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Extraction, Purification, and Characterization of Lignin Fractions from Sugarcane Bagasse

Aiping Zhang、Chuanfu Liu、Run‐Cang Sun 等 4 位作者2013-02-06BioResources

Three-step extraction of lignin fractions from ball-milled sugarcane bagasse (SCB) was studied with 96% dioxane, 50% dioxane, and 80% dioxane containing 1% NaOH at boiling temperature followed by purification to remove hemicelluloses. The total yields of hemicelluloses and lignin were 15.8% and 7.2% based on dried SCB…

Advanced Cellulose Research StudiesFermentation and Sensory AnalysisLignin and Wood Chemistry

Research on mechanism of ammonia escaping and control in the process of CO2 capture using ammonia solution

Shuangchen Ma、Song Huihui、Mengxuan Wang 等 5 位作者2013-02-06Process Safety and Environmental Protection

As CO2 is the major greenhouse gas, reducing its emission has become an attentive problem in the whole world. It is very important to develop CO2 capture technology for coal-fired power plants. Using ammonia solution to absorb CO2 from the flue gas, which is expected to have advantages of low cost, high efficiency and…

Catalytic Processes in Materials ScienceCarbon Dioxide Capture TechnologiesAmmonia Synthesis and Nitrogen Reduction

Hydrothermal Synthesis and Electrochemical Properties of Li2CoSiO4/C Nanospheres

Guang He、Guerman Popov、Linda F. Nazar2013-02-06Chemistry of Materials

A highly ordered mesoporous carbon/silica (MCS) framework was used as both a silicate precursor and carbon source to prepare Li 2 CoSiO 4 /carbon nanocomposites via hydrothermal synthesis. TEM-EDX and TGA measurements showed that ∼2 wt % carbon was incorporated within Li 2 CoSiO 4 crystal aggregates on the nanoscale.…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

DFT theoretical investigations of π-conjugated molecules based on thienopyrazine and different acceptor moieties for organic photovoltaic cells

Mohamed Bourass、Adil Touimi Benjelloun、M. Hamidi 等 11 位作者2013-02-06Journal of Saudi Chemical Society

In this work, theoretical study by using the DFT method on eleven conjugated compounds based on thienopyrazine is reported. Different electron side groups were introduced to investigate their effects on the electronic structure; The HOMO, LUMO and Gap energy of these compounds have been calculated and reported in this…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNonlinear Optical Materials Research

Adsorption removal of crystal violet from aqueous solution using a metal‐organic frameworks material, copper coordination polymer with dithiooxamide

Xiaojuan Li、Lingyan Zheng、Lianzhu Huang 等 8 位作者2013-02-06Journal of Applied Polymer Science

Abstract The potential application of copper coordination polymer with dithiooxamide (H2dtoaCu), one of the metal‐organic frameworks (MOFs) in the adsorption removal of crystal violet (CV) from aqueous solution was studied. Batch adsorption experiments were carried out as a function of initial pH, adsorbent concentrat…

Adsorption and biosorption for pollutant removalMetal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched Polymers

Approximations of the discrete slip-link model and their effect on nonlinear rheology predictions

Marat Andreev、Renat N. Khaliullin、Rudi J. A. Steenbakkers 等 4 位作者2013-02-06Journal of Rheology

The discrete slip-link model (DSM) was developed to describe the dynamics of flexible polymer melts. The model is able to predict linear viscoelasticity of monodisperse linear, polydisperse linear, and branched systems. The model also shows good agreement with dielectric relaxation experiments, except for the single d…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlood properties and coagulation

Non-reciprocity of dipole-exchange spin waves in thin ferromagnetic films

Mikhail Kostylev2013-02-06Journal of Applied Physics

The non-reciprocity and asymmetry of the modal profiles for dipole-exchange spin waves have been investigated theoretically. We were interested in the most important case for applications: the waves propagating in in-plane magnetized ferromagnetic films at a right angle to the applied magnetic field. For large-magneti…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Evaluation of Stiffness and Strength of Scots Pine Wood Using Resonance Frequency and Ultrasonic Techniques

Khaled Hassan、Petr Horáček、Jan Tippner2013-02-06BioResources

The aim of this paper was to predict the static bending modulus of elasticity (MOES) and modulus of rupture (MOR) of Scots pine (Pinus sylvestris L.) wood using three nondestructive techniques. The mean values of the dynamic modulus of elasticity based on flexural vibration (MOEF), longitudinal vibration (MOELV), and…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesTree Root and Stability Studies

Electronic Structures of Homoleptic [Tris(2,2′-bipyridine)M]nComplexes of the Early Transition Metals (M = Sc, Y, Ti, Zr, Hf, V, Nb, Ta;n= 1+, 0, 1–, 2–, 3−): An Experimental and Density Functional Theoretical Study

A.C. Bowman、Jason England、Stephen Sproules 等 5 位作者2013-02-06Inorganic Chemistry

The electronic structures of the complexes [M((t)bpy)(3)](0,1-) (M = Nb, Ta; (t)bpy = 4,4'-di-tert-butyl-2,2'-bipyridine) have been investigated using a combination of UV-vis spectroscopy, EPR spectroscopy, and XAS. Furthermore, the crystal structure of [Na(THF)(5)][Ta((t)bpy)(3)] has been determined. These studies we…

Advanced Chemical Physics StudiesOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexes

A Large Magnetoresistance Effect in p–n Junction Devices by the Space‐Charge Effect

Dezheng Yang、Fangcong Wang、Yang Ren 等 7 位作者2013-02-06Advanced Functional Materials

Abstract The finding of an extremely large magnetoresistance effect on silicon based p–n junction with vertical geometry over a wide range of temperatures and magnetic fields is reported. A 2500% magnetoresistance ratio of the Si p–n junction is observed at room temperature with a magnetic field of 5 T and the applied…

ZnO doping and propertiesQuantum and electron transport phenomenaAdvancements in Semiconductor Devices and Circuit Design

Reduction of the clogging potential of clays: new chemical applications and novel quantification approaches

R. Zumsteg、Michael Plötze、Alexander M. Puzrin2013-02-06Géotechnique

Earth pressure balance machines are increasingly being used for tunnelling in difficult soils and ground conditions. In clayey soils, clogging of the working tools is among the main hazards. Attempts to reduce this risk by adding anti-clogging chemicals do not always produce the desired effect. In this paper, the limi…

Diamond and Carbon-based Materials ResearchDrilling and Well EngineeringTunneling and Rock Mechanics

Discrete shape modeling for skin model representation

Min Zhang、Nabil Anwer、Andreas Stockinger 等 5 位作者2013-02-06Proceedings of the Institution of Mechanical Engineers Part B Journal of Engineering Manufacture

Nowadays, the management of product geometrical variations during the whole product development process is an important issue for companies’ competitiveness. During the design phase, geometric functional requirements and tolerances are derived from the design intent. Furthermore, the manufacturing and measurement stag…

3D Shape Modeling and AnalysisManufacturing Process and OptimizationTextile materials and evaluations

Recent Developments in the Study of Recrystallization

Peter W. Wilson2013-02-06InTech eBooks

Recrystallization is a phenomenon moderately well documented in the geological and metallurgical literature. This book provides a timely overview of the latest research and methods in a variety of fields where recrystallization is studied and is an important factor. The main advantage of a new look at these fields is…

Minerals Flotation and Separation TechniquesCrystallization and Solubility StudiesMineral Processing and Grinding

Amorphous Zinc Stannate (Zn2SnO4) Nanofibers Networks as Photoelectrodes for Organic Dye‐Sensitized Solar Cells

Seung‐Hoon Choi、Daesub Hwang、Dong Young Kim 等 8 位作者2013-02-06Advanced Functional Materials

Abstract A new strategy for developing dye‐sensitised solar cells (DSSCs) by combining thin porous zinc tin oxide (Zn2SnO4) fiber‐based photoelectrodes with purely organic sensitizers is presented. The preparation of highly porous Zn2SnO4 electrodes, which show high specific surface area up to 124 m2/g using electrosp…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesZnO doping and properties

Molecular or Nanoscale Structures? The Deciding Factor of Surface Properties on Functionalized Poly(3,4‐ethylenedioxythiophene) Nanorod Arrays

Hsing‐An Lin、Shyh‐Chyang Luo、Bo Zhu 等 6 位作者2013-02-06Advanced Functional Materials

Abstract Nanostructures of poly(3,4‐ethylenedioxythiophene) (PEDOT) are assembled by using an anodic aluminum oxide template directly fabricated on gold‐coated silicon wafers. Inside these templates, PEDOT and hydroxy functionalized PEDOT form tubes. On the other hand, alkyl‐ and perfluoro‐functionalized PEDOTs assemb…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAnodic Oxide Films and Nanostructures

High volumetric power density, non-enzymatic, glucose fuel cells

Vlad Oncescu、David Erickson2013-02-06Scientific Reports

The development of new implantable medical devices has been limited in the past by slow advances in lithium battery technology. Non-enzymatic glucose fuel cells are promising replacement candidates for lithium batteries because of good long-term stability and adequate power density. The devices developed to date howev…

Electrochemical sensors and biosensorsFuel Cells and Related MaterialsConducting polymers and applications

Study of support vector machine and serum surface-enhanced Raman spectroscopy for noninvasive esophageal cancer detection

Shaoxin Li、Qiuyao Zeng、Linfang Li 等 9 位作者2013-02-06Journal of Biomedical Optics

The ability of combining serum surface-enhanced Raman spectroscopy (SERS) with support vector machine (SVM) for improving classification esophageal cancer patients from normal volunteers is investigated. Two groups of serum SERS spectra based on silver nanoparticles (AgNPs) are obtained: one group from patients with p…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Chemometric AnalysesSpectroscopy Techniques in Biomedical and Chemical Research

Iodine (I2) as a Janus-Faced Ligand in Organometallics

Andrey Yu. Rogachev、Roald Hoffmann2013-02-06Journal of the American Chemical Society

The four known diiodine complexes have distinct geometries. These turn out, as we demonstrate by a bonding analysis, to be a direct consequence of diiodine acting as an acceptor in one set, the van Koten complexes, and as a donor in the Cotton, Dikarev, and Petrukhina extended structure. The primary analytical tool ut…

Magnetism in coordination complexesCrystallography and molecular interactionsVanadium and Halogenation Chemistry

1:2‐sequence‐regulated radical copolymerization of naturally occurring terpenes with maleimide derivatives in fluorinated alcohol

Masaru Matsuda、Kotaro Satoh、Masami Kamigaito2013-02-06Journal of Polymer Science Part A Polymer Chemistry

Abstract Naturally occurring bulky terpenes, such as (+)‐ and (–)‐limonene and (–)‐β‐pinene, were quantitatively copolymerized with maleimide (MI) derivatives (i.e., phenyl‐, cyclohexyl‐, ethyl‐, and unsubstituted‐MI) in PhC(CF3)2OH solvent via selective 1:2‐alternating propagation governed by the penultimate effect,…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods

Uniaxial extensional rheology of well-characterized comb polymers

Helen Lentzakis、D. Vlassopoulos、Daniel J. Read 等 7 位作者2013-02-06Journal of Rheology

We present a detailed systematic investigation of the transient uniaxial extensional response of a series of well-characterized, anionically synthesized comb polystyrenes and polyisoprenes. The comb architecture consists of a linear chain backbone with multiple branches of equal molar mass, and represents an excellent…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites