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Fabrication of High-Density Polymer Brush on Polymer Substrate by Surface-Initiated Living Radical Polymerization

Chiaki Yoshikawa、Atsushi Goto、Yoshinobu Tsujii 等 6 位作者2005-05-01Macromolecules

A well-defined, high-density poly(2-hydroxyethyl methacrylate) (PHEMA) brush was fabricated on the surface of a poly(tetrafluoroethylene- co -hexafluoropropylene) (FEP) film by surface-initiated living radical polymerization (LRP). First, a sufficient amount of peroxides as initiating moieties were successfully introd…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Miniature fiber-optic multicavity Fabry–Perot interferometric biosensor

Yan Zhang、Helen Shibru、Kristie L. Cooper 等 4 位作者2005-05-01Optics Letters

A fiber-optic sensor is designed based on multicavity Fabry-Perot interferometry for the study of optical thickness in self-assembled thin-film layers. This miniature sensor is applicable not only to the measurement of self-assembled polyelectrolyte layers but also to the immobilization of proteins such as immunoglobu…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAcoustic Wave Resonator Technologies

Simulation of structural phase transitions by metadynamics

Roman Martoňák、Alessandro Laio、Marco Bernasconi 等 7 位作者2005-05-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract We describe here in detail the recently introduced methodology for simulation of structural transitions in crystals. The applications of the new scheme are illus trated on various kinds of crystals and the advantages with respect to previous schemes are emphasized. The relevance of the new method for the prob…

Theoretical and Computational PhysicsScientific Research and DiscoveriesMaterial Properties and Failure Mechanisms

GDIS: a visualization program for molecular and periodic systems

Sean D. Fleming、Andrew L. Rohl2005-05-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract GDIS is a freely available chemical visualization program for displaying molecules, periodic structures, and crystal morphologies. A key feature of the package is the mechanism for constructing and manipulating arbitrary crystal surfaces. This enables GDIS to offer a powerful tool set for computing surface an…

Zeolite Catalysis and SynthesisCrystallization and Solubility StudiesX-ray Diffraction in Crystallography

New Structural Motifs, Unusual Quenching of the Emission, and Second Harmonic Generation of Copper(I) Iodide Polymeric or Oligomeric Adducts with Para-Substituted Pyridines or trans-Stilbazoles

Elena Cariati、Dominique Roberto、Renato Ugo 等 6 位作者2005-05-01Inorganic Chemistry

The structural, emissive, and nonlinear optical properties of new CuI adducts with para-substituted trans-stilbazolic and pyridinic ligands are reported. Single-crystal X-ray diffraction results indicate that the para-substituent on the organic ligand greatly influences the structural motif by its steric (tert-butyl),…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Bulk Ring-Opening Polymerization of Lactides Initiated by Ferric Alkoxides

Xiaoying Wang、Kairong Liao、Daping Quan 等 4 位作者2005-05-01Macromolecules

Ferric alkoxides (Fe(OR) 3 ), where R = Et, n Pr, i Pr, and n Bu, were used as initiators for bulk ring-opening polymerization of lactides. It was showed that these ferric alkoxides were efficient initiators for the ring-opening polymerization of lactides with higher than 90% of monomer conversions polymerized at 130…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

CVD Growth of Single-Walled Carbon Nanotubes with Narrow Diameter Distribution over Fe/MgO Catalyst and Their Fluorescence Spectroscopy

Hiroki Ago、Shingo Imamura、Toshiya Okazaki 等 6 位作者2005-05-01The Journal of Physical Chemistry B

Single-walled carbon nanotubes (SWNTs) with a narrow diameter distribution are synthesized by thermal chemical vapor deposition (CVD) of methane over Fe/MgO catalyst on the basis of parametric study considering Fe loading, reaction temperature and time, methane concentration, and structure of a support material. We fo…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Tissue Engineering of Recellularized Small-Diameter Vascular Grafts

Gregory H. Borschel、Yen-Chih Huang、Sarah Calve 等 9 位作者2005-05-01Tissue Engineering

A tissue-engineered small-diameter arterial graft would be of benefit to patients requiring vascular reconstructive procedures. Our objective was to produce a tissue-engineered vascular graft with a high patency rate that could withstand arterial pressures. Rat arteries were acellularized with a series of detergent so…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative MedicineInfectious Aortic and Vascular Conditions

A New Route to Monolithic Methylsilsesquioxanes: Gelation Behavior of Methyltrimethoxysilane and Morphology of Resulting Methylsilsesquioxanes under One-Step and Two-Step Processing

Hanjiang Dong、Michael A. Brook、John D. Brennan2005-05-01Chemistry of Materials

Polymerization of methyltrimethoxysliane (MTMS) results in methylsilsesquioxane (MSQ), which has found important applications in recent years including use as low- k dielectric materials in the semiconductor industry, superhydrophobic materials, monolithic columns, and hybrid matrixes for immobilizing proteins. For po…

Surface Modification and SuperhydrophobicityCopper Interconnects and ReliabilitySilicone and Siloxane Chemistry

Functionalized Gold Nanoparticles for Applications in Bionanotechnology

Wilhelm R. Glomm2005-05-01Journal of Dispersion Science and Technology

Gold nanoparticles have unique optical and chemical properties that make them ideally suited for a number of applications in bionanotechnology, including optical probes, targeted drug delivery, and programmed materials synthesis. The recurring theme is the versatility of gold nanoparticles and how this versatility can…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniques

Linear tunable phase shifter using a left-handed transmission line

Hongjoon Kim、Alexander B. Kozyrev、A. Karbassi 等 4 位作者2005-05-01IEEE Microwave and Wireless Components Letters

We demonstrate a compact, linear, and low loss variation hybrid phase shifter using a left-handed (LH) transmission line. For frequencies from 4.3 to 5.6 GHz, this phase shifter gives a nearly linear phase variation with voltage, with a maximum deviation of /spl plusmn/7.5/spl deg/. Within this frequency range, the ma…

Metamaterials and Metasurfaces ApplicationsAnimal Vocal Communication and BehaviorNeural Networks and Reservoir Computing

Development of Innovative Three-Way Catalysts Containing Ceria–Zirconia Solid Solutions with High Oxygen Storage/Release Capacity

Masahiro Sugiura、Masakuni Ozawa、Akihiko Suda 等 5 位作者2005-05-01Bulletin of the Chemical Society of Japan

Abstract Innovative three-way catalysts containing ceria–zirconia solid solutions (CZ) with a ZrO2 content ranging from 5 to 75 mol% were developed. Such catalysts have very high oxygen storage/release capacity (OSC). The OSC of catalysts containing first-generation CZ was found to increase linearly with the amount of…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16

Kang Min Ok、P. Shiv Halasyamani2005-05-01Inorganic Chemistry

Two new mixed-metal tellurites, Na1.4Nb3Te4.9O18 and NaNb3Te4O16, have been synthesized by standard solid-state techniques using Na2CO3, Nb2O5, and TeO2 as reagents. The structures of Na1.4Nb3Te4.9O18 and NaNb3Te4O16 were determined by single-crystal X-ray diffraction. Both of the materials exhibit three-dimensional s…

Ferroelectric and Piezoelectric MaterialsCrystal Structures and PropertiesNuclear materials and radiation effects

Systematic Study on Experimental Conditions for Large-Scale Growth of Aligned ZnO Nanwires on Nitrides

Song、Wang、Elisa Riedo 等 4 位作者2005-05-01The Journal of Physical Chemistry B

In vapor-liquid-solid (VLS) growth, it is generally believed that nanowires would grow as long as the right catalysts and substrate are supplied as well as the growth temperature is adequate. We show here, however, that oxygen partial pressure plays a key role in determining the quality of the aligned ZnO nanowires. W…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Cell Morphology and Mechanical Properties of Rigid Polyurethane Foam

M. Cameron Hawkins、Brendan O’Toole、Dacia Jackovich2005-05-01Journal of Cellular Plastics

Polyurethane foam, used as a supporting or insulating material, is sometimes formed in complex molds with significant variations in geometry and size. This work investigates the relationships between cell morphology, density, and mechanical properties in a molded polyurethane material using relatively small cylindrica…

Cellular and Composite StructuresPolymer composites and self-healingPolymer Foaming and Composites

Liposomes in the treatment of inflammatory disorders

Josbert M. Metselaar、Gert Storm2005-05-01Expert Opinion on Drug Delivery

This review focuses on the therapeutic utility of liposomes in the treatment of inflammatory disorders, and aims to offer the reader an overview of the in vivo results obtained with liposomally encapsulated anti-inflammatory and immune suppressive drugs. The past 30 years has clearly indicated the added value of lipos…

Nanoparticle-Based Drug DeliveryImmunotherapy and Immune ResponsesRNA Interference and Gene Delivery

Synthesis and Optical Properties of Conjugated Polymers Containing Polyoxometalate Clusters as Side-Chain Pendants

Bubin Xu、Meng Kai Lü、Jeonghee Kang 等 6 位作者2005-05-01Chemistry of Materials

Hexamolybdate clusters have been covalently attached, for the first time, to the side chains of conjugated polymers. Two sets of such hybrid conjugated polymers have been prepared, one ( Ia and Ib ) with the clusters linked to the conjugated backbone through a rigid conjugated bridge, the other ( IIa and IIb ) through…

Metal-Organic Frameworks: Synthesis and ApplicationsConducting polymers and applicationsPolyoxometalates: Synthesis and Applications

Experiment of Commercial Heat Treatment Process for 82 mm Plate of Steel 14Cr1MoR

杨海林、杨秀芹2005-05-01Teshugang

The experiment of commercial heat treatment process for 82 mm plate of steel 14Cr1MoR (0. 15C- 1.48Cr- 0.57Mo)has been carried out at Wuyang Iron and Steel. The test results showed that heat- treated with 9℃/min heating up speed, austenite conditioning at 930 ℃ for 2.4 min/mm,water quenching at 870 ℃,and tempering at…