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In vitro cell response to differences in poly-L-lactide crystallinity

Ann Park、Linda G. Cima1996-05-01Journal of Biomedical Materials Research

Many different processing techniques are currently being used to produce tissue regeneration devices from polyesters in the polylactide/polyglycolide family. While it is generally well recognized that processing techniques influence bulk mechanical and degradation properties of these materials, the effects on surface…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

Illitization of diagenetic kaolinite-to-dickite conversion series; late-stage diagenesis of the Lower Permian Rotliegend Sandstone reservoir, offshore of the Netherlands

Bruno Lanson、Daniel Beaufort、Gilles Berger 等 5 位作者1996-05-01Journal of Sedimentary Research

Abstract This paper describes the diagenetic evolution of clay minerals in the Rotliegend sandstone reservoir under contrasting burial histories in the Broad Fourteens basin (Dutch sector, Southern North Sea). The diagenetic modifications affecting the crystal structure of clay minerals (both kaolin-group and illitic…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Reaction Products Formed in Lime-Stabilized Marine Clays

S. Narasimha Rao、G. Rajasekaran1996-05-01Journal of Geotechnical Engineering

The use of lime to improve the behavior of marine clays has been in practice in several parts of the world over a long period. In this paper, the beneficial changes occurred in a marine clay due to the diffusion of lime from lime column and lime injected points have been studied using XRD and SEM techniques. The new c…

Soil and Unsaturated FlowClay minerals and soil interactionsGeotechnical and construction materials studies

Export of Cadmium and Phytochelatin by the Marine Diatom Thalassiosira weissflogii

Jennifer G. Lee、Beth A. Ahner、François M. M. Morel1996-05-01Environmental Science & Technology

Cadmium is one of the most toxic trace metals and induces high concentrations of the metal-binding polypeptide phytochelatin, (γ-Glu-Cys) n Gly where n ≥ 2, in the marine diatom Thalassiosira weissflogii . Here we show that at high inorganic cadmium concentrations there is an efflux of cadmium from T. weissflogii so l…

Environmental Toxicology and EcotoxicologyGeochemistry and Elemental AnalysisDiatoms and Algae Research

In Situ X‐Ray Absorption Near‐Edge Structure Evidence for Quadrivalent Nickel in Nickel Battery Electrodes

William E. O’Grady、K. I. Pandya、Karen E. Swider 等 4 位作者1996-05-01Journal of The Electrochemical Society

The oxidation state of nickel in a nickel oxide battery has been examined using x‐ray absorption spectroscopy. Chemically synthesized β‐NiOOH and were used as reference standards for the Ni(III) and Ni(IV) oxidation states of nickel, respectively. The shift of the Ni K‐edge absorption in both a completely charged nick…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionTransition Metal Oxide Nanomaterials

Mechanistic Aspects of Intergranular Stress Corrosion Cracking of Ferritic Steels

R. N. Parkins1996-05-01CORROSION

Evidence of intergranular attack (IGA) in the absence of stress, together with dissolution kinetics, indicates that intergranular stress corrosion cracking (IGSCC) of ferritic steels in various environments is by a dissolution mechanism. Film rupture can play an important role in the rate of growth of cracks, but film…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

A microcellular processing study of poly(ethylene terephthalate) in the amorphous and semicrystalline states. Part II: Cell growth and process design

Daniel F. Baldwin、Chul B. Park、Nam P. Suh1996-05-01Polymer Engineering and Science

Abstract Microcellular semicrystalline polymers such as poly(ethylene terephthalate) show great promise for engineering applications because of their unique properties, particularly at higher densities. Recent studies have shown that some high density microcellular polymers have longer fatigue lives and/or equivalent…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Ferroic Phase Transitions in (Na 1/2 Bi 1/2 )TiO 3 Crystals

Seung‐Eek Park、Su‐Jin Chung、In‐Tae Kim1996-05-01Journal of the American Ceramic Society

The ferroic phase‐transition behavior of two (Na 1/2 Bi 1/2 )TiO 3 (NBT) crystals grown by flux and by the Czochralski method has been investigated in the present study. Although both the tetragonal and the rhombohedral phases of NBT are expected to be ferroelastic, these crystals exhibit different ferroelastic behavi…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Chain extension of polyesters PET and PBT with two new diimidodiepoxides. II

Demetris N. Bikiaris、George P. Karayannidis1996-05-01Journal of Polymer Science Part A Polymer Chemistry

Two new diglycidyl ester compounds containing preformed imide rings for better thermal stability were prepared to be used as chain extenders for PET and PBT. The preparation of these compounds was carried out in two steps. In the first step, diimidodiacids were prepared from pyromellitic anhydride and 3-aminopropanoic…

Fuel Cells and Related Materialsbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Characterization of Human Type III Collagen Expressed in a Baculovirus System

Arja Lamberg、Tarja Helaakoski、Johanna Myllyharju 等 7 位作者1996-05-01Journal of Biological Chemistry

An efficient expression system for recombinant collagens would have numerous scientific and practical applications. Nevertheless, most recombinant systems are not suitable for this purpose, as they do not have sufficient amounts of prolyl 4-hydroxylase activity. Pro-alpha 1 chains of human type III collagen expressed…

biodegradable polymer synthesis and propertiesEnzyme Production and CharacterizationCollagen: Extraction and Characterization

Computer simulation studies of anisotropic systems. XXVI. Monte Carlo investigations of a Gay–Berne discotic at constant pressure

Martin A. Bates、G. R. Luckhurst1996-05-01The Journal of Chemical Physics

The majority of molecules which form liquid crystals are elongated in shape. However, disk shaped molecules have also been shown to exhibit liquid crystalline phases. In this paper we report a series of constant pressure Monte Carlo simulations of model discotic molecules. We have used the Gay–Berne potential, which i…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Epitaxial growth of Co3O4 on CoO(100)

G. A. Carson、M. H. Nassir、M. A. Langell1996-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Under mildly oxidizing ultrahigh vacuum conditions, it is possible to form on top of CoO(100) single crystal substrates, thin films that have higher oxygen content but that preserve the overall symmetry of the CoO(100) low-energy electron diffraction pattern. X-ray photoelectron spectroscopy (XPS) and high-resolution…

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsCopper-based nanomaterials and applications

Preparation of transparent and conductive In2O3–ZnO films by radio frequency magnetron sputtering

Tadatsugu Minami、Toshikazu Kakumu、Shinzo Takata1996-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Highly transparent and conductive In2O3–ZnO films have been prepared by rf magnetron sputtering using targets composed of In2O3 and ZnO. Polycrystalline Zn2In2O5 films were deposited at a substrate temperature of 350 °C using targets with a Zn content [Zn/(Zn+In)] of about 10–60 at. %. A uniform spatial resistivity di…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Characterization of a-C:H:N deposition from CH4/N2 rf plasmas using optical emission spectroscopy

Kim Clay、S.P. Speakman、G.A.J. Amaratunga 等 4 位作者1996-05-01Journal of Applied Physics

Optical emission spectra (OES) from CH4/N2 rf plasmas, which are used for the deposition of nitrogen-containing hydrogenated amorphous carbon (a-C:H:N) thin films, have been characterized. Previously unidentified spectral lines have been assigned to atomic N. Further identified species include CH, H, H2, N2, N+2, N, a…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchThin-Film Transistor Technologies

Low-frequency vibrations in a model glass

H. R. Schober、C. Oligschleger1996-05-01Physical review. B, Condensed matter

Previous simulation studies of localized low-frequency vibrational modes in a soft sphere glass are extended to larger samples. We find a boson peak in the spectral density and a maximum in the specific heat divided by ${\mathit{T}}^{3}$ similar to experiment. These maxima are caused by (quasi)localized vibrations. Fo…

Material Dynamics and PropertiesGlass properties and applicationsRandom lasers and scattering media

Ultrafine Spinel Powders by Flame Spray Pyrolysis of a Magnesium Aluminum Double Alkoxide

Clint R. Bickmore、Kurt F. Waldner、David R. Treadwell 等 4 位作者1996-05-01Journal of the American Ceramic Society

Ultrafine crystalline spinel powder has been prepared using flame spray pyrolysis of alcoholic solutions of a novel double alkoxide precursor. The particles produced are spherical, dense, single crystals with diameters of 10–100 nm and specific surface areas ranging from 40 to 60 m 2 /g. Powder production rates of 50–…

Advanced ceramic materials synthesisCoagulation and Flocculation StudiesMagnesium Oxide Properties and Applications

Comparison of the diffusion barrier properties of chemical-vapor-deposited TaN and sputtered TaN between Cu and Si

Mei‐Hui Tsai、Shuo Sun、C.E. Tsai 等 5 位作者1996-05-01Journal of Applied Physics

This work investigated the barrier properties of metalorganic chemical-vapor-deposited (CVD) tantalum nitride (TaN) and physical-vapor-deposited (PVD) TaN between Cu and Si. The CVD TaN film had a preferred orientation (200) with a grain size of around 60 nm, while the PVD TaN had a (111) preferred orientation with a…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

A mesogen‐functionized carbosilane dendrimer: A dendritic liquid crystalline polymer

Klaus Lorenz、Dirk Hölter、Bernd Stühn 等 5 位作者1996-05-01Advanced Materials

The first dendritic liquid crystalline polymer (DLCP) , consisting of a flexible, second‐generation dendritic carbosilane scaffold substituted with 36 rid cyanobiphenyl groups (see Figure), has been prepared. The synthesis and characterization of the mesophase are reported as an initial approach to determining how the…

Liquid Crystal Research AdvancementsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Evidence for domain-type dynamics in the ergodic phase of thePbMg1/3Nb2/3O3relaxor ferroelectric

A. E. Glazounov、A. K. Tagantsev、Andrew J. Bell1996-05-01Physical review. B, Condensed matter

It was observed that the dielectric permittivity of ${\mathrm{PbMg}}_{1/3}$${\mathrm{Nb}}_{2/3}$${\mathrm{O}}_{3}$ (PMN) relaxor ceramics increases with increasing amplitude of the applied ac field. A strong nonlinearity occurs at temperatures where the frequency dispersion of the dielectric response is observed. A si…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Conductive polymer blends with low carbon black loading: Polypropylene/polyamide

R. Tchoudakov、O. Breuer、M. Narkis 等 4 位作者1996-05-01Polymer Engineering and Science

Abstract The electrical resistivity and morphology of polypropylene/nylon (PP/Ny) immiscible blends incorporated with carbon black (CB) were studied. CB was found to be preferentially located in the Ny phase or upon the Ny/PP interface. Blends with a co‐continuous phase morphology depicted especially low resistivity v…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesConducting polymers and applications