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A failure-mode based anisomorphic constant life diagram for a unidirectional carbon/epoxy laminate under off-axis fatigue loading at room temperature

M. Kawai、Naohiro Itoh2013-02-20Journal of Composite Materials

The off-axis constant fatigue life diagrams for a unidirectional carbon/epoxy laminate in different fiber orientations are identified over the whole range of stress ratio. The experimental results show that the off-axis constant fatigue life diagram plotted in the plane of alternating and mean stresses tends to shrink…

Mechanical Behavior of CompositesFatigue and fracture mechanicsTextile materials and evaluations

Iron Oxide Nanoparticle-Micelles (ION-Micelles) for Sensitive (Molecular) Magnetic Particle Imaging and Magnetic Resonance Imaging

Lucas W. E. Starmans、Dirk Burdinski、Nicole P. M. Haex 等 7 位作者2013-02-20PLoS ONE

BACKGROUND: Iron oxide nanoparticles (IONs) are a promising nanoplatform for contrast-enhanced MRI. Recently, magnetic particle imaging (MPI) was introduced as a new imaging modality, which is able to directly visualize magnetic particles and could serve as a more sensitive and quantitative alternative to MRI. However…

Nanoparticle-Based Drug DeliveryGeomagnetism and Paleomagnetism StudiesCharacterization and Applications of Magnetic Nanoparticles

Photodegradation of Orange II under Visible Light Using Cu–Ni/TiO2: Influence of Cu:Ni Mass Composition, Preparation, and Calcination Temperature

Nadia Riaz、Fai Kait Chong、Zakaria Man 等 5 位作者2013-02-20Industrial & Engineering Chemistry Research

Bimetallic Cu–Ni/TiO 2 photocatalysts were prepared at different temperatures with varying Cu:Ni mass compositions. The photocatalysts were further calcined at selected temperatures. Characterization procedures were carried out on the photocatalysts to understand the correlation between the photocatalytic activity and…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Effect of Electrode Materials on AlN-Based Bipolar and Complementary Resistive Switching

Chao Chen、Shuang Gao、Guangsheng Tang 等 8 位作者2013-02-20ACS Applied Materials & Interfaces

We report the complementary resistive switching (CRS) behaviors in aluminum nitride (AlN)-based memory devices as the promising new material system for large-scale integration of passive crossbar arrays. By utilizing different electrodes (Cu, Pt, and TiN), CRS characteristics are demonstrated in both TiN/AlN/Cu/AlN/Ti…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsFerroelectric and Negative Capacitance Devices

Lanthanide-Porphyrin Hybrids: from Layered Structures to Metal–Organic Frameworks with Photophysical Properties

Jan Demel、Pavel Kubát、Franck Millange 等 6 位作者2013-02-20Inorganic Chemistry

Rare-earth layered hydroxides with intercalated tetrasulfonated porphyrins and corresponding to the chemical formula Ln2(OH)4.7(Por)0.33·2H2O (Ln = Eu(3+), Tb(3+); Por = 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) and PdTPPS) have been prepared to investigate their photophysical properties. A slight variati…

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Development of MRI phantom equivalent to human tissues for 3.0‐T MRI

Kengo Hattori、Yusuke Ikemoto、Wataru Takao 等 10 位作者2013-02-20Medical Physics

PURPOSE: A 3.0-T MRI phantom (called the CAGN-3.0T phantom) having human-equivalent relaxation times and human-equivalent conductivity was developed. METHODS: The ingredients of the phantom are carrageenan (as a gelatinizer), agarose (as a T2-relaxation modifier), GdCl3 (as a T1-relaxation modifier), NaCl (as a conduc…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Modeling Liquid Bridge between Surfaces with Contact Angle Hysteresis

H. Chen、Alidad Amirfazli、Tian Tang2013-02-20Langmuir

This paper presents the behaviors of a liquid bridge when being compressed and stretched in a quasi-static fashion between two solid surfaces that have contact angle hysteresis (CAH). A theoretical model is developed to obtain the profiles of the liquid bridge given a specific separation between the surfaces. Differen…

Surface Modification and SuperhydrophobicityForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Improvement of Nanoprecipitation Technique for Preparation of Gelatin Nanoparticles and Potential Macromolecular Drug Loading

Saeed Ahmad Khan、Marc Schneider2013-02-20Macromolecular Bioscience

An optimum nanoprecipitation technique for gelatin nanoparticles is established, based on aqueous gelatin solution and ethanolic solution containing stabilizer. Crosslinking with glutaraldehyde results in stable gelatine nanoparticles. Several factors such as the surfactant concentration, type of surfactant, type of n…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsAdvanced Drug Delivery Systems

Migration Insertion Polymerization (MIP) of Cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP): A New Concept for Main Chain Metal-Containing Polymers (MCPs)

Xiaosong Wang、Kai Cao、Yibo Liu 等 5 位作者2013-02-20Journal of the American Chemical Society

We report a conceptually new polymerization technique termed migration insertion polymerization (MIP) for main chain metal-containing polymer (MCP) synthesis. Cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP) is synthesized and polymerized via MIP, resulting in air stable poly(cyclopentadienylcarbonyldipheny…

Organometallic Complex Synthesis and CatalysisPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods

Reference Region Approaches in PET: a Comparative Study on Multiple Radioligands

Francesca Zanderigo、R. Todd Ogden、Ramin V. Parsey2013-02-20Journal of Cerebral Blood Flow & Metabolism

Reference region (RR) approaches (RRAs) for positron emission tomography (PET) brain studies aim to obtain full quantification without arterial input function (IF) sampling, an invasive and costly procedure. Although they need a reliable RR and are only able to estimate the nondisplaceable binding potential (BPND), RR…

Advanced MRI Techniques and ApplicationsMedical Imaging Techniques and ApplicationsLanthanide and Transition Metal Complexes

Photo- and Thermal-Induced Multistructural Transformation of 2-Phenylazolyl Chelate Boron Compounds

Yingli Rao、Hazem Amarne、Leanne D. Chen 等 6 位作者2013-02-20Journal of the American Chemical Society

The new N,C-chelate boron compounds B(2-phenylazolyl)Mes2 [Mes = mesityl; azolyl = benzothiazolyl (1a), 4-methylthiazolyl (2a), benzoxazolyl (3a), benzimidazolyl (4a)] undergo an unprecedented multistructural transformation upon light irradiation or heating, sequentially producing isomers b, c, d, and e. The dark isom…

Radical Photochemical ReactionsLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Effect of Basalt Fiber on the Asphalt Binder and Mastic at Low Temperature

Dong Wang、Linbing Wang、Xinyu Gu 等 4 位作者2013-02-20Journal of Materials in Civil Engineering

The effect of basalt fiber on asphalt binder and mastic at low temperatures is investigated in this study. Basalt fibers are dispersed into the asphalt binder and mastic specimens to prepare the fiber-reinforced binding materials. The fiber-reinforced specimens are tested using the direct tension test and a newly deve…

Asphalt Pavement Performance EvaluationNatural Fiber Reinforced CompositesInnovative concrete reinforcement materials

Hierarchically Plasmonic Z-Scheme Photocatalyst of Ag/AgCl Nanocrystals Decorated Mesoporous Single-Crystalline Metastable Bi20TiO32 Nanosheets

Jungang Hou、Zheng Wang、Chao Yang 等 6 位作者2013-02-20The Journal of Physical Chemistry C

The hierarchical photocatalysts of Ag–AgCl@Bi 20 TiO 32 composites have been successfully synthesized by anchoring Ag–AgCl nanocrystals on the surfaces of mesoporous single-crystalline metastable Bi 20 TiO 32 nanosheets via a two-stage strategy for excellent visible-light-driven photocatalytic activities in the Z-sche…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Multiple Lanthanide Helicate Clusters and the Effects of Anions on Their Configuration

Bei Wang、Zhipeng Zang、Haihong Wang 等 10 位作者2013-02-20Angewandte Chemie International Edition

Shaping up your clusters: Two supramolecular clusters of multiple lanthanide helicates have been synthesized. Cluster structure is controlled by the choice of anion, with tetrahedral ClO4− producing larger circular helicates, and trigonal-planar NO3− leading to a compact quadruple-stranded helicate (see picture).

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesSynthesis and Properties of Aromatic Compounds

Functional graphene oxide as a plasmid-based Stat3 siRNA carrier inhibits mouse malignant melanoma growth in vivo

Di Yin、Yang Li、Hang Lin 等 10 位作者2013-02-20Nanotechnology

Graphene oxide (GO) has attracted intensive interest in the biomedical field in recent years. We investigate whether the use of functional graphene oxide as an efficient delivery system for delivering specific molecular antitumor therapeutics in vivo could achieve a more excellent antitumor effect. Constitutive activa…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryGraphene and Nanomaterials Applications

Synthesis of Cyclic Carbonates from Epoxides and CO2 under Mild Conditions Using a Simple, Highly Efficient Niobium‐Based Catalyst

Antoine Monassier、Valerio D’Elia、Mirza Cokoja 等 7 位作者2013-02-20ChemCatChem

Like a sore thumb: Niobium stands out among neighboring transition metals for its catalytic performance in the synthesis of cyclic carbonates. Readily available NbCl5 is a very efficient catalyst for the preparation of industrially relevant carbonates at ambient temperature, low CO2 pressure, and low concentrations. D…

biodegradable polymer synthesis and propertiesAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysis

Criteria for Shear Banding in Time-Dependent Flows of Complex Fluids

Robyn L. Moorcroft、Suzanne M. Fielding2013-02-20Physical Review Letters

We study theoretically the onset of shear banding in the three most common time-dependent rheological protocols: step stress, finite strain ramp (a limit of which gives a step strain), and shear startup. By means of a linear stability analysis we provide a fluid-universal criterion for the onset of banding for each pr…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesBlood properties and coagulation

Nanostructured 3D Constructs Based on Chitosan and Chondroitin Sulphate Multilayers for Cartilage Tissue Engineering

Joana M. Silva、Nicole Georgi、Rui R. Costa 等 8 位作者2013-02-20PLoS ONE

Nanostructured three-dimensional constructs combining layer-by-layer technology (LbL) and template leaching were processed and evaluated as possible support structures for cartilage tissue engineering. Multilayered constructs were formed by depositing the polyelectrolytes chitosan (CHT) and chondroitin sulphate (CS) o…

Bone Tissue Engineering MaterialsOsteoarthritis Treatment and MechanismsSilk-based biomaterials and applications

Urinary Phthalate Metabolites Are Associated with Body Mass Index and Waist Circumference in Chinese School Children

Hexing Wang、Ying Zhou、Chuanxi Tang 等 7 位作者2013-02-20PLoS ONE

BACKGROUND: Lab studies have suggested that ubiquitous phthalate exposures are related to obesity, but relevant epidemiological studies are scarce, especially for children. OBJECTIVE: To investigate the association of phthalate exposures with body mass index (BMI) and waist circumference (WC) in Chinese school childre…

Effects and risks of endocrine disrupting chemicalsPolymer Science and PVCHealth, Environment, Cognitive Aging

Mixed‐Ligand Zn‐MOFs for Highly Luminescent Sensing of Nitro Compounds

Hao Wang、Weiting Yang、Zhong‐Ming Sun2013-02-20Chemistry - An Asian Journal

Three Zn(II) metal-organic frameworks (Zn-MOFs), [Zn2(tib)(HL(1))(H2L(1))0.5]·2H2O (1), [Zn2(tib)(L(2))]·H2O (2) and [Zn3(tib)(L(3))2(H2O)6]·2 H2O (3), have been prepared by reactions of 1,3,5-tris(1-imidazolyl)benzene (tib), and biphenyl-3,3',4,4'-tetracarboxylic acid (H4L(1)), 4,4'-oxydiphthalic acid (H4L(2)), or be…

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionAdvanced Nanomaterials in Catalysis