Materials Literature
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Electronic structure of pulsed laser deposited hexagonal-YMnO3 film on Al2O3 (0001) substrate has been investigated by photoemission spectroscopy using variable energy photon sources. Resonance photoemission results reveal the charge transfer nature of h-YMnO3 and variation in strength of hybridization between oxygen…
Galvanic replacement reactions have been widely used to transform solution dispersed silver template structures into intricate nanoshell geometries. Here, we report on the use of these same reactions to form hollow substrate-supported Au-Ag nanoshells from silver templates having a heteroepitaxial relationship with th…
First-principle supercell calculations are used to determine how 3d elemental additions, especially Fe additions, modify the magnetization, exchange and anisotropy of L10-ordered ferromagnets. Calculations are performed using the VASP code and partially involve configurational averaging over site disorder. Three isost…
Total zerlegt: Stimuli-responsive polymere Therapeutika, die unter völligem Kettenzerfall reagieren (CSPTs), wurden durch Kondensationspolymerisation einer UV- oder H2O2-responsiven Domäne und eines Wirkstoffs als Comonomere hergestellt. Die Wirkstoff-Freisetzung lässt sich durch An- und Absetzen des Stimulus starten…
ABSTRACT A series of segmented poly(urethane‐urea) block copolymers were synthesized with varying proportions of polydimethylsiloxane diols in combination with polytetramethylene ether glycol (PTMG) using 4,4'‐methylenediphenyl diisocyanate followed by chain extension with a (50:50 mol %) mixture of 4,4'‐methylene‐bis…
The present work explores the potential use of the conjugated cationic polyfluorene {[9,9-bis(6'-N,N,N-trimethylammonium)hexyl]fluorene-phenylene} bromide (HTMA-PFP) as a fluorescent membrane marker. To this end, the interaction of the polyelectrolyte with anionic model membranes has been investigated using different…
We show the growth of high-quality epitaxial graphene on 6$H$-SiC with Raman signatures comparable to exfoliated flakes. We ascribe the remaining low-quality transport properties to the strong electron-phonon coupling to two low-energy phonon modes at 70 and 16 meV. The coupling of these modes is enhanced by the defec…
In this paper, we propose a tunable all optical switch based on metamaterial structure enhanced with metal nanocomposite layer which has adjustable optical properties and strong nonlinear Kerr effect. The results demonstrate an ultrafast, low threshold and high extinction ratio all optical switch with tunable frequenc…
Double-shell composite microcapsule with a ripened CaCO3 nanoparticle outer shell and melamine formaldehyde (MF)/copolymer inner shell shows advantages in adjustable permeability and mechanical strength, comparing with single shell microcapsules. Here, we have systematically studied the effects of certain formulation…
Abstract The impact of grafted surface of cellulose fibers on the mechanical and physical properties of fiber-cement composites (FCC) has been investigated. The grafting was performed with n-octadecyl isocyanate [i.e., with an aliphatic isocyanate (AI)], with the intention to protect the cellulose fiber from alkali de…
Abstract Sintering and consequent deactivation in supported metal catalysts is a severe problem encountered in heterogeneous catalysis. This problem can be addressed by encapsulating active metal nanoparticles within inert oxides such as silica, provided the oxide shell is porous to enable access of reactant molecules…
The aim of this research is to prepare a biomaterial to be used in health care. A series of hydrogels based on polyvinyl pyrrolidone (PVP)/κ-Carrageenan (KC) has been prepared by radiation technique. PVP (5-15%) were mixed with ΚC (2%) and irradiated by gamma rays at the doses from 25 kGy to 35 kGy (dose rate 7 kGy/h)…
We demonstrate active control of plasmonic bandgap on a metallic photonic crystal slab using thermo-optic effects. The Au grating, which is milled by focused-ion beam on a glass substrate, is designed to exhibit an extraordinary optical transmission and a sharp transitional edge for high modulation efficiency. Only a…
Shining a nanobeacon: Single-label nanobeacon sensors were constructed by using graphitic carbon nanoparticles (CNPs) and their oxides as energy acceptors (see figure; FRET=fluorescence resonance energy transfer). Excellent sensing performances were achieved with simplified operation and lowered cost.
The internal organization of a fifth-generation dendronized polymer (PG5) has been investigated by atomistic molecular dynamics simulations in a vacuum. This study reveals an exceptional behavior of PG5 within the homologous series of g-generation PGg polymers. Three molecular configurations, which present a heterogen…
Schlanke Gäste sind willkommen: Aromatische makrobicyclische Amphiphile selbstorganisieren über ihre Flächen zu dimeren Micellen, die wiederum durch laterale Assoziation poröse Schichten mit nanometergroßen Poren bilden. Die Schichten interkalieren planare Gastmoleküle und werden dabei reversibel von porösen in geschl…
We study the dispersion relations and spectra of invariant Schr\"odinger operators on a graphyne structure (lithographite). In particular, description of different parts of the spectrum, band-gap structure, and Dirac points are provided.
Pd-catalyzed Sonogashira cross-coupling reactions were used to synthesize novel π-conjugated oligothienylene-ethynylene dendrons and their corresponding terpyridine-based ligands. Their complexation with Ru(II) led to interesting novel metallodendrimers with rich spectroscopic properties. All new compounds were fully…
The intramolecular exchange interactions within the single-molecule magnet (SMM) ``butterfly'' molecule [Fe${}_{3}$Ln(${\ensuremath{\mu}}_{3}$-O)${}_{2}$(CCl${}_{3}$COO)${}_{8}$(H${}_{2}$O)(THF)${}_{3}$], where Ln(III) represents a lanthanide cation, are determined in a combined experimental [x-ray magnetic circular d…
Semicrystalline/fluorinated side-chain crystalline block copolymers, dinonylphenyl end-capped poly(ethylene glycol)- block -poly(fluorinated methyl methacrylate) (DNPEPEO- b -PFMAs), were synthesized by ATRP of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methacrylate using a surfactant poly(ethylene glyc…