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ZnO Nanoparticles: Synthesis and Adsorption Study

K. Prasad、Anal K. Jha2009-01-01Natural Science

A low-cost, green and reproducible probiotic microbe (Lactobacillus sporogens) mediated biosynthesis of ZnO nanoparticles is reported. The synthesis is performed akin to room tem-perature in five replicate samples. X-ray and transmission electron microscopy analyses are performed to ascertain the formation of ZnO nano…

ZnO doping and propertiesSupramolecular Self-Assembly in MaterialsEchinoderm biology and ecology

Supported gold nanoparticles as a reusable catalyst for synthesis of lactones from diols using molecular oxygen as an oxidant under mild conditions

Takato Mitsudome、Akifumi Noujima、Tomoo Mizugaki 等 5 位作者2009-01-01Green Chemistry

The oxidative lactonization of various diols using molecular oxygen as a primary oxidant can be efficiently catalyzed by hydrotalcite-supported Au nanoparticles (Au/HT). For instance, lactonization of 1,4-butanediol gave γ-butyrolactone with an excellent turnover number of 1400. After lactonization, the Au/HT can be r…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Carbon Nanotubes as Active Components for Gas Sensors

Wei‐De Zhang、Wei-De Zhang、Wen-Hui Zhang 等 4 位作者2009-01-01Journal of Sensors

The unique structure of carbon nanotubes endows them with fantastic physical and chemical characteristics. Carbon nanotubes have been widely studied due to their potential applications in many fields including conductive and high‐strength composites, energy storage and energy conversion devices, sensors, field emissio…

Carbon Nanotubes in CompositesGas Sensing Nanomaterials and SensorsAdvanced Chemical Sensor Technologies

Monitoring catalytic degradation of dye molecules on silver-coated ZnO nanowire arrays by surface-enhanced Raman spectroscopy

Xinmei Zhao、Baohua Zhang、Kelong Ai 等 9 位作者2009-01-01Journal of Materials Chemistry

Catalytic degradation of organic dye molecules has attracted extensive attention due to their high toxicity to water resources. In this paper, we propose a novel method for the fabrication of uniform silver-coated ZnO nanowire arrays. The degradation of typical dye molecule rhodamine 6G (R6G), as an example, is invest…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchAdvanced Nanomaterials in Catalysis

Effect of Exopolymers on the Liquid Limit of Clays and Its Engineering Implications

R. A. Nugent、Guoping Zhang、Robert P. Gambrell2009-01-01Transportation Research Record Journal of the Transportation Research Board

An experimental study aimed at understanding the interactions between exopolymers exuded by microorganisms and clays, particularly kaolinite, is described. Two biopolymers–-xanthan gum, an anionic bacterial extracellular polysaccharide, and guar gum, a neutrally charged plant polysaccharide–-were used as exopolymer an…

Clay minerals and soil interactionsPolysaccharides Composition and ApplicationsGrouting, Rheology, and Soil Mechanics

Mechanical properties of polypropylene/calcium carbonate nanocomposites

Daniel Eiras、Luiz Antônio Pessan2009-01-01Materials Research

The aim of this work was to study the influence of calcium carbonate nanoparticles in both tensile and impact mechanical properties of a polypropylene homopolymer. Four compositions of PP/CaCO3 nanocomposites were prepared in a co-rotational twin screw extruder machine with calcium carbonate content of 3, 5, 7 and 10…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Hydrophilic elastomeric biomaterials based on resilin-like polypeptides

Manoj B. Charati、Jamie L. Ifkovits、Jason A. Burdick 等 5 位作者2009-01-01Soft Matter

The production of complex, yet well defined materials offers many opportunities in regenerative medicine, in which the mechanical and biological properties of the matrix must meet stringent requirements. Here we report the recombinant production of modular polypeptidic materials, based on the highly resilient protein…

Hydrogels: synthesis, properties, applicationsCellular Mechanics and InteractionsSilk-based biomaterials and applications

Nanomedicine for targeted drug delivery

Do Kyung Kim、Jon Dobson2009-01-01Journal of Materials Chemistry

In recent years, nanoparticles have played an ever increasing role in biomedical research and clinical applications. The unique physical properties of nanomaterials are being exploited in the field of nanomedicine for applications as diverse as drug delivery and targeting, MRI contrast enhancement, gene therapy, bioma…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNanoplatforms for cancer theranostics

Nanoporous colloids: building blocks for a new generation of structured materials

Yajun Wang、Andrew Price、Frank Caruso2009-01-01Journal of Materials Chemistry

Porous colloidal particles have recently attracted a renewed interest in both fundamental and applied research. The large internal surface area and adsorbent potential of porous particles have led to their widespread application in diverse fields, including sensing, catalysis, drug delivery, and separations. This revi…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Surface Modification for Improving the Stability of Nanoparticles in Liquid Media

Motoyuki Iijima、Hidehiro Kamiya2009-01-01KONA Powder and Particle Journal

Nanoparticles are now an indispensable material for science and technology such an in materials, medicals, and cosmetics areas. Controlling the dispersion stability of nanoparticles in various liquid media is an essential issue to control the properties of the final products. At the beginning of this review, we will i…

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Properties

Colloidal molecules with well-controlled bond angles

Daniela J. Kraft、Jan Groenewold、Willem K. Kegel2009-01-01Soft Matter

We present a straightforward technique for the synthesis of asymmetric colloidal molecules with uniform and well-controlled bond angles. The new method makes use of coalescence of liquid protrusions on polystyrene spheres. The bond angle between the seed particles and central sphere can be chosen as desired by adjusti…

Proteins in Food SystemsPickering emulsions and particle stabilizationBiocrusts and Microbial Ecology

Micropatterning of bioactive self-assembling gels

Álvaro Mata、Lorraine Hsu、Ramille M. Capito 等 6 位作者2009-01-01Soft Matter

Microscale topographical features have been known to affect cell behavior. An important target in this area is to integrate top down techniques with bottom up self-assembly to create three-dimensional (3D) patterned bioactive mimics of extracellular matrices. We report a novel approach toward this goal and demonstrate…

RNA Interference and Gene DeliverySupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

A novel approach to raspberry-like particles for superhydrophobic materials

Zhen Qian、Zhicheng Zhang、Linyong Song 等 4 位作者2009-01-01Journal of Materials Chemistry

A new strategy was developed to prepare raspberry-like particles by introducing poly(acrylic acid) (PAA)-functionalized polystyrene (PS) particles into hydrolysis reaction of tetraethoxysilane (TEOS). The monodisperse PAA-functionalized PS particles were used as cores and nanosized silica particles were then assembled…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPickering emulsions and particle stabilization

Acute and chronic toxicity of nano-scale TiO2particles to freshwater fish, cladocerans, and green algae, and effects of organic and inorganic substrate on TiO2toxicity

Scott Hall、Tina Bradley、Joshua T. Moore 等 5 位作者2009-01-01Nanotoxicology

This research evaluated the toxicity of TiO2 nanoparticles to freshwater aquatic organisms and the effects of organic and inorganic material on TiO2 toxicity. The fathead minnow was much less acutely sensitive to TiO2 (LC50 500 mg/l and higher) than Ceriodaphnia dubia and Daphnia pulex (mean LC50 values 7.6 and 9.2 mg…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyWater Quality and Pollution Assessment

Azobenzene-containing block copolymers: the interplay of light and morphology enables new functions

Yue Zhao、Jie He2009-01-01Soft Matter

In azobenzene-containing block copolymers (azo BCPs), the reversible trans–cisphotoisomerization of the chromophore can be coupled with the microphase separation-induced morphology. Recent studies revealed a number of new functions generated from the interaction of photoactivity and self-organized nanostructures in BC…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

A novel smart organogel which could allow a two channel anion response by proton controlled reversible sol–gel transition and color changes

You‐Ming Zhang、Qi Lin、Tai‐Bao Wei 等 5 位作者2009-01-01Chemical Communications

A super gelator (F3) with an excellent gelation ability was synthesized; the organogel of F3 could allow two channel recognition of F-, AcO- and H2PO4- through proton controlled reversible sol-gel transition and color changes.

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Effective force coarse-graining

Yanting Wang、W. G. Noid、Pu Liu 等 4 位作者2009-01-01Physical Chemistry Chemical Physics

An effective force coarse-graining (EF-CG) method is presented in this paper that complements the more general multiscale coarse-graining (MS-CG) methodology. The EF-CG method determines effective pairwise forces between coarse-grained sites by averaging over the atomistic forces between the corresponding atomic group…

Material Dynamics and PropertiesTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Amine-terminated silicon nanoparticles: synthesis, optical properties and their use in bioimaging

Milena Rosso‐Vasic、Evan Spruijt、Zoran Popović 等 10 位作者2009-01-01Journal of Materials Chemistry

Very stable and bright emitting amine-terminated Si nanoparticles (NPs) with different alkyl chain lengths between the Si core and amine end-group are synthesized. The obtained NPs have a spherical shape and homogeneous size distribution (1.57 ± 0.24 nm). Their emission can be tuned from the UV to the blue spectral re…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesSilicon Nanostructures and Photoluminescence

Solvent-free oxidation of benzyl alcohol using Au–Pd catalysts prepared by sol immobilisation

Nikolaos Dimitratos、José Antonio López-Sánchez、David Morgan 等 8 位作者2009-01-01Physical Chemistry Chemical Physics

We report the preparation of Au-Pd nanocrystalline catalysts supported on TiO(2) and carbon prepared via a sol-immobilisation technique using three different preparation strategies; namely, simultaneous formation of the sols for both metals or initial formation of a seed sol of one of the metals followed by a separate…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsOxidative Organic Chemistry Reactions

Solubility of H2O and CO2 in ultrapotassic melts at 1200 and 1250 C and pressure from 50 to 500 MPa

Harald Behrens、Valeria Misiti、C. Freda 等 6 位作者2009-01-01American Mineralogist

The solubility of H 2 O-CO 2 fluids in a synthetic analogue of a phono-tephritic lava composition from Alban Hills (Central Italy) was experimentally determined from 50 to 500 MPa, at 1200 and 1250 °C. Contents of H 2 O and CO 2 in experimental glasses were determined by bulk-analytical methods and FTIR spectroscopy.…

Geological and Geochemical AnalysisMaterial Dynamics and PropertiesGlass properties and applications