Materials Literature
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Experiments show that the characteristic periodic damage pattern that results from the optical fuse can be produced by purely thermal means by heating the fiber to temperatures in the 700-1000 degrees C range in the absence of light. The nature of the damage region bubbles suggests local temperatures high enough to so…
Dissolution rates of two commercial soda—lime silicate glasses and Pyrex borosilicate glass (Corning 7740) have been measured as a function of pH. The dissolution rate was constant with time and increased with increase in pH from 4 to 9. The activation energy for dissolution was nearly constant with pH for the Pyrex b…
A new genus of naviculoid diatoms is described from subalpine tarns on Mount Giluwe (Papua New Guinea). Its relationship to other groups is discussed.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoluminescence studies of silver-exchanged cadmium selenide crystals: modification of a chemical sensor for aniline derivatives by heterojunction formationLarry K. Leung, Norma J. Komplin, Arthur B. Ellis, and Ned TabatabaieCite this: J. Phys. Chem. 1991, 95, 15, 5918–592…
A vapor explosion is a physical event in which a hot liquid (fuel) transfers its internal energy to a colder, more volatile liquid (coolant); thus the coolant vaporizes at high pressures and expands analyses work on its surroundings. In postulated severe accidents in current fission reactors, vapor explosions are cons…
The static adhesion of living L1210 cells (in serum-containing medium) to the surface of (styrene/methylmethacrylate) copolymers differing in styrene content (from 5% to 50% of styrene units) was investigated. The examination of wettability of the copolymer surfaces showed that the contact angle of water on the hydrop…
Slow diffusion of cobalt chloride with Na2[Fe(CN)5NO]-5H2O in aqueous solution produced crystals of Co[Fe(CN)5NO]-5H2O suitable for analysis by three-dimensional, single-crystal X-ray diffractometry. This polynuclear transition metal cyanide crystallized in the cubic space group Fm3m (No. 225, O5 h), a = 10.28 I (2)Å,…
The toughness increment resulting from the stress‐induced dilatational component of the t → m transformation is calculated for a zirconia‐toughened‐alumina (ZTA) composition containing a high proportion of tetragonal zirconia precipitates and is shown to agree very well with the experimental value. The good agreement…
This review of the chemistry and electrochemistry of the Hall-Heroult process discusses the composition and constitution of the electrolyte, phenomena occurring at the anode and cathode, the chemical behaviour of the carbon cell-lining, the mechanism of the loss of Faradaic efficiency, and matters of current concern f…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLow-valent titanium porphyrin complexes. Synthesis and structural characterization of the first titanium(II) porphyrin complex, (.eta.2-diphenylacetylene)titanium octaethylporphyrinL. Keith Woo, J. Alan Hays, Robert A. Jacobson, and Catherine L. DayCite this: Organometallics…
Vapor-deposited films prepared under low adatom mobility conditions commonly exhibit columnar structures. We present the scanning electron microscopy study of Cu films with a thickness around 3.7 μm deposited on rough Al2O3 ceramic substrates and smooth SiO2 substrates. The Cu films were deposited using the partially…
Abstract Poly(phenylene-chloroethylene) film was prepared by the vapor deposition polymerization of 1,9-dichloro[2.2]paracyclophane and was converted into fully extended π-conjugated poly (phenylene-vinylene) by thermal dehydrochlorination at 300 °C under nitrogen for 1 h.
Photoinduced absorption spectra for vibrational and electronic excitations have been investigated in a prototypical one-dimensional Peierls-Hubbard system, potassium tetracyanoquinodimethane crystals. Strong photoinduced-absorption signals and their temperature-and time-dependent characteristics are discussed in terms…
We have used x-ray photoelectron spectroscopy (XPS) to measure the valence band offset in situ for CdSe/ZnTe (100) heterojunctions grown by molecular-beam epitaxy. XPS measurements were performed for films of CdSe (100) and ZnTe (100), and for heterojunctions consisting of either ∼25 Å of CdSe grown on ZnTe or ∼25 Å o…
Silica soots were sintered under a reducing ambient to study the generation mechanism of the oxygen-deficient-type defects in silica glasses. Glasses sintered under H2/He gas mixtures or vacuum were prepared with an intent to produce oxygen-deficient centers. Two optical-absorption bands were generated in the silica g…
Ten Gomphonema taxa and four taxa of Gomphoneis from the upper Laurentian Great Lakes are considered. Gomphonema taxa include five new species and one new variety and a new record for the Great Lakes. Two new Gomphoneis taxa are described. SEM study of Gomphonema species indicates that all have occluded puncta. Occlus…
Abstract Polymerization of ε‐caprolactone initiated with dialkylaluminum alkoxides is a living system; formation of macrocyclics is fully depressed. Polymerization initiated with diethylaluminum alkoxide and diisobutylaluminum alkoxide proceeds on monomeric (deaggregated) active species, reversibly aggregating into tr…
Abstract 1,2-Dimethylindolylfulgides with 5-methylthio, 5-methoxy, or 5-dimethylamino group on the indole ring were synthesized and their photochromic properties were examined. Electron donating substituents lengthened the absorption maximum of the colored form and decreased the quantum yields of the photoreactions. T…
The digestive gland of Pecten maximus consists, as in other lamellibranchs, of numerous blindending tubules which communicate with the stomach by partially ciliated main ducts and non ciliated secondary ducts. The non-ciliated cells of the main ducts are characterized by a well developed brush border constituted by hi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal process for orientation of polyaniline filmsK. R. Cromack, M. E. Jozefowicz, J. M. Ginder, A. J. Epstein, R. P. McCall, G. Du, J. M. Leng, K. Kim, C. Li, and Cite this: Macromolecules 1991, 24, 14, 4157–4161Publication Date (Print):July 1, 1991Publication History Pub…