Materials Literature
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Research Article| January 01, 2005 Heterosilicates with Tetrahedral-Octahedral Frameworks: Mineralogical and Crystal-Chemical Aspects Nikita V. Chukanov; Nikita V. Chukanov 1Institute of Problems of Chemical Physics, 142432 Chernogolovka, Moscow Region, Russia, chukanov@icp.ac.ru Search for other works by this author…
Heterometallic wheels can be templated about tertiary amines and imidazoles, leading to new octa-, nona- and deca-nuclear rings.
In preferential CO oxidation in H2-rich gas, K-Pt/Al2O3(K/Pt = 10) was very effective in decreasing CO concentration below 10 ppm in the 375-410 K range, and the turnover frequency of the K-Pt/Al2O3 was 20 times as high as that of Pt/Al2O3 at 353 K; furthermore, the activity of CO oxidation was promoted drastically by…
This review critically evaluates the factors affecting the process of slag splashing. Two mechanisms are involved in slag splashing, namely ‘slag wash coating’ and ‘slag ejection coating’. Our knowledge of slag splashing is largely based on physical modelling studies. It is necessary to optimise the following for good…
Based on first-principles electron structure calculations and employing the frozen-magnon approximation we study the exchange interactions in a series of transition-metal binary alloys crystallizing in the zinc-blende structure and calculate the Curie temperature within both the mean-field approximation (MFA) and rand…
In this paper, dispersive propagation and radiation properties of leaky waves on metamaterial grounded slabs are investigated. The proper or improper nature of leaky modes supported by such structures is shown to be related to the metamaterial being /spl epsi/-negative, /spl mu/-negative, or double-negative, and to fi…
The synthesis of nanomaterials with control over size, shape and chemical composition continues to be a major challenge in nanoscience. The requirements of nanomaterial synthesis are becoming more sophisticated and, in addition to anisotropic structures, there is much excitement surrounding the development of recipes…
Dendritic supramolecular assemblies were formed in water with Reichardt's dye or the anticancer drug 10-hydroxycamptothecin and the dendritic macromolecule, ([G4]-PGLSA-OH)2-PEG3400.
We reported an evidence for C-C bond cleavage by milder oxidizing agent H2O2 in a mesoporous CMK-5 type carbon at room temperature.
Fresnel integral is modeled with three equivalent functions. The first function is derived by considering the sum of the first term of the Fresnel integral's asymptotic expansion {F(x)} and an exponential function which approaches to infinity at the zero of the Fresnel function's argument and has the properties of a u…
ZnS nanoparticles with different morphology; spherical, ellipsoidal particles’ nanotubes and nanorods, could be successfully synthesized from quaternary W/O microemulsion system. The morphology of the final products could be clearly confirmed by the scanning electron microscopy (SEM) and the transmission electron micr…
The rhodium–BIPHEPHOS catalysed hydroformylation of trans-4-octene yields n-nonanal at high selectivity under mild reaction conditions. In this contribution a new method for an efficient product and catalyst separation in hydroformylation reactions is presented. By application of a temperature-dependent multi-componen…
Recently, the phase-field method is becoming a powerful tool to simulate and predict complex microstructure evolutions in interdisciplinary fields of materials science. In this study, the phase-field simulations are demonstrated on the phase decomposition in the α (bcc) phase during isothermal aging in Fe–Cu–Mn–Ni qua…
ZrOCl2·8H2O is an efficient catalyst for the esterification of long chain carboxylic acids with long chain primary and secondary alcohols. Supporting ZrOCl2·8H2O on ordered mesoporous silica enhances the catalytic activity of the esterification. The esters of C10–C18 normal acid and alcohol are obtained in high yield…
A simple, low-temperature strategy has been developed for the low-cost and large-area fabrication of ZnO nanoarrays on a zinc substrate by the natural oxidation of zinc metal in formamide/water mixtures. The one-step, wet-chemical approach has exhibited well-controlled growth of highly oriented and densely packed ZnO…
Abstract The photodynamic activities of a porphyrin-C60 dyad (P-C60) and its metal complex with Zn(II) (ZnP-C60) were compared with 5-(4-acetamidophenyl)-10,15,20-tris(4-methoxyphenyl)porphyrin (P), both in homogeneous medium-bearing photooxidizable substrates and in vitro on the Hep-2-human-larynx–carcinoma cell line…
Enlargement of the pi-electronic network of meso-meso, beta-beta, beta-beta triply linked diporphyrin has been exploited by preparing a corresponding dibenzo-fused porphyrin dimer that exhibits a perturbed absorption spectrum and a large two-photon absorption cross section.
Microorganisms frequently contaminate jet fuel and cause corrosion of fuel tank metals. In the past, jet fuel contaminants included a diverse group of bacteria and fungi. The most common contaminant was the fungus Hormoconis resinae. However, the jet fuel community has been altered by changes in the composition of the…
The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2](10-) by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates.
Clusters which display the rare cubic Fe8 topology have been obtained by reaction of the metastable hexavacant polyoxotungstate [H2P2W12O48]12- with basic trinuclear metal acetates.