parameter fi…

Electromagnetic Scattering and AnalysisElectromagnetic Simulation and Numerical MethodsOptical Coatings and Gratings

Nonvolatile resistive switching behaviour and the mechanism in Nd:BiFeO3/Nb:SrTiO3heterostructure

Yongdan Zhu、Meiya Li、Zhongqiang Hu 等 7 位作者2013-05-10Journal of Physics D Applied Physics

This paper reports the bipolar resistive switching (RS) effect of the Nd 0.05 Bi 0.95 FeO 3 /Nb:SrTiO 3 heterostructure fabricated by pulsed laser deposition. This heterostructure shows a high RS ratio of over 600 at a read voltage of −0.3V after applying 5V/−8V pulse voltages. Moreover, the resistance states could be…

Ferroelectric and Piezoelectric MaterialsAdvanced Memory and Neural ComputingElectronic and Structural Properties of Oxides

Orientational order of guest molecules in aligned liquid crystal as measured by EPR and UV–vis techniques

Tatiana S. Yankova、Natalia A. Chumakova、Daria A. Pomogailo 等 4 位作者2013-05-10Liquid Crystals

Orientational order of guest molecules in aligned liquid crystal 4-cyano-4′-pentylbiphenyl (5CB) is studied via optical dichroism and electron paramagnetic resonance (EPR) spectra measurements. The guest molecules used are bifunctional molecules bearing paramagnetic nitroxide group and photochromic azobenzene moiety.…

Photochemistry and Electron Transfer StudiesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Excited Cr impurity states in Al 2 O 3 from constraint density functional theory

Yukie Kitaoka、Kohji Nakamura、Toru Akiyama 等 6 位作者2013-05-10Physical Review B

The excited states, ${}^{4}{T}_{2g}$ and ${}^{2}{E}_{g}$, of a Cr impurity in Al${}_{2}$O${}_{3}$ were treated by constraint density functional theory by imposing a density matrix constraint (constraint field) to control the electron occupation numbers of the $d$ orbitals. The calculated excitation energies, directly…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Effect of hygrothermal conditioning on the fracture toughness of carbon/epoxy composites cured in autoclave/Quickstep

Laraib Alam Khan、Ali Hasan Mahmood、Ahmed Shuja Syed 等 5 位作者2013-05-10Journal of Reinforced Plastics and Composites

The hygrothermal effect on the flexural, interfacial and glass transition behaviors of 977-2A carbon/epoxy composites cured in an autoclave and by using Quickstep were evaluated in the previous paper. This article concerns with the hygrothermal effect on the mode I and mode II delamination resistance of the samples cu…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesEpoxy Resin Curing Processes

Parallel Polymer Reactions of a Polyfluorene Derivative by Electrochemical Oxidation and Reduction

Shinsuke Inagi、Hiroyuki Nagai、Ikuyoshi Tomita 等 4 位作者2013-05-10Angewandte Chemie

Doppelt gut: Die parallele elektrochemische Oxidation und Reduktion eines einzigen Polymers (P1) ergab simultan zwei korrespondierende Polymere (P2 und P3), die einfach zu trennen waren. Bei Bestrahlung mit UV-Licht unterschieden sich die Emissionen der P2- und P3-Filme drastisch von der von P1 (links). Parallele Reak…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsRadical Photochemical Reactions

Cd(II) MOFs based on cadmium/carboxylate units and 4,4′-bis(benzoimidazol-1-yl)bibenzene: syntheses, structures, and luminescence

Hong-Jian Cheng、Miao Yu、Hong‐Xi Li 等 8 位作者2013-05-10Journal of Coordination Chemistry

Solvothermal reactions of CdCl2·2.5H2O with 4,4′-bis(benzoimidazol-1-yl)bibenzene (bimbb) and 1,4-benzenedicarboxylic acid (1,4-H2bdc), 4,4′-biphenyldicarboxylic acid (4,4′-H2bpdb), 5-methyl-1,3-benzenedicarboxylic acid (5-Me-1,3-H2bdc), or 1,3,5-benzenetricarboxylic acid (H3btc) afforded four 3-D metal–organic framew…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesX-ray Diffraction in Crystallography

Anticorrosive efficiency of ion‐exchanged bentonites in chlorinated rubber paints

Nivin M. Ahmed、Hassan S. Emira、H. Tawfik2013-05-10Pigment & Resin Technology

Purpose Ion‐exchange clays containing sodium such as bentonite and montmorillonite have the ability to exchange their cations. Few studies conducted with this type of ion‐exchange pigments are not conclusive about their anticorrosive efficiency. The present research aims to address the study on the anticorrosive effic…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisPigment Synthesis and Properties

Magnetic configurations of Co(111) nanostripes with competing shape and crystalline anisotropies

Yurii P. Ivanov、Óscar Iglesias-Freire、Е. В. Пустовалов 等 5 位作者2013-05-10Physical Review B

Nanostripes with varying widths are lithographed on Co thin films with strong magnetic anisotropy resulting from the epitaxial growth onto vicinal Si(111) substrate. The competition between magnetocrystalline and shape anisotropies is used to tune the magnetic behavior of Co nanostripes. Single domain configuration is…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsSurface and Thin Film Phenomena