Materials Literature
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Abstract The synthesis of two new monomers based on 4‐hydroxythiazoles, with a non‐classical chromophore structure similar to the luciferin dye of glowworms, is presented. These dyes are functionalized with methacrylates and copolymerized with methyl methacrylate using a RAFT polymerization process. The obtained polym…
Hydrogen shallow donors in undoped and doped ZnO systems have been studied by means of the electron paramagnetic resonance and nuclear magnetic resonance measurements. Experimental evidence is given in this work for coupling of hydrogen shallow donors and Mn ions in Mn-doped ZnO mediating short-range ferromagnetic spi…
Simultaneous measurements of work function (ϕ) and C 1s core level shift were employed to determine the change in electron affinity (χ) and band bending as a function of hole sheet density on H-terminated diamond for atmospheric and fullerene (C60F48) induced surface conductivity. Contrary to earlier investigations, i…
A detailed, chemically sensitive study of the morphology of nanocomposites prepared by melt blending of polypropylene (PP) reinforced with an organically modified nanoclay (montmorillonite 20A) and toughened with poly(styrene- b -ethylenebutylene- b -styrene) (SEBS) is reported. Polar functionalities were incorporated…
The increasing production and use of quantum dot (QD) nanoparticles have caused concerns on the possibility of contaminating the aquatic and terrestrial ecosystems with wastes that may contain QDs. Therefore, studies on the behavior of QDs upon interaction with components of the natural environment have become of inte…
In this contribution the first examples of so-called rigid-core, T-shaped imidazolium ionic liquid crystals, in which the C-2 atom of the imidazolium ring is substituted with an aryl moiety decorated with one or two alkoxy chains, are described. The length of the alkoxy chain(s) was varied from six to eighteen carbon…
DNA-templated nanoparticle (NP) chains were examined as potential magnetic resonance imaging (MRI) contrast agents using in vitro environments of the extracellular matrix and tissue. A 3-T clinical MRI scanner was utilized to examine and compare image contrast enhanced by dispersed NPs, DNA-templated NP chains, gold-s…
Abstract Poly(butylene succinate) (PBS)/organoclay nanocomposites were prepared by both solution blending and melt mixing methods. In addition, nanocomposites of PBS/organoclay were also prepared by a two‐step process where the solution blended mixture is subsequently compounded in the melt state using a torque rheome…
4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) as a fluorescent label can be incorporated into DNA by two conceptually different ways: the non-nucleosidic DNA base surrogate Bo exhibits high brightness but no preferential base-pairing properties, whereas the BODIPY-modified uridine BodU has reduced quantum yields…
Conductive atomic force microscope (cAFM) nanopatterning is demonstrated on epitaxial graphene on SiC (0001) under ambient conditions. Nanopatterning kinetics and chemistry suggest that ambient cAFM nanopatterning induces local oxidization with the surface, interface, and bulk layers of epitaxial graphene on SiC (0001…
Thermal conductivity of chalcogenide material with superlatticelike (SLL) structure is investigated using the 3ω method and the molecular dynamics method. Both the measured and calculated results show that the thermal conductivity of SLL is lower than those of conventional chalcogenide materials and will decrease to a…
In this study, poly[2-(4′-vinylphenyl)-3,4,5-triphenylthiophene] (PTP) with pendant tetraphenylthiophene (TP) groups was synthesized to study its aggregation-induced emission (AIE) property. The solution emission spectra of the PTP nanoaggregates contain discernible monomer and aggregate bands with their relative inte…
Abstract A series of Fe(III), Co(II) and Cu(II) complexes of 8‐quinolinol were encapsulated into the supercages of zeoliteY and characterized by X‐ray diffraction, SEM, N 2 adsorption/desorption, FT‐IR, UV–vis spectroscopy, elemental analysis, ICP‐AES and TG/DSC measurements. The encapsulation was achieved by a flexi…
The absent critical thickness of fully relaxed asymmetric ferroelectric tunnel junctions is investigated by first-principles calculations. The results show that PbTiO3 thin film between Pt and SrRuO3 electrodes can still retain a significant and stable polarization down to thicknesses as small as 0.8 nm, quite unlike…
Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14π-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.
We demonstrate large and reversible tuning of plasmonic properties of gold nanoparticles mediated by the reversible breaking and making of linear and branched chains of gold nanoparticles adsorbed on an ultrathin (1 nm) responsive polymer film. Atomic force microscopy revealed that at pH below the isoelectric point of…
This work tried to identify the relationship between the internals of selective catalytic reduction (SCR) system and mixing performance for controlling ammonia (NH(3)) slip. In the SCR flow section, arranging the flow-guided internals can improve the uniformity of velocity distribution but is unfavorable for the unifo…
Abstract The triggered assembly of organic and biological materials in response to imposed electrical signals (i.e., electroaddressing) provides interesting opportunities for applications in molecular electronics, biosensing and nanobiotechnology. Recent studies have shown that the conjugation of aromatic moieties to…
A novel crosslinked conductive polyaniline (PANI) was prepared by chemically copolymerizing aniline (An) and p-phenylenediamine (PPDA) with triphenylamine (TPA) as crosslinker, using ammonium peroxydisulfate (APS) as an oxidant. The effects of different preparation conditions on the electrical conductivity of polymers…
I want to break free: A photoactivatable split intein can be genetically fused to a protein of interest and used in potentially general ways to relay a phototrigger in a coupled fashion (see picture). The protein staphylocoagulase can be unmasked by light and thereby activates native prothrombin.