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Self-assembly of a peptide amphiphile: transition from nanotape fibrils to micelles

Juan F. Miravet、Beatriu Escuder、Maria Dolores Segarra‐Maset 等 7 位作者2013-01-01Soft Matter

A thermal transition is observed in the peptide amphiphile C16-KTTKS (TFA salt) from nanotapes at 20 °C to micelles at higher temperature (the transition temperature depending on concentration). The formation of extended nanotapes by the acetate salt of this peptide amphiphile, which incorporates a pentapeptide from t…

Molecular Sensors and Ion DetectionSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Review on measurement techniques of transport properties of nanowires

Miguel Muñoz Rojo、Olga Caballero‐Calero、A. F. Lopeandía 等 5 位作者2013-01-01Nanoscale

Physical properties at the nanoscale are novel and different from those in bulk materials. Over the last few decades, there has been an ever growing interest in the fabrication of nanowire structures for a wide variety of applications including energy generation purposes. Nevertheless, the study of their transport pro…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsSurface and Thin Film Phenomena

Tobacco mosaic virus rods and spheres as supramolecular high-relaxivity MRI contrast agents

Michael A. Bruckman、Stephen C. Hern、Kai Jiang 等 6 位作者2013-01-01Journal of Materials Chemistry B

To compensate for the low sensitivity of magnetic resonance imaging (MRI), nanoparticles have been developed to deliver high payloads of contrast agents to sites of disease. Here, we report the development of supramolecular MRI contrast agents using the plant viral nanoparticle tobacco mosaic virus (TMV). Rod-shaped T…

Lanthanide and Transition Metal ComplexesCarbon and Quantum Dots ApplicationsElectron Spin Resonance Studies

Controlling polyurethane foam flammability and mechanical behaviour by tailoring the composition of clay-based multilayer nanocoatings

Yu‐Chin Li、Yeon Seok Kim、John R. Shields 等 4 位作者2013-01-01Journal of Materials Chemistry A

This study is a thorough evaluation of clay-based Layer-by-Layer (LbL) coatings intended to reduce the flammability of polymeric materials. Through a systematic variation of a baseline coating recipe, an ideal combination of the coating attributes that provides a rapidly developing coating with an optimum balance of f…

Polymer Nanocomposites and PropertiesPolymer Surface Interaction StudiesFlame retardant materials and properties

Using cuprophilicity as a multi-responsive chromophore switching color in response to temperature, mechanical force and solvent vapors

Xiao-Chen Shan、Feilong Jiang、Lian Chen 等 7 位作者2013-01-01Journal of Materials Chemistry C

A novel strategy is provided in this paper to design multi-stimuli-responsive luminescent materials by taking a multi-responsive chromophore which responds to multiple environmental stimuli instead of constructing multi-chromophore systems. Herein, we have successfully prepared a tri-stimuli-responsive luminescent mat…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

H2O2-triggered shape transformation of silver nanospheres to nanoprisms with controllable longitudinal LSPR wavelengths

Tewarak Parnklang、Chutiparn Lertvachirapaiboon、Prompong Pienpinijtham 等 6 位作者2013-01-01RSC Advances

A novel approach for the synthesis of colloidal silver nanoprisms (AgNPrs) with controllable localized surface plasmon resonance (LSPR) via a chemical shape transformation of silver nanospheres (AgNSs) is presented. The shape conversion is carried out by feeding hydrogen peroxide (H2O2) solution into a starch-stabiliz…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesNanocluster Synthesis and Applications

Covalent organic polymer supported palladium catalysts for CO oxidation

You Zhou、Zhonghua Xiang、Dapeng Cao 等 4 位作者2013-01-01Chemical Communications

Covalent organic polymer-4 (COP-4) supported palladium (Pd) catalysts were prepared for the first time. The Pd particles are highly dispersed into pores of COP-4 with electron reduction and the use of N,N-dimethylformamide (DMF) as the solvent. The catalysts show high activity for CO oxidation.

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceCovalent Organic Framework Applications

Stable superhydrophobic and superoleophilic soft porous materials for oil/water separation

Weixin Liang、Zhiguang Guo2013-01-01RSC Advances

In this paper, polyaniline nanofibers were deposited on the surface of fabrics and generated a rough structure similar to the micromorphology of a lotus leaf via the oxidative chemical polymerization of aniline. After modification with n-octadecyl thiol, water-repellent fabrics were obtained. Interestingly, the as-pre…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Mimic nature, beyond nature: facile synthesis of durable superhydrophobic textiles using organosilanes

Lei Wu、Junping Zhang、Bucheng Li 等 4 位作者2013-01-01Journal of Materials Chemistry B

Low mechanical stability of superhydrophobic surfaces is the bottle neck we are facing for their practical applications. Here we report facile fabrication of durable superhydrophobic textiles by dip coating in a nanocomposite solution of fluoro-free organosilanes. The kind of organosilane, molar ratio of organosilane…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomena

A Pharmacokinetic Overview of Nanotechnology-Based Drug Delivery Systems: An ADME-Oriented Approach

Mehrdad Hamidi、Amir Azadi、Pedram Rafiei 等 4 位作者2013-01-01Critical Reviews in Therapeutic Drug Carrier Systems

With the extensive progress in nanotechnology-based drug delivery systems, pharmacokinetic evaluations have gained much attention from researchers as a central part of the study of these systems. Because the fulfillment of any therapeutic goal(s) by a novel drug delivery system requires that the absorption, distributi…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

Ethanol assisted synthesis of pure and stable amorphous calcium carbonate nanoparticles

Shaofeng Chen、Helmut Cölfen、Markus Antonietti 等 4 位作者2013-01-01Chemical Communications

Stable monodispersed amorphous calcium carbonate (ACC) nanoparticles can be synthesized in ethanol media by a facile method, and crystallization of ACC is kinetically controlled, resulting in the formation of three polymorphs in a mixed solvent of ethanol-water at different pH values.

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionEnzyme function and inhibition

Poly(Lactic Acid)/Polycaprolactone Blends Compatibilized with Block Copolymer

Kamolrat Chavalitpanya、Siriwan Phattanarudee2013-01-01Energy Procedia

This research focused on using a block copolymer of poly(ethylene glycol) and poly(propylene glycol) as a new type of compatibilizer in poly(lactic acid)/polycaprolactone (PLA/PCL) blends. The blends were prepared at 80/20 by a melt blending method, and concentrations of the block copolymer were varied from 0-10 phr.…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

A new fluorometric turn-on assay for alkaline phosphatase and inhibitor screening based on aggregation and deaggregation of tetraphenylethylene molecules

Xinggui Gu、Guanxin Zhang、Zhuo Wang 等 6 位作者2013-01-01The Analyst

Based on the consideration that compound 1 with a -PO3H2 group can be hydrolyzed into compound 3 which shows low solubility in aqueous solutions and thus aggregation can occur easily, a new fluorescence turn-on assay has been constructed for alkaline phosphatase (ALP) with compound 1. ALP at concentrations as low as 1…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

The toxicity of Gold Nanoparticles in relation to their physiochemicalproperties.

Clarence S. Yah2013-01-01Biomedical Research-tokyo

The rapid emergence of gold nanoparticles (AuNPs) technology holds great promise for future applications due to their large volume specific surface areas with high diverse surface activities than bulk gold. These properties have made AuNPs of great importance in the development of excellent nanoelectronic chips, promi…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsGraphene and Nanomaterials Applications

New perspectives on potential hydrogen storage materials using high pressure

Yang Song2013-01-01Physical Chemistry Chemical Physics

In addressing the global demand for clean and renewable energy, hydrogen stands out as the most suitable candidate for many fuel applications that require practical and efficient storage of hydrogen. Supplementary to the traditional hydrogen storage methods and materials, the high-pressure technique has emerged as a n…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsCarbon dioxide utilization in catalysis

Controlling magnetism of MoS2 sheets by embedding transition-metal atoms and applying strain

Yungang Zhou、Qiulei Su、Zhiguo Wang 等 5 位作者2013-01-01Physical Chemistry Chemical Physics

Prompted by recent experimental achievement of transition metal (TM) atoms substituted in MoS2 nanostructures during growth or saturating existing vacancies (Sun et al., ACS Nano, 2013, 7, 3506; Deepak et al., J. Am. Chem. Soc., 2007, 129, 12549), we explored, via density functional theory, the magnetic properties of…

ZnO doping and properties2D Materials and ApplicationsMXene and MAX Phase Materials

Anisotropy barrier enhancement via ligand substitution in tetranuclear {CoIII2LnIII2} single molecule magnets

Stuart K. Langley、Nicholas F. Chilton、Boujemaa Moubaraki 等 4 位作者2013-01-01Chemical Communications

The replacement of coordinated acetylacetonate for nitrate around a Dy(III) ion results in the enhancement of the single molecule magnet properties of a {Co(III)2Dy(III)2} complex, resulting in a large thermal energy barrier and reduced quantum tunnelling at low temperatures. The analogous Tb(III) complex displays fie…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Ultrafine nanoporous PdFe/Fe3O4 catalysts with doubly enhanced activities towards electro-oxidation of methanol and ethanol in alkaline media

Zhonghua Zhang、Chi Zhang、Junzhe Sun 等 7 位作者2013-01-01Journal of Materials Chemistry A

Here, we report the fabrication of ultrafine nanoporous PdFe/Fe3O4 electrocatalysts by a facile dealloying strategy. The results show that the phase formation of the as-dealloyed samples is dependent upon the Pd : Fe atomic ratio in the Al–Pd–Fe ternary precursors. The size of ligaments is as small as ∼2 nm in the nan…

Electrocatalysts for Energy ConversionNanomaterials for catalytic reactionsNanoporous metals and alloys

Boron nitride nanotubes functionalized with mesoporous silica for intracellular delivery of chemotherapy drugs

Xia Li、Chunyi Zhi、Nobutaka Hanagata 等 6 位作者2013-01-01Chemical Communications

Boron nitride nanotube (BNNT)@mesoporous silica hybrids with controllable surface zeta potential were fabricated for intracellular delivery of doxorubicin. The materials showed higher suspension ability, doxorubicin intracellular endocytosis efficiency, and LNcap prostate cancer cell killing ability compared with nake…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsBoron Compounds in Chemistry

Artificial multiferroic heterostructures

C. A. F. Vaz、U. Staub2013-01-01Journal of Materials Chemistry C

The electric field control of magnetism in the solid state has become a very active topic of research recently, made possible by the advances in the synthesis and fabrication of new materials and artificial heterostructures. Key strategies include structural manipulation through epitaxial growth to create single cryst…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials