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Reduction of the clogging potential of clays: new chemical applications and novel quantification approaches

R. Zumsteg、Michael Plötze、Alexander M. Puzrin2013-02-06Géotechnique

Earth pressure balance machines are increasingly being used for tunnelling in difficult soils and ground conditions. In clayey soils, clogging of the working tools is among the main hazards. Attempts to reduce this risk by adding anti-clogging chemicals do not always produce the desired effect. In this paper, the limi…

Diamond and Carbon-based Materials ResearchDrilling and Well EngineeringTunneling and Rock Mechanics

Discrete shape modeling for skin model representation

Min Zhang、Nabil Anwer、Andreas Stockinger 等 5 位作者2013-02-06Proceedings of the Institution of Mechanical Engineers Part B Journal of Engineering Manufacture

Nowadays, the management of product geometrical variations during the whole product development process is an important issue for companies’ competitiveness. During the design phase, geometric functional requirements and tolerances are derived from the design intent. Furthermore, the manufacturing and measurement stag…

3D Shape Modeling and AnalysisManufacturing Process and OptimizationTextile materials and evaluations

Recent Developments in the Study of Recrystallization

Peter W. Wilson2013-02-06InTech eBooks

Recrystallization is a phenomenon moderately well documented in the geological and metallurgical literature. This book provides a timely overview of the latest research and methods in a variety of fields where recrystallization is studied and is an important factor. The main advantage of a new look at these fields is…

Minerals Flotation and Separation TechniquesCrystallization and Solubility StudiesMineral Processing and Grinding

Amorphous Zinc Stannate (Zn2SnO4) Nanofibers Networks as Photoelectrodes for Organic Dye‐Sensitized Solar Cells

Seung‐Hoon Choi、Daesub Hwang、Dong Young Kim 等 8 位作者2013-02-06Advanced Functional Materials

Abstract A new strategy for developing dye‐sensitised solar cells (DSSCs) by combining thin porous zinc tin oxide (Zn2SnO4) fiber‐based photoelectrodes with purely organic sensitizers is presented. The preparation of highly porous Zn2SnO4 electrodes, which show high specific surface area up to 124 m2/g using electrosp…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesZnO doping and properties

Molecular or Nanoscale Structures? The Deciding Factor of Surface Properties on Functionalized Poly(3,4‐ethylenedioxythiophene) Nanorod Arrays

Hsing‐An Lin、Shyh‐Chyang Luo、Bo Zhu 等 6 位作者2013-02-06Advanced Functional Materials

Abstract Nanostructures of poly(3,4‐ethylenedioxythiophene) (PEDOT) are assembled by using an anodic aluminum oxide template directly fabricated on gold‐coated silicon wafers. Inside these templates, PEDOT and hydroxy functionalized PEDOT form tubes. On the other hand, alkyl‐ and perfluoro‐functionalized PEDOTs assemb…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAnodic Oxide Films and Nanostructures

High volumetric power density, non-enzymatic, glucose fuel cells

Vlad Oncescu、David Erickson2013-02-06Scientific Reports

The development of new implantable medical devices has been limited in the past by slow advances in lithium battery technology. Non-enzymatic glucose fuel cells are promising replacement candidates for lithium batteries because of good long-term stability and adequate power density. The devices developed to date howev…

Electrochemical sensors and biosensorsFuel Cells and Related MaterialsConducting polymers and applications

Study of support vector machine and serum surface-enhanced Raman spectroscopy for noninvasive esophageal cancer detection

Shaoxin Li、Qiuyao Zeng、Linfang Li 等 9 位作者2013-02-06Journal of Biomedical Optics

The ability of combining serum surface-enhanced Raman spectroscopy (SERS) with support vector machine (SVM) for improving classification esophageal cancer patients from normal volunteers is investigated. Two groups of serum SERS spectra based on silver nanoparticles (AgNPs) are obtained: one group from patients with p…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Chemometric AnalysesSpectroscopy Techniques in Biomedical and Chemical Research

Iodine (I2) as a Janus-Faced Ligand in Organometallics

Andrey Yu. Rogachev、Roald Hoffmann2013-02-06Journal of the American Chemical Society

The four known diiodine complexes have distinct geometries. These turn out, as we demonstrate by a bonding analysis, to be a direct consequence of diiodine acting as an acceptor in one set, the van Koten complexes, and as a donor in the Cotton, Dikarev, and Petrukhina extended structure. The primary analytical tool ut…

Magnetism in coordination complexesCrystallography and molecular interactionsVanadium and Halogenation Chemistry

1:2‐sequence‐regulated radical copolymerization of naturally occurring terpenes with maleimide derivatives in fluorinated alcohol

Masaru Matsuda、Kotaro Satoh、Masami Kamigaito2013-02-06Journal of Polymer Science Part A Polymer Chemistry

Abstract Naturally occurring bulky terpenes, such as (+)‐ and (–)‐limonene and (–)‐β‐pinene, were quantitatively copolymerized with maleimide (MI) derivatives (i.e., phenyl‐, cyclohexyl‐, ethyl‐, and unsubstituted‐MI) in PhC(CF3)2OH solvent via selective 1:2‐alternating propagation governed by the penultimate effect,…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Uniaxial extensional rheology of well-characterized comb polymers

Helen Lentzakis、D. Vlassopoulos、Daniel J. Read 等 7 位作者2013-02-06Journal of Rheology

We present a detailed systematic investigation of the transient uniaxial extensional response of a series of well-characterized, anionically synthesized comb polystyrenes and polyisoprenes. The comb architecture consists of a linear chain backbone with multiple branches of equal molar mass, and represents an excellent…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Sub-10 nm Nano-Organization in AB2- and AB3-Type Miktoarm Star Copolymers Consisting of Maltoheptaose and Polycaprolactone

Takuya Isono、Issei Otsuka、Yohei Kondo 等 9 位作者2013-02-06Macromolecules

The AB 2 - and AB 3 -type miktoarm star copolymers consisting of maltoheptaose (MH, as A block) and poly(ε-caprolactone) (PCL, as B block), namely MH- b -(PCL) 2 and MH- b -(PCL) 3, were synthesized, and their nano-organization was characterized. The syntheses of MH- b -(PCL) 2 and MH- b -(PCL) 3 were carried out thro…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Viscometric functions for noncolloidal sphere suspensions with Newtonian matrices

Shaocong Dai、Erwan Bertevas、Fuzhong Qi 等 4 位作者2013-02-06Journal of Rheology

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Shao-Cong Dai, Erwan Bertevas, Fuzhong Qi, Roger I. Tanner; Viscometric functions for noncolloida…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesComposite Material Mechanics

Bandwidth Enhancement of the Resonant Cavity Antenna by Using Two Dielectric Superstrates

Muhannad A. Al‐Tarifi、Dimitris E. Anagnostou、Anthony K. Amert 等 4 位作者2013-02-06IEEE Transactions on Antennas and Propagation

We propose a novel approach to enhance the bandwidth of the high directivity of the resonant cavity antenna (RCA) by applying two dielectric layers as superstrates. The approach is based on creating two cavities corresponding to two operating frequency bands that combine to form a single wide band of operation. The RC…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Fabrication of porous polyvinyl alcohol scaffold for bone tissue engineering via selective laser sintering

Cijun Shuai、Zhongzheng Mao、Haibo Lu 等 6 位作者2013-02-06Biofabrication

A tetragonal polyvinyl alcohol (PVA) scaffold with 3D orthogonal periodic porous architecture was fabricated via selective laser sintering (SLS) technology. The scaffold was fabricated under the laser power of 8 W, scan speed of 600 mm min(-1), laser spot diameter of 0.8 mm and layer thickness of 0.15 mm. The microstr…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Apparent elongational yield stress of soft matter

Laëtitia Martinie、H. Buggisch、N. Willenbacher2013-02-06Journal of Rheology

International audience

Polymer crystallization and propertiesMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Star‐Shaped Polymer Consisting of a Porphyrin Core and Poly( L ‐lysine) Dendron Arms: Synthesis, Drug Delivery, and In Vitro Chemo/Photodynamic Therapy

Dong Ma、Zonghua Liu、Qianqian Zheng 等 8 位作者2013-02-06Macromolecular Rapid Communications

A novel star-shaped polymer, porphyrin-poly(L-lysine) dendrons (PP-PLLD), is synthesized by the click reaction between azido-modified porphyrin and propargyl focal point poly(L-lysine) dendrons. Its chemical structure is characterized by (1) H nuclear magnetic resonance, Fourier transform infrared spectroscopy, and ge…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesDendrimers and Hyperbranched Polymers

Iron Hexacyanoferrate Nanoparticles as Cathode Materials for Lithium and Sodium Rechargeable Batteries

Seung‐Ho Yu、Mohammadreza Shokouhimehr、Taeghwan Hyeon 等 4 位作者2013-02-06ECS Electrochemistry Letters

Sodium and potassium iron hexacyanoferrate nanoparticles were synthesized by coprecipitation method. As-prepared nanoparticles were employed as cathode materials for lithium and sodium rechargeable batteries. Utilizing a well-defined Prussian blue structure exhibits high cyclic stability. In particular, NaFeHCF NPs de…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

In Situ Synthesis of Porous Fe3O4/C Microbelts and Their Enhanced Electrochemical Performance for Lithium-Ion Batteries

Leiming Lang、Zheng Xu2013-02-06ACS Applied Materials & Interfaces

The porous Fe3O4/C microbelts (FCBs) were synthesized by simple electrospinning method, combined with carbonization of the precursor microbelts at high temperature in N2 flow. Compared with α-Fe2O3 microbelt, the FCBs show better cyclic performance. The high capacity of 710 mA h g(-1) is still maintained after 50 cycl…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Doped Mott Insulators in (111) Bilayers of Perovskite Transition-Metal Oxides with a Strong Spin-Orbit Coupling

Satoshi Okamoto2013-02-06Physical Review Letters

The electronic properties of Mott insulators realized in (111) bilayers of perovskite transition-metal oxides are studied. The low-energy effective Hamiltonians for such Mott insulators are derived in the presence of a strong spin-orbit coupling. These models are characterized by the antiferromagnetic Heisenberg inter…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Parallel Screening of Electrocatalyst Candidates Using Bipolar Electrochemistry

Stephen E. Fosdick、Sean P. Berglund、C. Buddie Mullins 等 4 位作者2013-02-06Analytical Chemistry

Here we report simultaneous screening of bimetallic electrocatalyst candidates for the oxygen reduction reaction (ORR) using bipolar electrochemistry. The analysis is carried out by dispensing different bimetallic precursor compositions onto the cathodic poles of an array of bipolar electrodes (BPEs) and then heating…

Electrocatalysts for Energy ConversionConducting polymers and applicationsElectrochemical Analysis and Applications