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Templateless Synthesis of Nanoporous Gold Sponge with Surface-enhanced Raman Scattering Activity

Hamed Ataee‐Esfahani、Naoki Fukata、Yusuke Yamauchi2010-03-06Chemistry Letters

Abstract We demonstrate templateless synthesis of nanoporous gold (Au) sponge by chemical reduction of Au species in aqueous solution. The obtained Au nanosponges exhibit surface-enhanced Raman scattering activity.

Nanocluster Synthesis and ApplicationsNanomaterials for catalytic reactionsNanoporous metals and alloys

Stress corrosion cracking of sensitized austenitic stainless steels in Kuwait petroleum refineries

A. Almubarak、M. Belkharchouche、Afzal Hussain2010-03-06Anti-Corrosion Methods and Materials

Purpose The purpose of this paper is to investigate stress corrosion cracking (SCC) for 304, 316, and 321 stainless steels in petroleum‐processing environments. Design/methodology/approach Sensitized austenitic stainless steels were subjected to a microstructure investigation and electrochemical test. Stressed sensiti…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Development of a high performance hybrid epoxy silicone resin for coatings

P. Bajpai、Manish Kumar Bajpai2010-03-06Pigment & Resin Technology

Abstract Purpose – The purpose of this paper is to develop a novel organic‐inorganic (epoxy‐silicone) hybrid resin for application in heat resistant surface coatings. Design/methodology/approach – Thermally stable aminosilicone resin was prepared by using diethoxydimethyl silane and γ‐aminopropyldiethoxy methyl silane…

Polymer composites and self-healingSynthesis and properties of polymersSilicone and Siloxane Chemistry

Reduction of high reset currents in unipolar resistance switching Pt/SrTiOx/Pt capacitors using acceptor doping

S. B. Lee、A. Kim、J. S. Lee 等 10 位作者2010-03-06arXiv

The high reset current, IR, in unipolar resistance switching is an important issue which should be resolved for practical applications in nonvolatile memories. We showed that,during the forming and set processes, the compliance current, Icomp, can work as a crucial parameter to reduce IR. Doping with Co or Mn can sign…

Materials Science

Magnetoresistance studies of $La_{2/3} Sr_{1/3} MnO_3$ - $YBa_2 Cu_3 O_7$ - $La_{2/3} Sr_{1/3} Mn O_3$ trilayers with ferromagnetic coupling along the nodal direction of $YBa_2 Cu_3 O_7$

Soumen Mandal2010-03-06arXiv

I have successfully prepared (110) trilayers of \LSMO-\YBCO-\LSMO. Magnetization measurements on these samples reveal a stronger coupling between the ferromagnetic layers. The coupling is an order of magnitude higher than that seen in the case of (001) trilayers. Magnetoresistance measurements show a first order trans…

Materials ScienceSuperconductivity

Synthesis, Crystal Structure and Vibrational Spectra of Barium Cyclotetraphosphate Hydrate Ba2(P4O12)∙3.5H2O

Henning A. Höppe、Karolina Kazmierczak、Michael Daub2010-03-05Zeitschrift für anorganische und allgemeine Chemie

Abstract Barium tetrametaphosphate hydrate Ba 2 (P 4 O 12 )∙3.5H 2 O was synthesized as a single‐phase crystalline powder starting from an aqueous solution of barium hydroxide and phosphorus pentoxide at 300 K. Ba 2 (P 4 O 12 )∙3.5H 2 O crystallizes in a new structure type in which…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesChemical Synthesis and Characterization

Synthesis, characterization and single crystal structure determination of aluminum alkoxydisilanolates: precursors for silica–alumina composite

Mostafa M. Amini、Gholamhossein Mohammadnezhad、Mahdi Mirzaee 等 4 位作者2010-03-05Applied Organometallic Chemistry

Abstract Several novel aluminum alkoxydisilanolate complexes were prepared by reaction of triphenylsilanol with aluminum 2‐methoxyethoxide, aluminum 2‐ethoxyethoxide, aluminum sec ‐butoxide and aluminum iso ‐propoxide. All new complexes, [(Ph 3 SiO) 2 Al(OR)] 2 [where R = CH 2 CH 2 OCH 3 (1), CH 2 CH 2 OC 2 H 5 (2), C…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Electrospinning of Heparin Encapsulated P(LLA-CL) Core/Shell Nanofibers

Feng Chen、Peng Huang、Xiumei Mo2010-03-05Nano Biomedicine and Engineering

Coaxial electrospinning was developed for simultaneously electrospinning two different polymer solutions into core/shell nanofibers, or encapsulated bioactive molecular and drugs into polymer nanofibers for controlled release.In this study, heparin encapsulated poly(L-lactic acid-co-ε-caprolactone) [P(LLA-CL)] core/sh…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsTissue Engineering and Regenerative Medicine

Large pretilt angle induced by an anhydride-terminal hyperbranched polyimide liquid crystal alignment layer

Zhen Sun、Ailin Qin、Zihua Chen 等 4 位作者2010-03-05Liquid Crystals

Through the polycondensation of a four-functional amine with pyromellitic dianhydride, a hyperbranched polyimide (HPI) was synthesised in this study. The HPI was used for liquid crystal alignment layers. Wide angle X-ray diffraction measurement showed that the HPI film was amorphous. The morphology of the surface laye…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchSynthesis and properties of polymers

Design and analysis of vibration test bed fixtures for space launch vehicles

T. Srinivas Reddy2010-03-05Indian Journal of Science and Technology

Space Launch Vehicles are subjected to rigor dynamic environment during lift-off and ascent phase of launch. The intense sound generated by the rocket propulsion system exerts significant acoustic pressure which induces vibrations. In addition, intense vibrations are generated by space propulsion engine ignitions, shu…

Structural Analysis and OptimizationSilicone and Siloxane ChemistrySpacecraft Design and Technology

Effective insulator maintenance scheduling using artificial neural networks

D.C. Karamousantas、George E. Chatzarakis、D. S. Oikonomou 等 5 位作者2010-03-05IET Generation Transmission & Distribution

One of the most frequent causes of failure of overhead high- and medium-voltage transmission and distribution lines is contamination of the insulators with diverse substances such as saline and industrial substances. The contamination mechanically degrades the insulators and affects the electrical characteristics of t…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationInfrastructure Maintenance and Monitoring

The nature of intermediate-range order in Ge–As–S glasses: results from reverse Monte Carlo modeling

Sezen Soyer‐Uzun、Chris J. Benmore、Joan Siewenie 等 4 位作者2010-03-05Journal of Physics Condensed Matter

The experimental neutron and x-ray diffraction data for stoichiometric and S-deficient Ge(x)As(x)S(100-2x) glasses with x = 18.2, 25.0, and 33.3 at.% have been modeled simultaneously using the reverse Monte Carlo (RMC) technique. Nearest-neighbor coordination environments, as obtained in previous x-ray absorption spec…

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Electronic phase diagram ofNdFe1−xRhxAsO

David Bérardan、Li‐Dong Zhao、L. Pinsard-Gaudart 等 4 位作者2010-03-05Physical Review B

We report on the electrical resistivity, thermoelectric power, and electronic phase diagram of rhodium-doped NdFeAsO. Rhodium doping suppresses the structural phase transition and spin-density wave observed in the undoped material, and superconductivity emerges at $x$ close to 0.05, despite the distortion of ${\text{F…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Enhanced Photoluminescence Features of Rare Earth Phenylphosphonate Hybrid Nanostructures Synthesized under Nonaqueous Conditions

Weihua Di、Rute A. S. Ferreira、Marc‐Georg Willinger 等 5 位作者2010-03-05The Journal of Physical Chemistry C

A novel nonaqueous route was applied for the synthesis of rare earth phenylphosphonate hybrid nanostructures by reacting rare earth chlorides with phenylphosphonic acid in benzyl alcohol. Powder X-ray diffraction and transmission electron microscopy studies reveal the ordered lamellar structure, with an interlayer dis…

Radioactive element chemistry and processingLanthanide and Transition Metal ComplexesChemical Synthesis and Characterization

Synthesis and luminescence of CePO4:Tb/LaPO4core/sheath nanowires

Yuebin Li、Zhong Sun、Lun Ma 等 8 位作者2010-03-05Nanotechnology

CePO(4):Tb/LaPO(4) nanowires with a core/sheath architecture have been successful synthesized by a facile aqueous chemical method mediated by original CePO(4):Tb aggregation seeds. The seed crystals serve as both a luminescence center and a nucleation site for epitaxial growth. The seed nanocrystals have an irregular…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Volatile Organic Compound Sensing by Quartz Crystal Microbalances Coated with Nanostructured Macromolecular Metal Complexes

Mutsumi Kimura、Masato Sugawara、Seiko Sato 等 5 位作者2010-03-05Chemistry - An Asian Journal

We report the construction of a molecular recognition layer composed of polyelectrolyte brushes and metal complexes on the surface of a quartz crystal microbalance (QCM) and the sensing abilities for various volatile organic compounds (VOCs). Atom-transfer radical polymerization of 2-(dimethylamino)ethyl acrylate from…

Polymer Surface Interaction StudiesAcoustic Wave Resonator TechnologiesLuminescence and Fluorescent Materials

Generalized Brillouin diagrams for evanescent waves in metamaterials with interelement coupling

E. Tatartschuk、A. Radkovskaya、E. Shamonina 等 4 位作者2010-03-05Physical Review B

A graphical representation for two-dimensional periodic structures is introduced that provides the full information contained in the dispersion equation: not only for the pass band but for the neighboring stop bands as well. It is a seamless natural extension of Brillouin diagrams obtained by adding eight new zones wh…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium−Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−

Minghuey Shieh、Chia-Hua Ho、Wen-Shyan Sheu 等 4 位作者2010-03-05Journal of the American Chemical Society

The facile synthesis of a novel electron-precise paramagnetic hexamanganese carbonyl selenide cluster [Se(6)Mn(6)(CO)(18)](4-) (1) was discovered, which demonstrates contrasting reactivity toward O(2) and Se(8) under markedly mild conditions to afford the O- and Se-inserted clusters [Se(6)Mn(6)(CO)(18)(O)](4-) (2) and…

Magnetism in coordination complexesMetalloenzymes and iron-sulfur proteinsNanocluster Synthesis and Applications

Exploitation of a Chain‐End‐Control Mechanism for the Synthesis of Alternating Copolymers

Jean‐François Carpentier2010-03-05Angewandte Chemie International Edition

Smart catalysts for new materials: A syndiospecific yttrium catalyst that operates by a chain-end-control mechanism enabled the highly alternating ring-opening polymerization of a mixture of two different enantiomerically pure 4-substituted β-propiolactones of opposite absolute configuration (see scheme). This strateg…

biodegradable polymer synthesis and propertiesSynthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysis

ZnO:Sb/ZnO:Ga Light Emitting Diode onc-Plane Sapphire by Molecular Beam Epitaxy

Zheng Yang、Sheng Chu、Winnie V. Chen 等 8 位作者2010-03-05Applied Physics Express

p-type Sb-doped ZnO (ZnO:Sb)/n-type Ga-doped ZnO (ZnO:Ga) junctions were grown on c -plane sapphire substrates using plasma-assisted molecular-beam epitaxy. Mesa geometry light emitting diodes (LEDs) were fabricated using standard photolithography and lift-off process, with ohmic contacts achieved using Au/Ni and Au/T…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials