Materials Literature
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We report on a joint experimental–theoretical study of collective diffusion in, and static shear viscosity of solutions of bovine serum albumin (BSA) proteins, focusing on the dependence on protein and salt concentration. Data obtained from dynamic light scattering and rheometric measurements are compared to theoretic…
The stoichiometric reaction of the salicylaldimine derivatives (L1-L12) with trimethylaluminium afforded the corresponding dimethylaluminium aldiminophenolates (C1-C12), which were fully characterized by NMR spectroscopy and elemental analysis. The molecular structures of the representative complexes C1, C6, and C8 we…
We have successfully developed a facile two-step anodization combined layer-by-layer (LBL) self-assembly route for rapid fabrication of well-defined metal-TiO(2) nanoring/nanotube combined nanostructures, i.e. M/T-NRNT (M = Au, Ag, Pt). These hierarchically self-assembled hybrid systems are demonstrated to exhibit ver…
A synergistic graphene-based catalyst was engineered by the in situ growth of "naked" Au-nanoparticles (NPs) on graphene sheets. The catalyst exhibits excellent switchable peroxidase-like activity in response to specific DNA.
The reaction of Na/K-reduced graphite with hexyliodide represents a new, versatile and mild approach to synthesize alkylated graphene derivatives, which were characterized by a combination of Raman spectroscopy, TEM and TGA/MS analysis.
A fast, linker free, one step strategy for in situ preparation of graphene oxide/Ag nanoparticle (GO-AgNP) nano-composites was proposed by reducing AgNO3 with chemiluminescent reagent luminol in the presence of GO. The nano-composites were characterized by transmission electron microscopy, energy-dispersive spectrosco…
Two linear tetranuclear lanthanide complexes of general formula [Ln(4)(L)(2)(C(6)H(5)COO)(12)(MeOH)(4)], where HL = 2,6-bis((furan-2-ylmethylimino)methyl)-4-methylphenol, () and Ln(III) = Dy(III) (1) and Gd(III) (2), have been synthesized and characterized. The crystal structural analysis demonstrates that two Schiff-…
Triple-shape memory polymers are developed by blending and crosslinking two semicrystalline polymers (poly(cyclooctene), PCO, and polyethylene, PE) towards creating two pronounced segregated crystalline domains within a covalently crosslinked network. The key thermo-mechanical properties of a series of a polyalkenamer…
The present study demonstrates a novel approach by which titanium foils coated with MnO2 nanowires can be processed into a high surface area electrode for rechargeable energy storage applications. A detailed study has been performed to elucidate how surface morphology and redox reaction behaviors underlying these elec…
National Natural Science Foundation of China [21074103]; Natural Science Foundation of Fujian Province [2010J05033]; Fundamental Research Funds for the Central Universities [2010121018]
CoFe(2)O(4) nanotubes have been directly fabricated by single-capillary spinneret electrospinning. The external diameter of the CoFe(2)O(4) nanotubes ranges from 60 nm to 160 nm. The morphology and structure characterizations show that individual CoFe(2)O(4) nanotubes are made of CoFe(2)O(4) nanocrystals stacking alon…
Here we report the synthesis, electrochemical properties, and optical properties of five novel π-conjugated alternating copolymers based on the BODIPY core. These polymers were synthesized via the Sonogashira polymerization reaction and contain BODIPY units alternating with comonomers such as 9,9-bis(2-ethylhexyl)-9H-…
The well-defined metal NPs@POM–GNS tri-component nanohybrids were synthesized by a green, facile, one-pot method. The obtained nanohybrids exhibited exciting electrocatalytic activity for methanol and formic acid oxidation.
For the very first time, highly efficient synthesis of DNA-peptide hybrids to scaffold self-assembled nanostructures is described. Oligonucleotide conjugation to the diphenylalanine dipeptide triggers a morphological transition from fibrillar to vesicular structures which may potentially be used as delivery vehicles,…
The programs hosted in the Bilbao Crystallographic Server (http://www.cryst.ehu.es) are briefly explained along with worked examples on various cases related to different fields of applications. It is our aim to have this text acting as a primer on the various usage of the crystallographic tools in conjunction with ea…
Ammonia borane (NH(3)BH(3), AB) is a unique molecular crystal containing an intriguingly high density of hydrogen. In the past several years, AB has received extensive attention as a promising hydrogen storage medium. Several strategies have been successfully developed for promoting H(2) release and for suppressing th…
The ability to control the morphologies and spectral properties of organic low-dimensional nanomaterials is of paramount importance. The research reported herein demonstrates a template-free approach to tailored morphological and optical properties for a novel class of pseudoisocyanine (PIC)-based fluorescent organic…
This review summarizes the recent developments in fluorescent conjugated polyelectrolytes (CPEs) in bioimaging. The CPEs discussed include linear-, hyperbranched-, and polyhedral oligomeric silsesquioxanes (POSS)-based derivatives. Originating from their special optical properties, good photostability, low cytotoxicit…
A functionalized six-membered cyclic carbonate monomer containing a protected thiol group, 2-(2,4-dinitrophenylthio)ethyl-5-methyl-2-oxo-1,3-dioxane-5-carboxylate (MTC), was prepared. Ring-opening polymerization (ROP) of MTC and L-lactide (LA) initiated by monohydroxyl poly(ethylene glycol) (mPEG) was successfully per…
Carbonaceous nanospheres with silver nanoparticles (CNs-Ag) composites were prepared by a facile and low cost method. Silver nanoparticles were successfully loaded onto the surface of carbonaceous nanospheres, which were examined by X-ray diffraction, UV-vis spectra, transmission electron microscopy, energy dispersive…