Materials Literature
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A general review of some of the theories proposed to account for the process of “bronze disease” is presented from both the historical and chemical points of view. The corrosion product of most serious concern, cuprous chloride, and its inter-relationship with some of the other important corrosion products of copper a…
Trinuclear complexes of general formulas [MCu2(CH3CO2)2(salpd)2](M = MgII, MnII, CoII, NiII, CuII, or ZnII) and [MNi2(CH3CO2)2(salpd)2](M = MgII, MnII, CoII, or NiII) were prepared, where H2salpd represents propene-1,3-diylbis(salicylideneimine). Further reactions of the complexes of the former series with sulphur dio…
A method for measuring the relaxation of internal stresses of optical fibers is developed. The authors discuss a few principal previous publications on the subject of annealing and relaxation of glass. The internal stress measurement setup is explained, and useful relations are given. It is pointed out that the relaxa…
Abstract This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as thi…
In Co-substituted Nd-Fe-B sintered magnets, several additional phases such as Nd(Fe,Co)/sub y/B/sub ?/ with y=2, 3, and 4 have been found besides the hard magnetic phase and the Nd-rich intergranular phase. The low coercivity of the magnet is attributed to the occurrence of these soft ferromagnetic phases. In Ga-doped…
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Abstract A study has been made of the thermal, X‐ray diffraction, and dynamic mechanical characteristics of polypropylene (PP1330, a copolymer containing 22% ethylene) filled with wollastonite. Various levels of β‐form crystallinity were produced in the PP by mixing in varying amount of wollastonite. It has been found…
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The preparation and characterisation of [MnL1(CH3CO2)2](1), [Mn6(µ4-O)2(C6H5CO2)10(H2O)4](9), [FeL1Cl3](10), [FeL2Cl3](2), and [Fe2L12(µ-O){µ-(CH3)3CCO2}2][ClO4]2(3) are reported where L1 and L2 are bis(benzimidazol-2-ylmethyl)amine and bis(benzimidazol-2-ylmethyl)methylamine. The molecular structures of (1), (2), and…
Abstract Durch Umsetzung von Na 2 O und TiAs bzw. TiSb in verschweißten Tantalampullen unter Argon gelang die Darstellung der metallisch grauen und sehr hydrolyseempfindlichen Verbindungen Na 2 Ti 2 As 2 O bzw. Na 2 Ti 2 Sb 2 O. Sie kristallisieren tetragonal innenzentriert in einem modifizierten anti‐K 2 NiF 4 ‐Typ […
An equivalent circuit approach is presented for synchronous machine analysis. The approach provides a detailed treatment of magnetic nonlinearity without excessive computational complexity. The number of parameters is typically in the range of 30 to 100, in contrast with 13 to 19 in conventional linear models and with…
Water enters the interlayer space in halloysite to minimize cation-cation Coulomb repulsion between adjacent layer surfaces and to coordinate exchangeable cations postulated as present to compensate for Al(IV). The layers roll into tubes due to lateral misfit between a larger tetrahedral sheet and a smaller octahedral…
Abstract. A description is given of a suite of computer programs recently developed at ISIS for the analysis of time-of-flight neutron diffraction data from non-crystalline samples. The various stages of the analysis are discussed, giving particular emphasis to those aspects in which the analysis of time-of-flight dif…
In order to identify a hard magnetic phase in rapidly quenched Zr-Co-B alloys and clarify its magnetic properties, Zr-Co-B ribbons, Zr-Co ribbons, and Zr-Co ingots were studied. The hard magnetic phase is interpreted as a Zr/sub 2/Co/sub 11/ intermetallic compound. This compound has a Curie temperature of 500 degrees…
Abstract Aluminum, the second most plentiful metallic element, is an economic competitor in various applications owing to its appearance, light weight, fabricability, physical properties, mechanical properties, and corrosion resistance. This article discusses the primary and secondary production of aluminum and classi…
A simple X-ray diffraction method for the measurement of crystallinity of cellulose was investigated. Principle of the method lies on the analysis of X-ray diffractograms of crystalline cellulose I or II mixed with varying amount of stable amorphous cellulose prepared from anhydro sulfurous acid-diethylamaine-dimethyl…
A fast, handy method of assessment of a three-dimensional leakage field distribution and hot-spot localization in three-phase power transformers is proposed. The computational model is based on the reluctance network method. A 3-D leakage field of a three-phase transformer is simulated with an equivalent reluctance of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA general free volume-based theory for the diffusion of large molecules in amorphous polymers above the glass temperature. I. Application to di-n-alkyl phthalates in PVCKenneth A. Mauritz, Robson F. Storey, and Scott E. GeorgeCite this: Macromolecules 1990, 23, 2, 441–450Pub…
Abstract The effects of intermolecular and intramolecular triplet quenchers and sensitizers on the photochromism of nitrospiropyran have been examined in order to clarify the role of the triplet state (3A*) as well as that of the excited singlet state (1A*). The rates of photocoloration and fatigue were significantly…
The drastic increase in coercivity observed after adding Al in Fe-Nd-B-based magnet alloys seems to originate partially from the occurrence of new Al-stabilized phases in the grain boundary region and at the surface of the Fe/sub 14/Nd/sub 2/B grains. To describe these phases, they were synthesized and their propertie…