Materials Literature
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A series of new poly(1, 3, 4-oxadiazole-amide)s have been synthesized by solution polycondensation of aromatic diamines containing preformed 1, 3, 4-oxadiazole rings with phenoxyterephthalic diacid chloride or by the reaction of the same diacid chloride with p-aminobenzhydrazide resulting in a polyhydrazide-amide whic…
The energy level schemes of the neodymium oxyhalides (NdOX, X = F, Cl, and Br) were studied and simulated with a phenomenological model accounting simultaneously for both the free ion interactions and the crystal fleld effect. The former included the electrostatic and interconfigurational interactions as well as the s…
Abstract PVC foamed building products have seen good growth lately because of their favorable properties and economics. Continued good growth is seen for the future. Expanding application areas, especially in the U.S. market, have created a need for knowledge on formulation and processin prarameters. Application areas…
Abstract Various size fractions of several samples of glauconitic clay and illite were heated stepwise under vacuum for extended periods to: 1) evaluate radiogenic-argon (Ar) yields in relation to composition and size range; and 2) investigate the kinetics of radiogenic-Ar release. Each sample was heated at 250, 375,…
Three POY yarns of 80/100, 80/48, and 80/34 denier/filament are textured with four variables at five levels. The Box-Hunter statistical experimental design is used to produce thirty-six samples in each case. The effects of texturing variables—draw ratio, disc surface speed to yam speed ratio ( D/Y ratio), first heater…
Abstract Formation of Fe-coatings or segregation at the expense of quartz grains is a common process in the tropical environment. Limited information is available about their internal structure at the submicroscopic level. The transmission electron microscope (TEM) and energy dispersive X-ray microprobe analyses (EDXR…
Abstract A novel heterogeneous polymerization process for synthesizing particulate with a wide range of properties has been developed. This process, which is called semi ‐ suspension polymerization (SSP), consists of two steps. In the first step a mixture of monomer, polymer, initiator, and other required ingredients…
Abstract The diprotonated, bishydroperchlorate forms of three isomeric β‐octaalkyl‐substituted tetrapyrrolic macro‐cycles, namely, etioporphyrin II (1) , etio porphycene (2) , and etiocorrphycene (3) , have been characterized both in chloroform solution, by UV/visible spectroscopy and 1 H and proton‐correlated 2D 15 N…
Crack faces in solids are modelled as non-standard patterns whose standard parts are self-affine fractals. The morphological and mechanical features of brittle and ductile fracture are discussed. A concept of equivalent traction is employed to obtain the asymptotic stress fields near the crack tip, which in turn used…
The use of natural zirconolites to assess the effect of α-decay damage and geochemical alteration on the release of actinides from HLW wasteforms is critically examined. There is evidence that the natural zirconolites provide a good chemical and radi-ation damage analogy for the HLW wasteforms, but additional work is…
Abstract Ammonia present in the product gas from coal gasification may increase NO x emissions from IGCC systems. A fixed bed reactor was used to study the effect of calcined limestone (CaO) on NH 3 decomposition and reaction of NH 3 and NO. Reactions at temperatures to 900°C in helium and in gas compositions typical…
Abstract The K-Ar systematics of illite/smectite (I/S) mixed layers in deeply buried shales from the Gulf Coast, the North Sea and the Mahakam Delta basins have been compared to provide additional perspectives on the diagenetic evolution of these minerals. Comparison of the results suggests that illitization proceeds…
Isocitrate dehydrogenase from an extremely thermophilic bacterium, Thermus aquaticus YT1, was purified to homogeneity, and the gene was cloned by using a degenerate oligonucleotide probe based on the N-terminal sequence. The gene consisted of a single open reading frame of 1,278 bp preceded by a Shine-Dalgarno ribosom…
A liquid‐crystalline coordination compound immobilized on an oligomeric superstructure free from cross‐linking (see Figure) is reported for the first time. A highly versatile synthetic methodology is described that allows unsymmetrical, mono‐functionalized, metal‐containing liquid‐crystalline coordination complexes to…
Abstract Two partially‐stabilized zirconia materials, Mg‐PSZ and Y‐PSZ, were investigated in static and cyclic fatigue tests. The crack growth rates were determined as a function of the stress intensity factor (static tests) and the stress intensity factor range (cyclic tests). For all R ‐ratios investigated the crack…
Gagaminine, a steroidal alkaloid, was isolated for the first time from the root of Cynanchum wilfordi Hemsley (Asclepiadaceae), and its effects on lipid peroxidation and the activity of aldehyde oxidase (EC. 1.2.3.1) were investigated in vitro. This alkaloid suppressed significantly the formation of lipid peroxides in…
Abstract Diffusion coefficients have been measured for the two-shell cluster of Au55(Hdpbs) 12Cl6 (Hdpbs = diphenylphosphino-benzene-3-sulfonic acid) in water at varying ionic strengths. Hydrodynamic radius of the particles are found to be 1.44 nm as calculated from the diffusion coefficient at sufficiently high ionic…
Polarization and impedance measurements were carried out on an iron electrode in an anhydrous methanol solution of and containing organic corrosion inhibitors. They were alkylamines, N,N‐dimethylalkylamines, and alkanethiols with various carbon numbers. These inhibitors suppressed both cathodic and anodic processes of…
Abstract In this work, poly ether ketone ether ketone ketone (PEKEKK) was used as a thermoplastic adhesive for joining metals. Titanium and cobalt chromium alloys were joined to form tensile butt joints. These tensile specimens were used to evaluate bond performance. A controlled thermal processing cycle was used to m…
The preparation, structure, and properties of microcrystalline cellulose (MCC) from rice straw were investigated by IR, x-ray, viscometry, polarizing microscope, SEM, etc. The results are as follows: 1. The leveling-off degree of polymerization (LODP) obtained from rice straw is about 80–150. The dimensions of MCC gra…