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Direct oxidation of H2 to H2O2 over PdO/Al2O3 catalysts in aqueous acidic medium: Influence on H2O2 formation of Pd loading, calcination temperature and reduction of catalyst and presence of halide anions

Vasant R. Choudhary、Prabhas Jana2008-06-01Catalysis Communications

Effects of the Pd loading (0.2–10 wt%), calcination temperature (400–900 °C) and reduction of PdO/Al 2 O 3 on its performance in the H 2 -to-H 2 O 2 oxidation (with H 2 /O 2 = 1:1) in an aqueous 0.1 M H 3 PO 4 medium, in the absence and presence of different halide anions, under ambient conditions have been investigat…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Detection of stress corrosion cracking in a simulated BWR environment by combined electrochemical potential noise and direct current potential drop measurements

Stefan Ritter、H.P. Seifert2008-06-01Energy Materials

Stress corrosion cracking (SCC) is one of the most important degradation mechanisms in light water reactor structural materials. In situ corrosion monitoring tools with the capability to detect SCC initiation in high temperature water environments would be important to identify critical conditions; the measurement of…

Hydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing TechniquesMaterial Properties and Failure Mechanisms

The effect of the structure of aliphatic diamines on their interaction with zinc porphyrinates

G. M. Mamardashvili、О. М. Куликова、Н. Ж. Мамардашвили 等 4 位作者2008-06-01Russian Journal of Coordination Chemistry

The complex formation of zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethylporphyrinate, 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28-dihydroxycalic-[4]-arene, and 5,17-bis(zinc 2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylporphyrinate)-25,27-dimethoxy-26,28…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Study on Synthesis and Mechanism of Melt Polymerization of L-lactic Acid

Lijing Wang2008-06-01Journal of Fiber Bioengineering and Informatics

A two steps direct polymerization process was developed. The first step is to produce oligomer and then the oligomer of lactic acid is polymerized with binary catalyst tin chloride dihydrate/ p-toluenesulfonic acid. In this way, the direct synthesis of poly (lactic acid)(PLLA) without any organic solvents was investig…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Novel Preparation of Polyethylene from Nano‐extrusion Polymerization Inside the Nanochannels of MCM‐41/MgCl2/TiCl4Catalysts

Mohammad Ali Semsarzadeh、Alireza Aghili2008-06-01Journal of Macromolecular Science Part A

The MCM‐41 and SiO2 supported TiCl4 and TiCl4/MgCl2 catalysts with different molar ratios of Mg/Ti were synthesized and used for ethylene polymerization under atmospheric pressure. The nanochannels of MCM‐41 serve as nanoscale polymerization reactor and the polyethylene nanofibers were extruded during the reaction. Th…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchPolymer Nanocomposites and Properties

Microstructural characteristics of Nd2Fe14B/α-Fe nanocomposite ribbons bearing Nb element

Zhenwei Wang、Weiwei Liu、Baochun Zhou 等 6 位作者2008-06-01Rare Metals

The effects of Nb on the microstructure and magnetic properties of (Nd0.9Dy0.1)9.5Fe79-xCo5NbxB6.5 (x = 0, 1) nanocomposite magnets were investigated. A fine and uniform microstructure was achieved for the ribbons annealed at 710°C for 4 min, enhancing the interaction coupling between grains and improving the magnetic…

Magnetic properties of thin filmsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Contact angle and surface free energy of electron-beam irradiated polymer composites

M. Żenkiewicz、Piotr Rytlewski、JOANNA CZUPRYNSKA 等 6 位作者2008-06-01Polimery

The effects of the electron radiation dose and of compatibilizers on the contact angle and surface free energy (SFE) of the composites made of low-density polyethylene (PE-LD), high-density polyethylene (PE-HD), polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET) were studied. Use of the high-en…

Recycling and Waste Management TechniquesElectron and X-Ray Spectroscopy TechniquesPolymer Nanocomposite Synthesis and Irradiation

Na8.25Y1.25Si6O18 and its family of zwölfer ring silicates

Daniel M. Többens、Volker Kahlenberg、Reinhard Kaindl 等 5 位作者2008-06-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The crystal structure of a sodium yttrium silicate with nominal composition Na 9 YSi 6 O 18 was determined from laboratory X-ray powder diffraction. The actual composition of the crystals was found to be Y-enriched, and a corrected nominal composition of Na 8.25 Y 1.25 Si 6 O 18 was established. The compound…

Glass properties and applicationsCrystal Structures and PropertiesNuclear materials and radiation effects

Eduction Position Control of Incorporated Gallium in Diamond-Like Carbon Deposited by Focused-Ion-Beam Chemical Vapor Deposition

Reo Kometani、Sunao Ishihara、Kazuhiro Kanda 等 6 位作者2008-06-01Japanese Journal of Applied Physics

Materials deposited by focused-ion-beam chemical vapor deposition (FIB-CVD) have numerous interesting material characteristics. They contain gallium (Ga) because Ga is implanted by Ga + FIB irradiation. Atomic ratios of the diamond-like carbon (DLC) deposited using phenanthrene (C 14 H 10 ) as a gas source for FIB-CVD…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Quantitative analysis of correlation between insulator surface copper contamination and TDDB lifetime based on actual measurement

Daisuke Oshida、T. Takewaki、Manabu Iguchi 等 11 位作者2008-06-01OpenAlex

We have analyzed the correlation between insulator surface copper contamination and time-dependent dielectric breakdown (TDDB) quantitatively for the first time. TDDB lifetime strongly depends on the copper contamination after CMP process, and it is important to control the redox potential to be less than -0.5 V vs. N…

Corrosion Behavior and InhibitionHigh voltage insulation and dielectric phenomenaCopper Interconnects and Reliability

Fabrication of Permittivity Graded Materials for Reducing Electric Stress on Electrode Surface

Muneaki Kurimoto、Akihiro Kai、K. Kato 等 4 位作者2008-06-01OpenAlex

For the size reduction of electric power equipment, an increase of electric field stress around solid insulators is carefully to be considered. The application of FGM (Functionally Graded Materials) with spatial distribution of dielectric permittivity (epsiv-FGM) will be an effective solution for this concern. In this…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Improvement of Contamination Flashover Voltage Performance of Cylindrical Porcelain Insulators

Kimio YAMADA、Akio Hayashi、Chiharu Saka 等 5 位作者2008-06-01OpenAlex

Superior contamination flashover voltage performance of polymer insulators for transmission or distribution line is attributable not only to the hydrophobicity of silicone rubber housing material but also to their configurations. In the case of transmission or distribution line polymer insulators, core diameters are s…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationThermal Analysis in Power Transmission

The crystal chemistry of the gedrite-group amphiboles. II. Stereochemistry and chemical relations

F. C. Hawthorne、Michael Schindler、Y. A. Abdu 等 6 位作者2008-06-01Mineralogical Magazine

Abstract The general formula of the amphiboles of this series may be written as Na x Mg 2 (Mg (5- y ) Al y ,)(Si (8- z ) Al z )O 22 (OH) 2 , where Mg = Mg + Fe 2+ + Mn 2+ and Al = Al + Fe 3+ + Ti. The individual < T –O> distances are linear functions of their [4] Al content, and the [4] Al content is strongly or…

Crystal Structures and PropertiesClay minerals and soil interactionsNuclear materials and radiation effects

Effect of calcium carbonate particle size and surface pretreatment on polyurethane composite Part 2 – phase behaviour

Domagoj Vrsaljko、Ivan Šmit、Vera Kovačević2008-06-01Materials Research Innovations

Effects of untreated calcium carbonate (CaCO3) of different sizes, and silane pretreated CaCO3 fillers on properties of polyurethane (PU) composites (PU/CaCO3) were investigated. Small angle X-ray scattering research of phase structure and morphology has shown significantly stronger influence of the CaCO3 nanofillers…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Effect of Phase Change Materials on Temperature and Moisture Distributions in Clothing during Exercise in Cold Environment

S X Wang、Yi Li、H. Tokura 等 9 位作者2008-06-01Research Explorer (The University of Manchester)

This paper reports a study on the effect of phase change material (PCM) in design of cold protective clothing. Two clothing systems with the same structural design, one was smart clothing (clothing C) was treated with PCM, the other one was moisture management clothing (clothing B), were tested in a climate chamber wh…

Thermoregulation and physiological responsesDyeing and Modifying Textile FibersTextile materials and evaluations

A Thermogravimetric Study of Cotton Fabric Flame‐Retardancy by Means of Impregnation with Red Phosphorus

S. M. Mostashari、Fatemeh Fayyaz2008-06-01Chinese Journal of Chemistry

Abstract The effect of red phosphorus was found to be effective for flame‐retardancy of a pure cotton fabric. The laundered bone‐dried weighed samples were impregnated with red phosphorus at suitable concentrations. Vertical flame spread test was accomplished. The optimum add‐on value to impart flame‐retardancy onto c…

Fire dynamics and safety researchFlame retardant materials and propertiesThermal and Kinetic Analysis

High-pressure Synthesis and Crystal Structure of the Vanadium Orthoborate VBO3

Almut Haberer、Hubert Huppertz2008-06-01Zeitschrift für Naturforschung B

The vanadium orthoborate VBO 3 was synthesized under high-pressure / high-temperature conditions of 7.5 GPa and 1250 °C in a Walker-type multianvil apparatus. The crystal structure was determined on the basis of single crystal X-ray diffraction data, collected at r. t. The title compound crystallizes in the trigonal c…

Crystal Structures and PropertiesRadioactive element chemistry and processingX-ray Diffraction in Crystallography

CORROSION OF CARBON-STEEL ALLOY IN 0.1M NITRIC ACID IN PRESENCE OF PLASTIC WASTE AS CORROSION INHIBITORS

Reda Abdel‐Hameed、Husein S. Ismail2008-06-01Al-Azhar Bulletin of Science

Recyclization of poly (ethyleneterphthalate), (PET), with Diethanolamine and Triethanolamine having 1:2 wt% of PET: wt% of DEA or wt% TEA, in presence of manganese acetate as a catalyst. The inhibition action of the prepared compounds (D2 & T2) on the corrosion of carbon-steel which used in the manufacture of petroleu…

Corrosion Behavior and Inhibition

Overview of Polymer Nanocomposites as Dielectrics and Electrical Insulation Materials for Large High Voltage Rotating Machines

Zhengyi Han、Randy Garrett2008-06-01OpenAlex

Polymer nanocomposites are defined as polymers in which small amounts of nanometer size filers are homogeneously dispersed and will have a potential significant impact on materials mechanical, electrical and thermal properties etc. In power industry, electrical insulating polymers usually incorporate inorganic fillers…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

High Frequency Life Testing of Stator Coil Insulation

D. Manns、Steven Galioto、K. Weeber 等 4 位作者2008-06-01OpenAlex

This paper focuses on the development of insulation systems for high-speed and hence high-frequency electric motors with multi-MW ratings. With the growing demand for variable speed applications, an increasing number of medium and high voltage (4-13.8 kV) motors are being powered by adjustable speed drives (ASD's). On…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques