Materials Literature
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We describe electrophoresis of spherical dielectric particles in a uniformly aligned nematic medium with a negative dielectric anisotropy. A spherical particle that orients the liquid crystal (LC) perpendicularly to its surface moves under the application of a uniform direct current or alternating current electric fie…
A series of cysteine-stabilized phenolic resin-based polymer and carbon spheres were prepared by the modified Stöber method. Cysteine plays a very important role in the proposed one-pot synthesis of the aforementioned spheres; namely, it acts as a particle stabilizer and a source of heteroatoms (nitrogen and sulfur) t…
Graphene exfoliated onto muscovite mica is studied using ultrahigh vacuum scanning tunneling microscopy (UHV-STM) techniques. Mica provides an interesting dielectric substrate interface to measure the properties of graphene due to the ultraflat nature of a cleaved mica surface and the surface electric dipoles it posse…
The effects of nonlinear deformation on the melt rheology of low molecular weight lightly sulfonated polystyrene ionomers (SPS) were investigated with dynamic, steady shear, and transient shear experiments. Changes in the viscosity and elasticity of the ionomers that occurred in large deformation flows were explained…
A computational inverse design algorithm is presented that predicts the necessary topographical template to direct the self-assembly of a diblock copolymer thin film into a desired complex morphology. This topographical template is determined from the spatial configuration of a template that results in an energy minim…
The catalytic N 2 O decomposition was investigated over a series of NiCe mixed oxides. Characterizations of XRD, N 2 -adsorption, SEM, XPS, and H 2 -TPR were applied to correlate their properties with the corresponding catalytic performance. The catalyst Ni90Ce10 prepared by citrate acid method exhibited the highest c…
We perform a systematic quantum Monte Carlo study of the pairing correlation in the S(4) symmetric microscopic model for iron-based superconductors. It is found that the pairing with an extensive s-wave symmetry robustly dominates over other pairings at low temperature in a reasonable parameter region regardless of th…
The reversible, temperature-dependent change in the permeability of a phospholipid bilayer has been used for controlling the diffusion rate of encapsulated molecular payload from liposomes. Liposomes were preloaded with a fluorescent dye and immobilized in calcium alginate hydrogel microparticles that also contained i…
Absorption and emission spectra arising from the lowest energy transition in BODIPY have been simulated in the gas phase and water using a quantum mechanics/molecular mechanics (QM/MM) approach. Kohn-Sham density functional theory (DFT) is used to calculate both ground (So) and first excited (S1) states using the maxi…
Corrosion inhibition of carbon steel in HCl by azo dye derivatives (ADD) was investigated using chemical and electrochemical techniques. Results obtained indicate that ADD inhibited the corrosion of carbon steel in the acid medium. Inhibition efficiency increases with increase in ADD concentration and is synergistical…
The effect of quench rate and Zr content on nanostructure and magnetic properties of melt-spun Zr x Co 100− x ( x = 16–21) is investigated. High quench rate favours the formation of rhombohedral Zr 2 Co 11 , which is the hard phase. The coercivity increases with an increase in quench rate. Zr addition in limited amoun…
Imidazolium-based ionic liquids that contain perrhenate anions are very efficient reaction media for the epoxidation of olefins with H2O2 as an oxidant, thus affording cyclooctene in almost quantitative yields. The mechanism of this reaction does not follow the usual pathway through peroxo complexes, as is the case wi…
Chitosan is a marine-derived product that has been widely used in clinical applications, especially in skin reconstruction. The mammalian scaffolds derived from bovine and porcine material have many limitations, for example, prion transmission and religious concerns. Therefore, we created a chitosan skin regenerating…
The first example of aryl-functionalized, butterfly-shaped, highly fluorescent and stable blue-emitting monomers, namely, 7-tert-butyl-1,3,5,9-tetrakis(p-R-phenyl)pyrenes, were synthesized by the Suzuki-Miyaura cross-coupling reaction from a novel bromide precursor of 1,3,5,9-tetrabromo-7-tert-butylpyrene. The crystal…
We present a chemical vapor deposition (CVD) method to catalytically synthesize large-area, transferless, single- to few-layer graphene sheets using hexamethyldisilazane (HMDS) on a SiO2/Si substrate as a carbon source and thermally evaporated alternating Ni/Cu/Ni layers as a catalyst. The as-synthesized graphene film…
A series of nonplanar tetraphenylethene (TPE)-hexaphenylbenzene (HPB) adducts was designed and synthesized by Diels-Alder reaction of the acetylene precursors and tetraphenylcyclopentadienone. All of the adducts showed aggregation-induced emission features. The twisting amplitude and steric hindrance of the TPE and HP…
A chromotropic acid (CTA) intercalated layered double hydroxide (LDH) supramolecular assembly with the molecular formula Zn 0.79 Al 0.21 (OH) 2 (CTA) 0.11 ·0.79H 2 O (denoted as Zn 4 Al–CTA–LDH) has been prepared using separate nucleation and aging steps. The adsorption behavior of Zn 4 Al–CTA–LDH for a number of meta…
Nowadays necessities for the green synthesis of nanoparticles are enlarged because of its neutral toxicity and eco-friendly advantages. In this present study, we have explored the rapid biosynthesis of AgNPs at room temperature by the fresh leaf aqueous extract of Anacardium occidentale . Aqueous extracts were prepare…
At the level of a single particle, nanocrystal quantum dots (NQDs) are observed to fluoresce intermittently or "blink." They are also characterized by an efficient non-radiative recombination process known as Auger Recombination (AR). Recently, new approaches to NQD heterostructuring have been developed that directly…
A simple and reproducible biosynthetic method was employed to synthesize iron and silver nanoparticles which resulted in monodispersed nanoparticles of high concentration. The iron oxide nanoparticles has been widely favored because of low cytotoxicity, biodegradable and reactive surface that can be modified with bioc…