Materials Literature
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Magnetoelectric (ME) coupling (αE) in piezoelectric:magnetostrictive composites is mediated through mechanical strain at their interfaces. Incorporating magnetic nanoparticles (NPs) in piezoelectric matrix enhances interfacial area between the two phases and therefore large αE can be expected. Here, we present electri…
Mimicking hybrid extracellular matrix is one of the main challenges for bone tissue engineering (BTE). Biocompatible polycaprolactone/poly(α,β)-DL-aspartic acid/collagen nanofibrous scaffolds were fabricated by electrospinning and nanohydroxyapatite (n-HA) was deposited by calcium phosphate dipping method for BTE. Hum…
The guanidine-based antimicrobial polymers were grafted onto the surface of beeswax latex particles stabilized with or without amphoteric surfactant, n-dodecyl-N,N-dimethylglycine. N-(3-Dimethylaminopropyl)-N'-ethylcarbodiimide hydrochloride (EDC) was used as a coupling reagent to introduce the covalent bonding or ens…
Superparamagnetic Fe3O4 nanoparticles were obtained using a hydrolysis product of starch, i.e., α-d-glucose, as the reducing agent and without any additional stabilizer and dispersant by a facile and green method at mild temperature. Magnetic dialdehyde starch nanoparticles (MDASN) were successfully synthesized with d…
The mechanism of CO oxidation by a CeO 2 (110)-supported gold atom has been investigated by DFT calculations. A novel stable surface structure has been identified in which one surface O atom of ceria migrates toward the isolated Au atom, resulting in a surface Au–O species that can react with CO. After CO 2 desorption…
A series of hyper-branched cationic conjugated polyelectrolytes containing different contents of phosphorescent Ir(III) complex has been designed and synthesized successfully. Their photophysical properties in both aqueous solution and solid film are investigated and their morphologies in aqueous solution are observed…
We demonstrate current-based, deep level transient spectroscopy (DLTS) on semiconductor nanocrystal solids to obtain quantitative information on deep-lying trap states, which play an important role in the electronic transport properties of these novel solids and impact optoelectronic device performance. Here, we apply…
CuO nanocrystals were prepared by thermal decomposition of Cu-oxalate at 400 °C; then CuO/TiO 2 core/shell nanocrystals were formed via the hydrolysis of titanium isopropoxide (TIP) on the surface of CuO nanocrystals. The characteristics of the synthesized nanocrystals were systematically studied using appropriate tec…
The variation in localized surface plasmon resonances of single Au nanodisks (diameter 100 nm and height 25 nm) on 0–13 graphene layers is investigated using dark-field scattering spectroscopy to obtain the graphene electric field screening length. For nanodisks (NDs) with and without underlying graphene layers on a S…
Several types of fibrous material containing poly(3-hydroxybutyrate) (PHB), nanosized TiO2 -anatase (nanoTiO2 ), and chitosan oligomers are prepared by combining the electrospinning, electrospraying, and impregnation techniques. Simultaneous electrospinning/electrospraying provides uniform distribution of electrospray…
The mechanism of selective catalytic reduction of NOx by propene (C3H6-SCR) over the Cu/Ti0.7Zr0.3O2 catalyst was studied by in situ Fourier transform infrared (FTIR) spectroscopy and density functional theory (DFT) calculations. Especially, the formation and transformation of cyanide (-CN species) during the reaction…
We present an effective method for actively controlling intrinsic resonances of optical metamaterials using graphene. Exploiting the Fermi level shift and associated variations in optical transitions of graphene due to voltage biasing, we attain the ability to significantly modulate the intrinsic resonance of the fish…
This work examined concentration-dependent variations in the fluorescence spectra of solutions of perylene and PMMA in toluene during the process of evaporation, using fluorescence microscopy. At low perylene concentrations, the fluorescence spectra of the resulting perylene/PMMA films exhibited a structural band orig…
The theory of molecular nonlinear optics based on the sum-over-states (SOS) model is reviewed. The interaction of radiation with a single wtpisolated molecule is treated by first-order perturbation theory, and expressions are derived for the linear (αij) polarizability and nonlinear (βijk, γijkl) molecular hyperpolari…
Orbital magnetism is studied for graphene flakes with various shapes and edge configurations using the tight-binding approximation. In the low-temperature regime where the thermal energy is much smaller than the energy-level spacing, the susceptibility rapidly changes between diamagnetism and paramagnetism as a functi…
Ein einfacher, aber leistungsfähiger chemischer Prozess – die Copolymerisation von Glucose mit Borsäure in Gegenwart von Dicyandiamid als Templat (siehe Bild) – wurde zur direkten Synthese von dotierten Graphen-Monolithen mit nanoporösen Ebenen verwendet. Die „löchrigen“ Graphen-Monolithe verfügen über eine große Ober…
The interfaces of LaAlO3/SrTiO3 and (LaAlO3)(x)(SrTiO3)(1-x)/SrTiO3 heterostructures have been investigated by soft x-ray photoelectron spectroscopy for different layer thicknesses across the insulator-to-metal interface transition. The valence band and Fermi edge were probed using resonant photoemission across the Ti…
We study diffusion processes of local fluctuations of heat, energy, momentum, and mass in three paradigmatic one-dimensional systems. For each system, diffusion processes of four physical quantities are simulated and the cross correlations between them are investigated. We find that, in all three systems, diffusion pr…
Magnetic properties (coercivity and magnetization) of ferromagnetic films are strongly affected by the proximity to materials that undergo a metal to insulator transition. Here, we show that stress associated with structural changes across the metal-insulator phase transition in VO2 and V2O3 produces a magnetoelastic…
Unveiling the full potential of doped silicon for electronic, photonic, and plasmonic application at THz frequencies requires a thorough understanding of its high-frequency transport properties. In this letter, we present a comprehensive numerical characterization of the frequency-dependent (0–2.5 THz) complex conduct…