Materials Literature
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A series of phospho-polyoxotungstate anions was transferred to the gas phase via electrospray ionization (ESI), and the anions' fragmentation was examined by collision-induced dissociation (CID). The anions included [PW12O40]3-, [P2W18O62]6-, and {Co4(H2O)2][PW9O34]2}10- as well as lacunary and metal-substituted deriv…
The photophysical properties of three new water-soluble terrylenediimide (WS-TDI) derivatives are investigated and their utilization in biological experiments is demonstrated. Each of these dyes can be excited in the far red region of the visible spectrum, making them good candidates for in-vivo studies. Single-molecu…
Hydrogen storage: Simple organic molecular systems (C(n)H(n), n=4, 5, 6, 8) are proposed for hydrogen storage purposes based on the concept of aromaticity. The adsorption of hydrogen is attributed to pronounced charge transfer from the sodium atom (green, see picture) to the organic systems and the electrostatic inter…
Morphology and conductivity modifications in poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) films induced by conductive atomic force microscopy probe are investigated. At an applied bias of positive or negative 10 V, raised features of 12.8±1.8 nm in height are generated and the local film conduc…
The efficacy of folate-targeted liposomal drug delivery has not been fully achieved in part because of the slow release of the encapsulated drugs following uptake of the liposomes by target cells. Since liposomal mitoxantrone (MXN) composed of lipids with high fluidity was reported to achieve strong anticancer effects…
We analyze the electronic properties of a simple stacking defect in Bernal graphite. We show that a bound state forms, which disperses as ${|\mathbit{k}\ensuremath{-}\mathbit{K}|}^{3}$, in the vicinity of either of the two inequivalent zone corners $\mathbit{K}$. In the presence of a strong $c$-axis magnetic field, th…
We report the growth of ZnS nanowires doped with cobalt using a one-step thermal evaporation method. The magnetism of the nanowires was maintained at room temperature, and the saturated magnetization increased with cobalt contents. Current-voltage measurements of a single nanowire showed not only a linear relationship…
A multi-addressable switching system has been constructed by employing photochromic diarylethene 1a, which is obtained by coupling photochromic 3,4-bis(5-formyl-2-methylthien-3-yl)-2,5-dihydrothiophene with 8-hydroxy-2-methylquinoline, as model compound. It is found that 1a exhibits ring-opening and ring-closing photo…
We theoretically investigate the optical properties of semiconductor- and metal-type armchair-edge graphene nanoribbon irradiated under an external longitudinal polarized electromagnetic field at low temperatures, respectively. Within the framework of linear response theory in the perturbation regime, we examine the r…
Poly(vinyl alcohol)-graft-lactic acid (PVA-g-LA) was synthesized by melt polycondensation of PVA and lactic acid using stannous chloride as a catalyst. The molecular structure of the copolymer was characterized by 1 H NMR. The thermal properties of PVA-g-LA were investigated by differential scanning calorimetry and th…
Single crystals of ferroelectric (1−x)Bi0.5Na0.5TiO3–xBi0.5K0.5TiO3 (BKT) solid solution with rhombohedral structure were grown by flux method in the composition range of 0<x<0.14. The polarization hysteresis, electric-field-induced strain, and temperature dependence of dielectric permittivity were inves…
BiFeO 3 films of different thicknesses were grown on the LaNiO3-buffered Si (100) substrate via a sol-gel spin-coating processing. X-ray diffraction and Raman spectra studies revealed a thickness dependent structural and strain state evolution. The thickness dependent size effect on ferroelectric behavior was reflecte…
One-dimensional (1D) mesoporous carbons with highly ordered 3D interconnected pore structure and large-diameter pore size (10-20 nm) have been synthesized by a simple precursor-controlled thermolysis approach; such unique carbonaceous frameworks show superior capacitive behavior in electrochemical double-layer capacit…
We developed a fully analytical ballistic theory of carbon nanotube field effect transistors enabled by the development of an analytical surface potential capturing the temperature dependence and gate and quantum capacitance electrostatics. The analytical ballistic theory is compared to the experimental results of a b…
An unusual [Mn(IV)Gd(III)(2)(mu(3)-O(2-))](8+) triangular complex has been prepared from the initial use of 2,6-diacetylpyridine dioxime (dapdoH(2)) in 3d/4f cluster chemistry. The complex has an S = (13)/(2) ground state, with exchange parameters J = +0.49 cm(-1) and J' = -0.12 cm(-1) [H = -2J(S(i) x S(j)) convention…
Electromigration failure kinetic has been studied with resistance evolution versus time of interconnects during degradation. Tests were performed on dual damascene copper lines, issued from the 65 nm technology node, of various widths and lengths. All samples exhibit similar resistance evolution: an initial step, char…
The X-ray crystallographic structure of cellulose III(II) is characterized by disorder; the unit cell (space group P2(1); a = 4.45 A, b = 7.64 A, c = 10.36 A, alpha = beta = 90 degrees, gamma = 106.96 degrees) is occupied by one chain that is the average of statistically disordered antiparallel chains. 13C CP/MAS NMR…
Chemically synthesized colloidal quantum dots can easily be incorporated into conjugated polymer host systems allowing for novel organic/inorganic hybrid materials combining the natural advantages from both organic as well as inorganic components into one system. In order to obtain tailored optoelectronic properties,…
We report solar cells based on high-density p-n heterojunctions between single wall carbon nanotubes (SWCNTs) and a n-type silicon wafer. Chemical modification by thionyl chloride of the SWCNT coating films was found to significantly increase the conversion efficiency by more than 45% through adjusting the Fermi level…
Lithium niobates and tantalates have a number of characteristics exploitable for optical and electrical devices that include ion conductivity, self-activating or dopant luminescence, piezoelectricity, pyroelectricity and ferroelectricity. To form these materials as nanometric powders or thin-film coatings, soft-chemic…