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Suppression of thermal conductivity in InxGa1−xN alloys by nanometer-scale disorder

Tao Tong、Deyi Fu、A. X. Levander 等 13 位作者2013-03-25Applied Physics Letters

We have systematically measured the room-temperature thermal conductivity of epitaxial layers of InxGa1−xN alloys with 15 different Indium compositions ranging from 0.08 to 0.98 by time-domain thermoreflectance method. The data are compared to the estimates of the strength of phonon scattering by cation disorder. The…

GaN-based semiconductor devices and materialsThermal properties of materialsThermal Radiation and Cooling Technologies

Elaborate Metallosupramolecular Architectures through Desymmetrization Self-assembly of Symmetric Building Blocks

Takashi Nakamura、Hitoshi Ube、Mitsuhiko Shionoya2013-03-25Chemistry Letters

Abstract Desymmetrization self-assembly of symmetric building blocks is a powerful method to construct elaborate metallosupramolecular architectures. Herein several examples are given to discuss how to build up self-assembled complexes with low symmetry, focusing on 1) stabilization of local structural motifs by templ…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Effect of Tertiary and Secondary Phosphines on Low‐Temperature Formation of Quantum Dots

Kui Yu、Xiangyang Liu、Qun Zeng 等 9 位作者2013-03-25Angewandte Chemie International Edition

Getting to the TOP of things: The coordination of tri-n-octylphosphine (TOP) instead of diphenylphosphine (DPP) to cadmium oleate (Cd(OA)2) reveals how tertiary and secondary phosphines enhance the yield and reproducibility of the synthesis of nanocrystals by shifting the equilibrium of the reaction to the right (see…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Structural properties of core and surface of silica nanoparticles investigated by Raman spectroscopy

A. Alessi、S. Agnello、Gianpiero Buscarino 等 4 位作者2013-03-25Journal of Raman Spectroscopy

We studied the experimental Raman spectra of various commercial silica nanoparticles of average diameter from 7 to 40 nm and specific surface from 50 to 380 m2/g. We found that the peculiarities of the particles Raman spectra systematically depend on their specific surface. In detail, the peak position of the R band a…

Material Dynamics and PropertiesGlass properties and applicationsClay minerals and soil interactions

Effects of substitutional Li on the ferromagnetic response of Li co-doped ZnO:Co nanoparticles

Saif Ullah Awan、S. K. Hasanain、M. F. Bertino 等 4 位作者2013-03-25Journal of Physics Condensed Matter

Li co-doped ZnO:Co (Zn0.96-yCo0.04LiyO , y ≤ 0.1) nanoparticles were synthesized by the sol-gel technique and the correlation between the structural, electronic and magnetic properties was investigated. All the samples show a single phase hexagonal (wurtzite) ZnO structure and no secondary phases were detected. Variat…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Ubiquinone-quantum dot bioconjugates for in vitro and intracellular complex I sensing

Wei Ma、Lixia Qin、Feng-Tao Liu 等 8 位作者2013-03-25Scientific Reports

Quantum dots (QDs) have attracted increasing interest in bioimaging and sensing. Here, we report a biosensor of complex I using ubiquinone-terminated disulphides with different alkyl spacers (QnNS, n = 2, 5 and 10) as surface-capping ligands to functionalise CdSe/ZnS QDs. The enhancement or quenching of the QD bioconj…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Effect of reduced dimensionality on the optical band gap of SrTiO3

Che‐Hui Lee、Nikolas J. Podraza、Ye Zhu 等 16 位作者2013-03-25Applied Physics Letters

The effect of dimensional confinement on the optical band gap of SrTiO3 is investigated by periodically introducing one extra SrO monolayer every n SrTiO3 layers. The result is the n = 1–5 and 10 members of the Srn+1TinO3n+1 Ruddlesden-Popper homologous series. Spectroscopic ellipsometry, optical transmission, and cat…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Self-Assembly of Two-Dimensional Colloidal Clusters by Tuning the Hydrophobicity, Composition, and Packing Geometry

Adam D. Law、M Auriol、D. F. Smith 等 5 位作者2013-03-25Physical Review Letters

We study the structure of binary monolayers of large ($3\text{ }\text{ }\ensuremath{\mu}\mathrm{m}$ diameter) very hydrophobic ($A$) and large ($3\text{ }\text{ }\ensuremath{\mu}\mathrm{m}$ diameter) hydrophilic ($B$) or small ($1\text{ }\text{ }\ensuremath{\mu}\mathrm{m}$ diameter) hydrophilic ($C$) silica particles…

Photonic Crystals and ApplicationsSpectroscopy and Quantum Chemical StudiesPickering emulsions and particle stabilization

Effects of La, Ce, and Y Oxides on SnO2 Catalysts for CO and CH4 Oxidation

Xianglan Xu、Rongbin Zhang、Xianrong Zeng 等 7 位作者2013-03-25ChemCatChem

Abstract SnO2‐based catalysts modified by La, Ce, and Y with a Sn/Ln (Ln=La, Ce, Y) atomic ratio of 2:1 were prepared by using a co‐precipitation method and used for CO and CH4 oxidation. The catalysts were characterized by N2 adsorption–desorption, XRD, energy dispersive X‐ray spectroscopy (EDS)‐SEM, H2 temperature‐p…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

The oxygen vacancy effect on the magnetic property of the LaMnO3−δ thin films

Ruiqiang Zhao、Kuijuan Jin、Zhongtang Xu 等 8 位作者2013-03-25Applied Physics Letters

The magnetic property of the LaMnO3−δ films was systematically investigated with the variation of the deposited oxygen pressure. The Curie temperature and the saturation magnetization of the films were found increased with the decrease of the oxygen pressure. We believe that the double exchange effect between Mn2+ and…

Advanced Memory and Neural ComputingMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Switchable focus using a polymeric lenticular microlens array and a polarization rotator

Hongwen Ren、Su Xu、Yifan Liu 等 4 位作者2013-03-25Optics Express

We demonstrate a flat polymeric lenticular microlens array using a mixture of rod-like diacrylate monomer and positive dielectric anisotropy nematic liquid crystal (LC). To create gradient refractive index profile in one microlens, we generate fringing fields from a planar top electrode and two striped bottom electrod…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced Optical Imaging Technologies

Anisotropic Debye model for the thermal boundary conductance

Zhen Chen、Zhiyong Wei、Yunfei Chen 等 4 位作者2013-03-25Physical Review B

Most standard models for the thermal boundary conductance (TBC) assume isotropic properties and thus are inappropriate for layered and chainlike materials such as graphite, Bi${}_{2}$Te${}_{3}$, and high-density polyethylene (HDPE). To model such anisotropic materials, here a framework is introduced whereby the first…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Effects of coherent ferroelastic domain walls on the thermal conductivity and Kapitza conductance in bismuth ferrite

Patrick E. Hopkins、Carolina Adamo、Linghan Ye 等 7 位作者2013-03-25Applied Physics Letters

Ferroelectric and ferroelastic domain structure has a profound effect on the piezoelectric, ferroelectric, and dielectric responses of ferroelectric materials. However, domain walls and strain field effects on thermal properties are unknown. We measured the thermal conductance from 100–400 K of epitaxially grown BiFeO…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Low-frequency optical conductivity in graphene and in other scale-invariant two-band systems

Ádám Bácsi、Attila Virosztek2013-03-25Physical Review B

We investigate optical transitions of noninteracting electron systems consisting of two symmetric energy bands touching each other at the Fermi energy (e.g., graphene at half-filling). Optical conductivity is obtained using Kubo formula at zero temperature. We show that for particles whose pseudospin direction is dete…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Doping for higher thermoelectric properties in p-type BiCuSeO oxyselenide

Jinle Lan、Bin Zhan、Yaochun Liu 等 7 位作者2013-03-25Applied Physics Letters

The low power factor (PF) of BiCuSeO oxyselenide inhibits further improvement on thermoelectric figure of merit in the moderate temperature range. In this Letter, we show that the electron transport properties of doped BiCuSeO oxyselenide can be accurately described in acoustic phonon scattering assumption within the…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Microwave‐assisted one‐step green synthesis of amino‐functionalized fluorescent carbon nitride dots from chitosan

Deli Xiao、Danhua Yuan、Hua He 等 4 位作者2013-03-25Luminescence

We present an economical, facile and effective microwave pyrolysis approach to synthesize highly amino-functionalized fluorescent carbon nitride dots (CNDs). The formation and the functionalization of CNDs was accomplished simultaneously through the dehydration of chitosan. It is suggested that these CNDs have good wa…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Smooth Muscle Cells Differentiated From Reprogrammed Embryonic Lung Fibroblasts Through DKK3 Signaling Are Potent for Tissue Engineering of Vascular Grafts

Eirini Karamariti、Andriana Margariti、Bernhard Winkler 等 14 位作者2013-03-25Circulation Research

RATIONALE: Smooth muscle cells (SMCs) are a key component of tissue-engineered vessels. However, the sources by which they can be isolated are limited. OBJECTIVE: We hypothesized that a large number of SMCs could be obtained by direct reprogramming of fibroblasts, that is, direct differentiation of specific cell linea…

Pluripotent Stem Cells ResearchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Green One-Step Approach to Prepare Sulfur/Reduced Graphene Oxide Nanohybrid for Effective Mercury Ions Removal

Suman Thakur、Gautam Das、Prasanta Kumar Raul 等 4 位作者2013-03-25The Journal of Physical Chemistry C

A one-step, eco-friendly strategy is developed to prepare sulfur/reduced graphene oxide nanohybrid (SRGO) (sulfur nanoparticles of average size ∼20 nm) using the combined effect of the polyphenolic compounds and acids present in Citrus limon juice. The prepared nanohybrid is characterized with Fourier transform infrar…

Magnesium Oxide Properties and ApplicationsStructural mechanics and materialsAdvanced Energy Technologies and Civil Engineering Innovations

Influence of the surface coating on the cytotoxicity, genotoxicity and uptake of gold nanoparticles in human HepG2 cells

Sónia Fraga、Helena Faria、Maria Elisa Soares 等 10 位作者2013-03-25Journal of Applied Toxicology

The toxicological profile of gold nanoparticles (AuNPs) remains controversial. Significant efforts to develop surface coatings to improve biocompatibility have been carried out. In vivo biodistribution studies have shown that the liver is a target for AuNPs accumulation. Therefore, we investigated the effects induced…

Nanoparticles: synthesis and applicationsHeavy Metal Exposure and Toxicity

Study of Bio-nano Interaction Outlook of Amino Acids on Single-walled Carbon Nanotubes

Majid Monajjemi、H. Yamola、Fatemeh Mollaamin2013-03-25Fullerenes Nanotubes and Carbon Nanostructures

We applied UV-Vis absorption spectroscopy to investigate the interaction among amino acids (Tyrosin, Glutamic acid, Histidin, and Isoleusin) as biological molecules and single-walled carbon nanotubes (SWCNTs) as biological deliver to mean Bio-nano interaction for using in drug design. Spectral features were recognized…

Carbon Nanotubes in CompositesElectrochemical sensors and biosensorsthermodynamics and calorimetric analyses