Materials Literature
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Starting from the formally exact Liouville equation, we derive a generalized Langevin equation for the simultaneous correlated motion of several molecules in dense melts. Our calculations are based upon phase space kinetic theory and Mori–Zwanzig projection operator techniques. In the overdamped regime, a set of nonli…
Using the aqueous cores of reverse micelles as nanoreactors, nanoparticles (d∼10 nm) of the mixed ferrite MnFe2O4 were produced. Seven processing trials were performed where the concentration of ammonium hydroxide, reaction temperature, and the oxidizing agent were varied. All trials result in Mn-ferrite particles wit…
Several binary copolycarbonates were prepared by polycondensation of 2,5-bis(4-hydroxybenzylidene)cyclopentanone, BHBC, with methylhydroquinone, MHQ, hydroquinone 4-hydroxybenzoate, HQHB, or isosorbide. Furthermore, five ternary copolycarbonates were prepared based on the aforementioned monomers. All polycondensations…
Ultrafine Co0.9Mn0.1Fe2O4 particles are fabricated by a sol–gel method. Magnetic and structural properties of powders are investigated with x-ray diffraction, vibrating samples magnetometer, and Mössbauer spectroscopy. Co–Mn ferrite powders which were fired at and above 673 K have only a single phase spinel structure…
Single domain epitaxial (110) films of SrRuO3 exhibit uniaxial magnetic anisotropy instead of the biaxial anisotropy observed in the bulk material. The magnetic easy axis for the film is along the orthorhombic [010] direction below TC, and it rotates toward the [110] perpendicular direction as temperature decreases. T…
Maskless laser patterning of indium tin oxide thin films for flat panel display applications was studied as a function of wavelength using different harmonics of a diode-pumped Q-switched Nd:YLF laser. Electrically isolating lines could be written at all wavelengths used. However, while lines written at the infrared a…
The exact lattice-gas solution for thermodynamics functions, jump and chemical diffusion coefficients of linear adsorbates in a one-dimensional space is presented. Results are compared with corresponding ones from the Flory's approximation. Significant quantitative and qualitative discrepancies are shown and discussed…
Electronic structures of Cr-based chalcogenide spinels ${\mathrm{Fe}}_{1\ensuremath{-}x}{\mathrm{Cu}}_{x}{\mathrm{Cr}}_{2}{\mathrm{S}}_{4}(x=0.0,0.5,1.0)$ are investigated by using the linearized muffin-tin orbital (LMTO) band method in both the local-spin-density approximation (LSDA) and the $\mathrm{LSDA}+U.$ The LS…
The effects of strain relaxation on the crystallographic domain structure and on the magnetic and transport properties of epitaxial colossal magnetoresistive La0.8Ca0.2MnO3 (LCMO) thin films have been studied. LCMO films in the thickness range of 100–4000 Å were grown on (001) SrTiO3 and (001) LaAlO3 substrates, which…
Chiral nanostructured thin films can be produced through precise control of the angle of incidence of a vapor flux concurrent with substrate rotation. The technique has been employed to create unique porous iron thin film structures on Si(100) with a columnar microstructure. Scanning electron microscopy images illustr…
We have developed a simple method to measure the transport spin polarization of ferromagnetic materials. This technique relies on the fact that the Andreev reflection process at the interface between a superconductive and normal is influenced by the spin polarization P of the normal metal. In a very short time we have…
Crystallinity and melting behavior are directly affected by the presence of a noncrystallizable comonomer. Hydrogenated polybutadiene, HPB, emulates a random ethylene−butene copolymer and provides the basis for comparison to the equilibrium theory of Flory. Melting behavior, density (crystallinity), and SAXS long peri…
Ultrafast pulsed laser deposition is a novel technique for depositing particle-free, thin solid films using very high repetition rate lasers. The process involves evaporation of the target by low energy laser pulses focused to an optimum intensity to eliminate particles from the vapor. This results in films with very…
In this study we investigate the effects of Ce doping in R1−xAxMnO3 (R=La, Ce, and A=Sr, Ce) on the magnetic and transport properties of this system. For La1−xCexMnO3 (LCMO), an increase in Ce concentration is accompanied by an increase in TC from 225 to 236 K, as well as an increase in the electrical resistivity. An…
Recent studies show that the magnetic properties of epitaxial thin films of magnetite (Fe3O4) deviate strongly from bulk behavior: it is difficult to saturate thin films, ultrathin films may become super paramagnetic, their saturation magnetization drops to zero, and the local magnetic moments are oriented out of plan…
We report both experimental measurements and molecular simulations of the melting and freezing behavior of simple fluids in porous media. The experimental studies are for carbon tetrachloride and nitrobenzene in controlled pore glass (CPG) and Vycor. Differential scanning calorimetry (DSC) was used to determine the me…
The improvement in oxygen barrier properties of poly(ethylene terephthalate) (PET) by incorporation of an impermeable phase such as crystallinity or talc platelets was examined. Crystallinity was induced by crystallization from the glassy state (cold crystallization). Microlayering was used to create talc-filled struc…
Through a systematic investigation of the complete dielectric tensor, between 0.5 and 5.0 eV, of Fe3O4 and of related spinel ferrites, i.e., MgFe2O4, Li0.5Fe2.5O4, NiFe2O4, and CoFe2O4, we have established that intervalence charge transfer and intersublattice charge transfer transitions dominate the optical and magnet…
The electronic structure of yttrium aluminum garnet $({\mathrm{Y}}_{3}{\mathrm{Al}}_{5}{\mathrm{O}}_{12})$ is studied by means of first-principles local-density calculations. Results on band structure, density of states, partial density of states, effective charges, bond order, charge-density distributions, equilibriu…
A new class of nanocrystalline alloys with composition Fe44Co44Zr7B4Cu1 has been developed. This and similar alloys of general composition (Fe, Co)–M–B–Cu (where M=Zr, Hf, Nb, etc.) have been named HITPERM. They offer large magnetic inductions and excellent soft magnetic properties at elevated temperatures. Thermomagn…