Materials Literature
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Abstract 35 Cl Nuclear Quadrupole Resonance (NQR) has provided a valuable tool for investigating the local structure in mixed crystals K 2 S 1-x Re x Cl 6 and Al 3+ doped crystals K 2 SnCl 6 :Al 3+ . The measured NQR line shapes and relaxation times of both kinds of impurity containing crystals in the cubic phase of t…
A blue electroluminescence (EL) device was fabricated using SrSO 4 :Ce-based phosphor layers deposited by rf sputtering in Ar–H 2 S atmosphere. Peak emission wavelength was observed at 420 nm corresponding to the energy transition from the T 2g (5d) level to the F 5/2 (4f) level of Ce ions. This wavelength is shorter…
Diffraction characteristics of periodic binary diffractive structures are studied using three different theoretical approaches. Namely rigorous coupled-wave analysis (RCWA), Kogelnik's two-wave method, and the scalar method of transmittance have been applied to study diffraction characteristics and have been compared,…
Abstract The successive phase transitions of [Mg(H 2 O) 6 ][SiF 6 ] were studied by measuring 2 H NMR spectra. The quadrupole coupling constant e 2 Q q /h and asymmetry parameter η changed drastically at each transition temperature. 1,2 H and 19 F NMR T l were measured for this compound to study the relation between t…
The surface properties of TiO2 anatase are of great importance in chemical technology because this material is frequently used as a support for oxide catalysts. In the framework of an extensive study of the system V2O5/TiO2 anatase, the vibrational properties of single crystal anatase (001) and (100) have been examine…
The effect of the substituents, solvent polarities and hydrogen ion concentration on the electronic structure and UV/VIS absorption spectra of some Schiff bases, derivatives of N-(R-benzylidene)benzidine (R = o-NO2 and o-OH, p-OH) and N-(R-furfurylidene)benzidine (R = H and 5 - NO2), have been studied. The spectral sh…
Results of an in-situ extended X-ray absorption fine-structure study of photostructural changes in films of amorphous selenium are reported. It is shown that at first the average coordination number decreases by about 10%. As time elapses, the initial coordination number is restored. This change is attributed to break…
Summary John Frederic Daniell (1790–1845) invented the constant battery in 1836. He meant it to be a philosophical instrument to be utilized in both lecture demonstrations and electrochemical laboratory research. But the constant battery was taken up in electrometallurgy, not primarily as a source of electric current…
The plasma-driven permeation behavior of deuterium through nickel membrane was examined in the temperature range from room temperature to 723 K. The modification of its surface impurities by exposing it to the hydrogen plasma was examined with Auger electron spectroscopy. The influence of surface impurities on the pen…
The extended Taylor assumption of uniform deformation gradient among grains was applied in 3-D polycrystal plasticity simulations for complex loading paths at finite strain for OFHC Cu using the Los Alamos polycrystal plasticity (LApp) code (Kocks et al., 1994). Comparisons of both stress-strain behavior and texture e…
The instantaneous-normal-mode (INM) densities of states (DOS) of Na in the supercooled-liquid and glassy states under constant pressure have been calculated via molecular-dynamics simulation, with a rapid quenching rate for the glassy states. In the glassy states, at frequencies less than ${\ensuremath{\omega}}_{m},$…
Abstract The dependence of the dynamic behaviour of the smectic C* layer reorientation on application of asymmetric electric fields is investigated for different surface treatment of the glass substrates, varying the alignment layer materials and rubbing conditions. It is found that already weak monostable anchoring l…
We present experiments on nanocrystalline materials where thermal activation gives rise to dynamic effects on hysteresis curves. A scheme of interpretation is presented and the typical activation volume is found to be about 100 nm.
We reconsider the problem of electronic transport across a heterojunction interface connecting two materials with different effective masses. Thermionic current does not remain invariant when the position X/sub int/ of the interface is shifted relative to that of the potential energy maximum, X/sub max/, even if the s…
The specific heat of the ceramic and the permittivity of a single-crystal sample of LaBSiO 5 , a new ferroelectric in the stilwellite family, were measured in a temperature range which includes the phase transition point ( T C =140 °C). The excess entropy of the phase transition Δ S =1.05 J/mol · K and the Curie-Weiss…
Sorption and permeation of allyl isothiocyanate vapor (AIT, an antimicrobial flavor compound from Cruciferae plants) in nylon 6,6 film were investigated in this study. AIT sorption by the dry nylon film was low (=0.5%, w/w), but increased to a maximum =3.5% as relative humidity (RH) increased. Above 70% RH, the decrea…
A C-centred monoclinic phase (M) with aM = 3.31 nm, bM= 1.23 nm, cM =2.48 nm and β = 112° has been found in both Al66Co9Cu6W19 and Al12 FeCr alloys. It is shown by both electron diffraction and high-resolution electron microscopy (HREM) that this monoclinic phase is an ordered superstructure of the body-centred orthor…
This paper concerns a magnetic sensor using a vicalloy wire with uniaxial anisotropy and torsion stress. In the magnetic sensor using a compound magnetic wire, the relationship between wire length, magnetization state and the output voltage based on the large Barkhausen jump was investigated. When the specimen wire wa…
MgO has important potential uses as a buffer layer for growth of perovskite and related oxides on GaAs. Equilibrium thermochemical data indicate MgO will be stable against interfacial reaction with GaAs but, under molecular beam epitaxy growth conditions, kinetic limitations can increase the probability of an undesire…
Abstract Iron-containing carbons were prepared from mixtures of ferrocene and poly(furfuryl alcohol) by varying their preparation conditions. The electrocatalytic activity of the carbons was assessed with Fe(CN)63−/Fe(CN)64− redox reaction, and was revealed to be strongly affected by the fraction of a turbostratic car…