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Removal of citric acid from aqueous solution by catalytic wet peroxidation using effective mesoporous Fe‐MCM‐41 molecular sieves

Narasimhan Gokulakrishnan、A. Pandurangan、Pradeep K. Sinha2006-12-15Journal of Chemical Technology & Biotechnology

Abstract The presence of citric acid in decontamination waste can cause complexation of radioactive cations, resulting in interferences in their removal by various treatment processes such as chemical precipitation and ion exchange, and may pose a potential danger to the environment. Mesoporous Fe‐MCM‐41 molecular sie…

Mesoporous Materials and CatalysisIron oxide chemistry and applicationsNanomaterials for catalytic reactions

Reversible paramagnetism to ferromagnetism in transition metal-doped TiO2 nanocrystals prepared by microwave irradiation

Garry Glaspell、Asit Baran Panda、M. Samy El‐Shall2006-12-15Journal of Applied Physics

Ti O 2 nanoparticles doped with 1%, 5%, and 10% M (M=Co, Fe, and Ni) were prepared by microwave irradiation and characterized using x-ray diffraction, transmission electron microscopy, and magnetometry. The as-prepared samples are found to be paramagnetic at room temperature, with the magnetic susceptibility following…

ZnO doping and propertiesMagnetic Properties and Synthesis of FerritesCopper-based nanomaterials and applications

Metal organic vapor phase epitaxy of BiSbTe3 films on (001) GaAs vicinal substrates

Jeong Hun Kim、Dae‐Yong Jeong、Jin-Sang Kim 等 4 位作者2006-12-15Journal of Applied Physics

We have investigated the growth of BiSbTe3 films by metal organic vapor phase epitaxy on (001) GaAs vicinal substrates. A detailed experimental study of the surface morphologies of BiSbTe3 films grown on GaAs (001) vicinal surfaces was carried out and is discussed in this paper with a view to understanding the step-st…

Semiconductor Quantum Structures and DevicesAdvanced Thermoelectric Materials and DevicesAdvanced Semiconductor Detectors and Materials

Analisa Ketangguhan dan Struktur Mikro pada Daerah Las dan HAZ Hasil Pengelasan Sumerged Arc Welding pada Baja SM 490

Anang Setiawan、Yusa Asra Yuli Wardana2006-12-15Jurnal Teknik Mesin Universitas Kristen Petra

Submerged Arc Welding (SAW) is one of method for welding process which used for the extensions of heavy construction, for example bridge construction. Broadness usage of SAW caused by welding process can be done automatically and have high reliability. Microstructure and toughness properties of weld metal were influen…

Welding Techniques and Residual StressesMaterial Selection and PropertiesRailway Systems and Materials Science

An Integrated Method for Product Material Selection Considering Environmental Factors and a Case Study

Hua Jun Cao、Fei Liu、Cong Bo Li 等 4 位作者2006-12-15Materials science forum

Materials have very important influence on the environmental impact of the product life cycle from production to disposal and recycling. The environmental factors should be considered when product materials are selected, in order to improve the environmental friendliness of products. Due to the complexity of product m…

Sustainable Supply Chain ManagementMaterial Selection and PropertiesQuality Function Deployment in Product Design

Nonlinear fitness–space–structure adaptation and principal component analysis in genetic algorithms: an application to x-ray reflectivity analysis

Jouni Tiilikainen、Juha-Matti Tilli、Vesa Bosund 等 7 位作者2006-12-15Journal of Physics D Applied Physics

Nonlinear fitness–space–structure adaptation and principal component analysis in genetic algorithms: an application to x-ray reflectivity analysis, Tiilikainen, J, Tilli, J-M, Bosund, V, Mattila, M, Hakkarainen, T, Airaksinen, V-M, Lipsanen, H

Magnetic Properties and Applications

Elastomeric Properties of Polysiloxane Networks. Bimodal Elastomers that are Spatially Inhomogeneous and Others that are Very Broadly Multimodal

Brent D. Viers、James E. Mark2006-12-15Journal of Macromolecular Science Part A

End‐linking poly(dimethylsiloxane) was used to prepare bimodal elastomers networks so as to have inhomogeneous nanostructures, and also to prepare others having very broadly multimodal chain‐length distributions. Macroscopic phase separation, probably high crosslink density clusters, was observed to occur in some of t…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Evaluation of the OH− influence on visible and near-infrared quantum efficiencies of Tm3+ and Yb3+ codoped sodium aluminophoshate glasses

Idelma A. A. Terra、Andréa Simone Stucchi de Camargo、L.A.O. Nunes 等 5 位作者2006-12-15Journal of Applied Physics

This paper presents a throughout spectroscopic investigation of Yb3+∕Tm3+ codoped sodium aluminophosphate glasses in the visible and near-infrared spectral regions. Two sets of samples, prepared in air and nitrogen atmospheres, were characterized by transmission, absorption, luminescence, excited state lifetimes, and…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Dynamics of the magnetization of single domain particles having triaxial anisotropy subjected to a uniform dc magnetic field

Bachir Ouari、Yuri P. Kalmykov2006-12-15Journal of Applied Physics

Thermally induced relaxation of the magnetization of single domain ferromagnetic particles with triaxial (orthorhombic) anisotropy in the presence of a uniform external magnetic field H0 is considered in the context of Brown’s continuous diffusion model. Simple analytic equations, which allow one to describe qualitati…

Magnetic properties of thin filmsTheoretical and Computational PhysicsMagnetic Properties and Applications

Additional dc magnetic field response of magnetostrictive/piezoelectric magnetoelectric Laminates by Lorentz force effect

Yanmin Jia、Yanxue Tang、Xiangyong Zhao 等 6 位作者2006-12-15Journal of Applied Physics

We have discovered that traditional long-type magnetoelectric laminate composite of magnetostrictive Tb1−xDyxFe2−y and piezoelectric materials possesses additional ability of detecting dc magnetic field, using the product effect of the Lorentz force effect from Terfenol-D metal strips in dc magnetic field applied with…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Influence of Direct Current Field on Powder-Pack Boriding

Fei Xie、Qiu Zhu、Jinjun Lü2006-12-15Diffusion and defect data, solid state data. Part B, Solid state phenomena/Solid state phenomena

The influence of direct current field (DCF) on powder-pack boriding has been investigated by applying DCF between boriding agent and specimen during the soaking. Experimental results show that DCF has the function of heating the agent and the specimen and thus enhancing boriding. It is shown that the specimen’s side f…

Diamond and Carbon-based Materials ResearchAdvanced materials and compositesMetal Alloys Wear and Properties

Free-base tripyrrins

Martin Bröring、S. Prikhodovski、E.C. Tejero2006-12-15Chemical Communications

The hitherto unavailable free-base tripyrrins HTrpy have been prepared by cyanide promoted demetallation of a nickel(ii) tripyrrin and by acid-induced condensation of a diformylpyrrole and an alkylpyrrole with a sterically shielded alpha-position.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Highly anisotropic conductivity in organosiloxane liquid crystals

Damian J. Gardiner、H. J. Coles2006-12-15Journal of Applied Physics

In this paper, we present the conductivity and dielectric characterization of three homologous series of smectic A siloxane containing liquid crystals. The materials studied include one monomesogenic series, which consists of a 4-(ω-alkyloxy)-4′-cyanobiphenyl unit terminated by pentamethyldisiloxane, and two bimesogen…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPhotochromic and Fluorescence Chemistry

Micromagnetic investigation on the coercivity mechanism of the SmCo5∕Sm2Co17 high-temperature magnets

Chuan‐bing Rong、Hongwei Zhang、Renjie Chen 等 5 位作者2006-12-15Journal of Applied Physics

The coercivity mechanism of the precipitation-hardened Sm(Co,Fe,Cu,Zr)z magnets at different temperature have been investigated by micromagnetic calculations. It was found that the coercivity mechanism varies with the temperature. The magnetization reversal is mainly controlled by domain-wall pinning when the temperat…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Effect of oxygen on characteristics of nickel oxide∕indium tin oxide heterojunction diodes

Hung-Lu Chang、Tien‐Chang Lu、Hao‐Chung Kuo 等 4 位作者2006-12-15Journal of Applied Physics

p -nickel oxide (NiOx)∕n-indium tin oxide heterostructure p-n junction diodes were fabricated on glass substrates and showed rectifying characteristics or negative differential resistance (NDR) characteristics depending on the content of oxygen in the NiOx films. After annealing the heterojunction diodes at 450°C in a…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Active Site Structure of NO Decomposition on Perovskite(-like) Oxides: An Investigation from Experiment and Density Functional Theory

Junjiang Zhu、Xiangguang Yang、Xuelian Xu 等 4 位作者2006-12-15The Journal of Physical Chemistry C

Active site structure for NO decomposition carried out on perovskite-like oxides were discussed based on the N 2 yield measured from LaSrNi 1- x Al x O 4 with different B-site cations and from La 2- y Sr y CuO 4 with different crystal phases. Results show that the active site contains two oxygen vacancies, two transit…

Catalytic Processes in Materials ScienceMagnetic and transport properties of perovskites and related materialsIndustrial Gas Emission Control

Dynamics of photosensitized formation of singlet oxygen by porous silicon in aqueous solution

Minoru Fujii、Naoki Nishimura、Hirokazu Fumon 等 7 位作者2006-12-15Journal of Applied Physics

Generation of singlet oxygen due to energy transfer from photoexcited silicon nanocrystals in D2O is demonstrated. It is shown that the singlet oxygen generation efficiency, i.e., the intensity of near-infrared emission from singlet oxygen gradually decreases when Si nanocrystals are continuously irradiated in O2-satu…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsGa2O3 and related materials

Heterogeneous dynamics, ageing, and rejuvenating in van der Waals liquids

Samy Mérabia、Didier Long2006-12-15The Journal of Chemical Physics

It has been shown over the past ten years that the dynamics close to the glass transition is strongly heterogeneous: fast domains coexist with domains three or four decades slower, the size of these regions being about 3 nm at T(g). The authors extend here a model that has been proposed recently for the glass transiti…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesAdvanced Thermodynamics and Statistical Mechanics

A one-pot synthesis of a paramagnetic high-nuclearity nickel( ii ) cluster: an octadecanuclear Ni II 16 Na I 2 metal aggregate

Biplab Biswas、Sumit Khanra、Thomas Weyhermüller 等 4 位作者2006-12-15Chemical Communications

An unusual Ni(II)(16)Na(I)(2) cluster which features formate as a bridging clamp between two octanuclear nickel cages is reported; preliminary magnetic studies exhibit paramagnetic low-lying states resulting from dominating antiferromagnetic interactions between the nickel(II) centers.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetalloenzymes and iron-sulfur proteins

Structural metrics of high-temperature lattice conductivity

Baoling Huang、Massoud Kaviany2006-12-15Journal of Applied Physics

An atomic structure-based model for high-temperature lattice conductivity is developed for both compact crystals and cage-bridge crystals. For compact crystals, where long-range acoustic phonons dominate, the Debye temperature TD and Grüneisen parameter γ are estimated using interatomic potentials to arrive at the lat…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity