Materials Literature
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A strong reducing power in the excited state is just one of the features of the tetranuclear copper(I) complex 1. It contains an acetylide dianion bridging four copper atoms in both η1 and η2 bonding modes and exhibits long-lived luminescence. The central framework of the structure is shown on the right.
The kinetics of phase separation in thin polymer blend films of polystyrene and polybutadiene on a silicon substrate is examined by optical microscopy of the free film boundary. Our observations on 1000 and 200 \AA{} films are consistent with a crossover from three- to two-dimensional spinodal decomposition kinetics i…
As deduced from Nature, the principle of symmetry-driven self-assembly, based on incommensurate coordination numbers, is employed to design clusters using metal coordination as the driving force. The ten-component cluster on the right demonstrates the predicted cooperativity in cluster formation.
The kinetics of solid-solid phase transitions are explored using pressure-induced structural transformations in Si nanocrystals. In agreement with the predictions of homogeneous deformation theories, large elevations in phase transition pressure are observed in nanocrystals as compared to bulk Si, and high pressure x-…
Abstract Zwar steht der Entwicklung von nanometergroßen Strukturen prinzipiell nichts im Wege, doch setzt sich immer mehr die Auffassung durch, daß sich Strukturminiaturisierungen unter die gegenwärtig durch lithographische Techniken erreichbare 1‐μ‐Grenze als nicht mehr praktikabel erweisen werden. Es wurde daher deu…
The hydrolysis of tri-sec-butoxyaluminum in the presence of nonionic surfactants leads to mesoporous alumina molecular sieves with wormlike arrays of channels with uniform diameters in the range 2.4 – 4.7 nm, depending on the nature of the surfactant. Molecular sieves of this type are of interest as possible catalysts…
The transport properties of electrons and holes in poly(dialkoxy-p-phenylene vinylene) (PPV) are investigated by current–voltage measurements using Ca as an electron and indium-tin-oxide as a hole injecting contact. Both the electron and hole currents are dominated by the bulk conduction properties of the PPV, in cont…
Spun cast alloy HP50–Nb tubing retired from service in a steam reformer after approximately 8 years of service had stress rupture properties suggesting very short remaining life. Microstructural examination, however, indicated little or no creep damage (cavitation) but did reveal extensive microstructural modification…
An in situ method of monitoring the electron cyclotron resonance etching of III-V semiconductor heterostructures is discussed for in-plane lasers. Surface reflected and Fabry-Perot interference signals determine the etch depth, rate and surface quality. The etching accuracy is better than 500 /spl Aring/. The etch mon…
We have studied ion-beam-induced epitaxial crystallization and densification of sol-gel zirconia thin films on single-crystal yttria-stabilized zirconia (YSZ) substrates. The spin-coated sol-gel zirconia thin films (100 nm) on YSZ substrates were irradiated at 300 C with various ion beams (360 keV argon, 360 keV neon…
Abstract The spectral, polarization, and kinetic characteristics of luminescence are studied for In + and In 2+ ions associated with interstitials and vacancies in an X‐irradiated KCl: In crystal. It is shown that the 2.08 eV emission is caused by the electronic transitions from the tetragonal minima of the triplet re…
Abstract Molecules of the amphiphilic polyalcohol [9]‐10‐[9] arborol (molar mass M = 1053 g mol −1 ) dissolved in water form gels which are thermo‐reversible and shear sensitive. The gel formation sets in above a characteristic composition y gel of the solution and temperature T gel ( y gel = 7.5·10 −3 ; T gel ≈35°C;…
The results are presented of an investigation of radioluminescence and phosphorescence spectra, decay of phosphorescence at a constant temperature, and thermostimulated luminescence of transparent BeO:Li ceramics. The phosphorescence decay dependence on time suggests the appearance of tunnelling.
Abstract A linear relationship exists in oxide glasses between glass transition temperature (T g ) and quadrupole splitting (Δ) of Fe 3+ . DTA and Mössbauer measurements of silicate and tungstate glasses yielded large slopes of 680 and 260 °C/(mm s -1 ) from the slope of the straight lines when Fe 3+ occupied, as netw…
This paper deals with the spherically symmetric Stefan problem in three space dimensions. The melting temperature satisfies the Gibbs–Thomson law. The solution is obtained as a limit of solutions of similar problems containing a small additional kinetic term in the melting temperature. Under some structural assumption…
Elastomer–elastomer joints are a special case of polymer bonding. Interfacial adsorption, molecular interdiffusion, and entanglements, as well as chemical bonding, are the different mechanisms which intervene in adhesion phenomena. Their relative contribution is not well known and depends on many parameters. If the fo…
A noise analysis for a planned PIN diode X-ray detector array using CMOS technology explores the affect of allowed device dimensions on attainable energy resolution using a methodology which allows low frequency, process dependent 1/f and 1/f/sup 2/ terms to be explicitly evaluated for arbitrary noise filters. We find…
The authors intend the book to be an introduction to the field of radiation protection dosimetry. Having just been published last year, the book is able to take into account all the changes and developments that have come in recent ICRP and ICRU reports. The book is aimed at graduate students or as a reference work fo…
We report an experimental study on the pattern dynamics of the salt-crystal (NaCl) surface when dissolved from below by its own aqueous solutions with mass concentrations between 0.0% and 24.0%. The surface pattern roughness grew exponentially for a range of unstable wave numbers with a fastest growing wave number ${k…
We have made extensive studies of the charge-carrier mobilities in the discotic hexagonal mesophases of triphenylene-based discotic liquid crystals. Using the time-of-flight technique, transient photocurrents were measured yielding charge-carrier mobilities for various electric fields and temperatures. Starting from p…