Materials Literature
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This paper reports on the characteristics and use of a new mode of measurement: High Performance DSC (HPer DSC), which represents a major step forward in high-speed calorimetry, as compared to standard DSC. It facilitates the study of the kinetics and metastability of macromolecular systems, especially the analysis of…
Carbon nanotubes are functionalized by bovine serum albumin (BSA) proteins via diimide-activated amidation under ambient conditions. The nanotube-BSA conjugates thus obtained are highly water-soluble, forming dark-colored aqueous solutions. Results from characterizations using atomic force microscopy (AFM), thermal gr…
An anodic oxidized film has been deposited in pure water at room temperature. Film thickness increases linearly as a function of total charge during oxidation. High film deposition rate and low surface roughness are obtained by alternately changing the polarity of the applied voltage. The film growth mechanism is disc…
Rationally controlled growth of inorganic semiconductor nanowires is important for their applications in nanoscale electronics and photonics. In this article, we discuss the rational growth, physical properties, and integration of nanowires based on the results from the authors' laboratory. The composition, diameter,…
Ion generation and recombination have been characterized in nematic liquid crystal displays. A model for dispersive generation may explain the time dependency of the leakage current through the cell. This current leads to the build-up of a charge layer near the electrodes depending on the resistivity of the alignment…
A symmetric binary mixture containing mobile nanoscale rods is quenched from a one-phase state into an unstable phase-separating region. Incorporating the motion of rods, the system undergoes spinodal decomposition to form a dropletlike structure. The rod-rod interaction and the preferential adsorption of one of the t…
A doubly symmetric electrostatic corrector which compensates for the axial chromatic and the axial third-order aberration of charged-particle lenses is outlined. Due to the double symmetry the corrector does not introduce linear off-axis aberrations and yields in combination with a round objective lens an electron-opt…
Structural models obtained using classical molecular dynamics (MD) simulations and realistic interatomic potentials for solid metals are tested using experimental results obtained by x-ray absorption spectroscopy (XAS). Accurate L-edge extended x-ray absorption fine-structure (EXAFS) measurements of Pb grains disperse…
Gd 2 SiO 5 is among the interesting and suitable hosts for Er 3+ which find extensive applications in the infrared, visible and ultraviolet spectral regions. In order to investigate its potentialities, a prior study of the spectroscopic behaviour of Er 3+ substituting for Gd 3+ ions in the two crystallographic sites o…
The anisotropic thermal expansion of BiB3O6 (BIBO) has been studied in the temperature range 25 °C to 299.5 °C. The three values of principal expansion coefficients α1, α2, and α3 and the orientation of the principal axes are −26.43×10−6 K−1, 50.4×10−6 K−1, 8.53×10−6 K−1, and 8.9°, respectively. Large anisotropic ther…
Novel silver(I) complexes 1 and 2 derived from tetrakis(methylthio)tetrathiafulvalene (TMTTTF) and bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF), respectively, were prepared by the self-assembly approach. Their crystal structures were determined. Complex 1 shows a three-dimensional structure with an unprecedented 4…
Characterizations of Fine-pitched Carbon Nanotube Pixels for Field Emitter Arrays, Cho, Young-Rae, Lee, Jin Ho, Hwang, Chi-Sun, Song, Yoon-Ho, Uhm, Hyun-Seok, Kim, Do-Hyung, Ahn, Seong-Deok, Chung, Choong Heui, Kim, Bong-Chul, Cho, Kyoung Ik
Irreversible adsorption of hard spheres at random site surfaces was studied theoretically. In contrast to the previous model of Jin et al. [J. Phys. Chem. 97, 4256 (1993)] the dimension of the sites, having the shape of circular disks, was finite and comparable with the size of adsorbing spheres. Adsorption was assume…
As a part of a broader study directed towards helical coordination compounds with benzenedithiolate donors, we have synthesized the bis(benzenedithiol) ligands 1,2-bis(2,3-dimercaptobenzamido)ethane (H(4)-1) and 1,2-bis(2,3-dimercaptophenyl)ethane (H(4)-2). Both ligands form dinuclear complexes with Ni(II), Ni(III) an…
A comprehensive presentation of the temperature evolution of "linear" and "nonlinear" dielectric relaxation in the isotropic phase of nematic liquid crystalline compound 5CB (4-cyano-4-n-pentylbiphenyl) is given. The "nonlinear" relaxation is related to the strong pretransitional rise in the lifetime of prenematic flu…
Domain configuration and ferroelectric related properties of Pb(Mg 1/3 Nb 2/3 )O 3 –PbTiO 3 were investigated as a function of applied electric field for the (110) cub cuts. It was found that a single domain orthorhombic state could be achieved by applying an electric field along the direction <110> cub , but the stat…
The preparation of the thiol-derivatised iron(II) phthalocyanine (FePc) complex, 2,3,9,10,16,17,23,24-octabutylthiophthalocyaninatoiron(II), FePc(SC4H9)8, is described. Electrochemical data obtained by both cyclic voltammetry and Osteryoung square wave voltammetry in DMF showed four redox couples. Kinetics and equilib…
Chemical vapor deposition (CVD) has been used to grow sulfur doped diamond films on undoped Si and single crystal HPHT diamond as substrates, using a 1% CH4/H2 gas mixture with various levels of H2S addition (100–5000 ppm), using both microwave (MW) plasma enhanced CVD and hot filament (HF) CVD. The two deposition tec…
A new layered strontium cobaltite, Sr x CoO 2 , was synthesized by a low-temperature ion-exchange technique from a γ-Na 0.7 CoO 2 precursor. The strontium content was determined to be x = 0.345 by inductively coupled plasma (ICP) analysis. Rietveld analysis of X-ray powder diffraction data indicates that strontium ion…
Domain structures of unpoled as well as poled (along [001]- and [110]-direction) Pb(Zn1/3Nb2/3)O3 (PZN)-8% PbTiO3 (PT) and Pb(Mg1/3Nb2/3)O3 (PMN)-29% PT single crystals have been investigated by scanning force microscopy (SFM) in the piezoresponse mode, at room temperature. Antiparallel domain structures have been det…