Materials Literature
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Abstract The hyperfine interactions in indium‐tin‐oxide were studied by 119 Sn Mössbauer spectroscopy. Polycrystalline samples with tin contents from 0.5 to 10 at% Sn on the cation sublattice were measured and compared to the results of 111 In and 111m Cd Perturbed Angular Correlation measurements. The Mössbauer data…
Abstract Thin composite laminates based on melamine‐formaldehyde (MF) and cellulose are made electrostatically dissipative or conductive by addition of carbon black (CB). CB in an ethanol dispersion was applied to MF sheets containing α‐cellulose. Areas around cellulose fibers are favored sites for CB and during subse…
Vanadia gels and vanadium-molybdenum oxide gels were investigated using the magnetic resonance techniques, EPR spectroscopy and (51)V MAS NMR spectroscopy. The vanadium oxide gels were derived from the reaction of H(2)O(2) and V(2)O(5), and the vanadium-molybdenum oxide (VMoO) gels were derived from the reaction of pe…
Infrared reflection absorption spectroscopy (IRAS) has been used to study CO-NO and CO-O(2) interactions on Cu(100) between 25 and 200 K. A strong repulsive interaction between CO and NO on Cu(100) at 25 K causes tilting of the CO molecules away from the surface normal and a blue-shift of the CO vibrational frequency.…
Many organelle enzymes coded for by nuclear genes have N-terminal sequences, which directs them into the organelle (precursor) and are removed upon import (mature). The experiments described below characterize the differences between the precursor and mature forms of watermelon glyoxysomal malate dehydrogenase. Using…
The effects of annealing on the crystal structure and magnetic properties of Co-rich cobalt platinum nanowire arrays embedded in anodic aluminium oxide membranes have been investigated. For this purpose, a rapid thermal annealing to temperatures of 300°Cto800°C has been used. Transmission electron microscopy and scann…
For the first time, attenuated total reflection (ATR)-Fourier transform infrared (FT-IR) spectroscopy was utilized to measure the thickness (d0) of a nanoscale polymer layer on polymer substrate with significant credibility. First, a mathematical formula, A/A0 = 1 - 2d0/ d(p), was derived based on a self-defining subs…
[BDTA]2[Cu(mnt)2] (BDTA = benzo-1,3,2-dithiazolyl, mnt = maleonitriledithiolate) was crystallized in the space group P with an inversion center on Cu giving a stacked structure with each metal complex anion sandwiched by two cations. Short intermolecular S...S contacts give rise to a one-dimensional chain lateral to t…
Reactions of Ln(BH4)3(THF)3 (Ln = Nd, Ce) and M2dddt (M = Na, K; dddt = 5,6-dihydro-1,4-dithiine-2,3-dithiolate) in THF or pyridine gave, after addition of 18c6 (18-crown-6), several crystalline compounds which all contain the tris(dithiolene) Ln(dddt)3 unit. Crystals of [Na(18c6)(py)2]2[Na(18c6)(py)][Nd(dddt)3(py)].3…
Magnon excitation in a ferromagnetic state of Sm(0.55)Sr(0.45)MnO(3) located on the verge of the metal-insulator transition has been studied in terms of the neutron scattering experiment. The anomalous magnon dispersion with the zone-boundary softening is well described by the Heisenberg model with extended exchange c…
Bi 4 − x La x Ti 3 O 12 (La-doped BIT, x=0–0.6) thin films prepared by metalorganic decomposition method, were studied using x-ray diffraction (XRD), polarization hysteresis and Raman scattering techniques. The XRD and polarization studies showed that La substitution reduces structural distortion, relaxes internal str…
Abstract Smoluchowski's coagulation theory is adopted to estimate the induction period for the formation of the critical nuclei of CaCO 3 in a supersaturated CaCl 2 ‐Na 2 CO 3 aqueous solution. The effects of the presence of impurity and crystal seeds, degree of supersaturation and operating temperature on the inducti…
The formation of all major intermediates in the reaction catalyzed by the citrate synthase from Thermoplasma acidophilum is accompanied by changes in tryptophan fluorescence. The largest change is the strong quenching observed on formation of the binary complex with substrate, oxaloacetate (OAA). The four tryptophan r…
Cholic acid (CA) forms inclusion crystals that have a sandwich-type lamellar structure constructed by the alternative stacking of host bilayers and guest layers. Five disubstituted benzenes, o-toluidine, m-fluoroaniline, o-chlorotoluene, o-bromotoluene, and indene, are accommodated in the two-dimensional void space be…
Reaction of UCl4 with 3 or 4 mol equiv of Na2dddt (dddt = 5,6-dihydro-1,4-dithiine-2,3-dithiolate) in THF afforded the first example of a tetrakis(dithiolene) metal compound, [Na4(THF)8U(dddt)4](infinity) (1). The red crystals of 1 are composed of infinite zigzag chains in which Na2(micro-THF)3 fragments ensure the li…
Abstract The blending and barrier properties of the MPAEVOH blends of modified polyamide (MPA) and ethylene vinyl alcohol copolymer (EVOH) were systematically investigated in this study. After blending MPA in EVOH resin, a noticeable “negative deviation” was found on the plot of the oxygen permeation rate versus MPA c…
The fermentation of beta-alanine by Clostridium propionicum proceeds via activation to the CoA-thiol ester, followed by deamination to acryloyl-CoA, which is also an intermediate in the fermentation of l-alanine. By shifting the organism from the carbon and energy source alpha-alanine to beta-alanine, the enzyme beta-…
The (17)O NMR spectrum of CaAl(2)Si(2)O(8) glass shows two types of O sites that are not present in the crystalline material. One of these, with (17)O NMR parameters C(Q) = 2.3 MHz and delta = +20 ppm, has been assigned to a "tricluster" O, a local geometry in which the O is coordinated to three tetrahedrally coordina…
The role of individual matrix proteins in avian eggshell calcification is poorly understood despite numerous attempts to characterize and localize their presence in the eggshell matrix. Ansocalcin, the major matrix protein from goose eggshell, was found to induce the formation of calcite crystal aggregates under in vi…
Polythioesters (PTEs) represent a novel class of biopolymers, which basically can be synthesized with polyhydroxyalkanoate (PHA) biosynthesis systems. Albeit technical applications of PTEs have not been elucidated yet, biodegradability might be an important property of this new thermoplastic material. In this study, e…