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Synthesis and characterization of C60/polyaniline composites from interfacial polymerization

Qiguan Wang、Sumin Wang、Jianping Li 等 4 位作者2012-08-10Journal of Polymer Science Part B Polymer Physics

Abstract C 60 /polyaniline (PANI) nanocomposites have been synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of C 60 by using an interfacial reaction. When compared with the pure PANI nanofibers from the similar process, the diameter of the obtained C 60 /PANI nanofib…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Electronic and Magnetic Properties of Graphene/Fluorographene Superlattices

Hongliang Shi、Hui Pan、Yong‐Wei Zhang 等 4 位作者2012-08-10The Journal of Physical Chemistry C

On the basis of density functional theory calculations, the electronic and magnetic properties of graphene/fluorographene superlattices (GFSLs) are systematically investigated. Our calculations show that the electronic properties are both interface-orientation- and graphene-width-dependent. All armchair GFSLs (AGFSLs)…

Advancements in Battery MaterialsGraphene research and applications2D Materials and Applications

Release Studies of Thymol and p-Cymene from Polylactide Microcapsules

Isabel M. Martins、Sofia N. Rodrigues、Maria Filomena Barreiro 等 4 位作者2012-08-10Industrial & Engineering Chemistry Research

The objective of this work is to access the release behavior of thymol and p -cymene used as model core materials with PLA microcapsules. The microcapsules were obtained by a coacervation process developed in a previous work and present a spherical shape with mean particle size of 25 and 37 μm for thymol and p -cymene…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Foaming and Composites

Squared form factors of valence-shell excitations of atomic argon studied by high-resolution inelastic x-ray scattering

Xu Kang、Ke Yang、X. Liu 等 8 位作者2012-08-10Physical Review A

State-resolved squared form factors of the electric monopolar excitations to $3{p}^{5}4p{[1/2]}_{0}$ and $3{p}^{5}4{p}^{\ensuremath{'}}{[1/2]}_{0}$, the electric dipolar excitations to $3{p}^{5}4s{[3/2]}_{1}$ and $3{p}^{5}4{s}^{\ensuremath{'}}{[1/2]}_{1}$, and the electric quadrupolar excitations to $3{p}^{5}4p{[5/2]}…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Historical Experience Providing Bases for Predicting Corrosion and Stress Corrosion in Emerging Supercritical Water Nuclear Technology: Part 1—Review

Xiangkun Ru、R. W. Staehle2012-08-10CORROSION

This review assesses past experiences from superheated fossil plants, supercritical fossil plants, superheated nuclear plants, and light water reactors from the late 1940s until the present. Data from the development and operation of these plants are directly applicable to supercritical water reactor (SCWR) plants bei…

Nuclear Materials and PropertiesNuclear Engineering Thermal-HydraulicsHeat transfer and supercritical fluids

Specific-heat discontinuityΔCvs.Tcin annealed Ba(Fe1−xCox)2As2

J. S. Kim、Brendan D. Faeth、G. R. Stewart2012-08-10Physical Review B

The low-temperature specific heat of annealed single-crystal samples of Ba(Fe${}_{1\ensuremath{-}x}$Co${}_{x}$)${}_{2}$As${}_{2}$ with compositions spanning the entire superconducting phase diagram was measured. Effort was made to discover the best annealing schedule to maximize ${T}_{c}$ and minimize transition width…

Rare-earth and actinide compoundsCorporate Taxation and AvoidanceIron-based superconductors research

High color rendering index white LED based on nano-YAG:Ce3+phosphor hybrid with CdSe/CdS/ZnS core/shell/shell quantum dots

Changyu Shen、Jinlei Chu、Feng Qian 等 7 位作者2012-08-10Journal of Modern Optics

To improve the poor color rendering index (CRI) of YAG:Ce-based white light-emitting diode (LED) due to the lack of red spectral component, core/shell/shell CdSe/CdS/ZnS quantum dots (QDs) were synthesized and blended into nano-YAG:Ce3+ phosphors. Prominent spectral evolution has been achieved by increasing the conten…

Luminescence Properties of Advanced MaterialsQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Micropatterning of Polymer Brushes: Grafting from Dewetting Polymer Films for Biological Applications

Andrew M. Telford、Laurence Meagher、Veronica Glattauer 等 6 位作者2012-08-10Biomacromolecules

In this novel platform, a micropatterned polymer brush was obtained by grafting poly(poly(ethylene glycol) methyl ether methacrylate) (poly(PEGMA)) from a thin macroinitiator film using atom transfer radical polymerization (ATRP). A pattern of holes was formed in the macroinitiator film by taking advantage of its spon…

Polymer Surface Interaction StudiesAdhesion, Friction, and Surface InteractionsNanofabrication and Lithography Techniques

Light-Controlled Resistance Modulation in a Photochromic Diarylethene–Carbon Nanotube Blend

Calogero Sciascia、Rossella Castagna、Maria Dekermenjian 等 10 位作者2012-08-10The Journal of Physical Chemistry C

Photochromic molecules are part of a large class of materials in which light stimulus not only induces a color variation but also affects other physicochemical properties. However, the change of bulk electrical properties (e.g., electrical conductivity) via light excitation remains difficult to control because the int…

Conducting polymers and applicationsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Near-ultraviolet zinc oxide nanowire sensor using low temperature hydrothermal growth

Michael Swanwick、Sieglinde M-L Pfaendler、Akintude I Akinwande 等 4 位作者2012-08-10Nanotechnology

Two near-ultraviolet (UV) sensors based on solution-grown zinc oxide (ZnO) nanowires (NWs) which are only sensitive to photo-excitation at or below 400 nm wavelength have been fabricated and characterized. Both devices keep all processing steps, including nanowire growth, under 100 °C for compatibility with a wide var…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Water-repellentall-cellulose nanocomposite using silane coupling treatment

Hossein Yousefi、Takashi Nishino、Alireza Shakeri 等 6 位作者2012-08-10Journal of Adhesion Science and Technology

Water-repellent all-cellulose nanocomposite (ACNC) was made using the silane coupling agent dodecyltriethoxysilane. The ACNC, consisting of cellulose nanofibers incorporated into a cellulosic matrix, was prepared by reducing crystallinity in the surface of the cellulose nanofibers using DMAc/LiCl solvent, followed by…

Surface Modification and SuperhydrophobicityNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

ACETIC ACID ENHANCED PURIFICATION OF CRUDE CELLULOSE FROM SUGARCANE BAGASSE: STRUCTURAL AND MORPHOLOGICAL CHARACTERIZATION

Jing Bian、Feng Peng、Xiaopeng Peng 等 6 位作者2012-08-10BioResources

Crude cellulose prepared from alkali-extracted sugarcane bagasse was subjected to a rapid purification treatment with a mixture of 80% acetic acid-68% nitric acid (10/1, v/v) at 120 C for 15 min. The yields of the preparations decreased slightly from 57.3%-58.6% in the crude cellulose preparations to 50.3%-51.9% in th…

Biofuel production and bioconversionAdvanced Cellulose Research Studies

Raman Spectroscopy as a Tool to Address Individual Graphene Layers in Few-Layer Graphene

Martin Kalbáč、Jing Kong、M. S. Dresselhaus2012-08-10The Journal of Physical Chemistry C

We developed a new general approach to address individual graphene sheets in few-layer graphene by Raman spectroscopy. Our method is based on isotope labeling of individual layers during their synthesis and subsequent transfer to form multilayered graphene. The power of the procedure is demonstrated in the analysis of…

Advancements in Battery MaterialsGraphene research and applicationsAdvanced Memory and Neural Computing

Effect of surface treatment of ramie fiber on the interfacial adhesion of ramie/acetylated epoxidized soybean oil (AESO) green composite

Tae Sang Lee、Hae Young Choi、Han Na Choi 等 7 位作者2012-08-10Journal of Adhesion Science and Technology

Recently, many researchers have attempted to convert soybean oil into useful polymers. One of the ways to make soybean oil into a matrix of green composites is to modify its triglyceride structure to obtain the acrylated epoxidized soybean oil (AESO) through epoxidization and acrylation. In this study, the effects of…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Solution-processable organic dielectrics for graphene electronics

Cecilia Mattevi、Florian Colléaux、HoKwon Kim 等 7 位作者2012-08-10Nanotechnology

We report the fabrication, at low-temperature, of solution processed graphene transistors based on carefully engineered graphene/organic dielectric interfaces. Graphene transistors based on these interfaces show improved performance and reliability when compared with traditional SiO(2) based devices. The dielectric ma…

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Intercalation of Amino Acids into Eu3+‐Doped Layered Gadolinium Hydroxide and Quenching of Eu3+ Luminescence

Qingyang Gu、Yahong Sun、Nankai Chu 等 6 位作者2012-08-10European Journal of Inorganic Chemistry

Abstract The NO 3 – ‐type Eu 3+ ‐doped layered gadolinium hydroxide (NO 3 –LGdH:Eu) was prepared by a developed homogeneous precipitation method through hexamethylenetetramine (HMT) hydrolysis with hydrothermal treatment. Two amino acid anions, phenylalanine (Phe) and tyrosine (Tyr), were intercalated into LGdH:Eu to…

Luminescence Properties of Advanced MaterialsLayered Double Hydroxides Synthesis and Applications

Separated Coil and Chain Aggregation Behaviors on the Miscibility and Helical Peptide Secondary Structure of Poly(tyrosine) with Poly(4-vinylpyridine)

Yi‐Syuan Lu、Yung‐Chih Lin、Shiao‐Wei Kuo2012-08-10Macromolecules

In this study, we synthesized a low-molecular-weight polytyrosine (PTyr) through living ring-opening polymerization of the α-amino acid- N -carboxyanhydride and then blended it with poly(4-vinylpyridine) (P4VP) homopolymer in N, N -dimethylformamide (DMF) and MeOH solutions, thereby controlling the miscibility behavio…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

A Novel Method to Mitigate the Top-of-the-Line Corrosion in Wet Gas Pipelines by Corrosion Inhibitor within a Foam Matrix

Ivana Jevremović、Marc Singer、M. Achour 等 7 位作者2012-08-10CORROSION

Top-of-the-line corrosion (TLC) has been a serious issue for the oil and gas industry. Conventional inhibition techniques are expensive and often do not seem to provide enough protection to the steel surface at the top of the pipe. A novel idea is to inject the corrosion inhibitor within a foam matrix. The foam slug i…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

EFFECTS OF PARTIAL REPLACEMENT OF RATTAN POWDER BY COMMERCIAL FILLERS ON THE PROPERTIES OF NATURAL RUBBER COMPOSITES

Komethi Muniandy、H. Ismail、Nadras Othman2012-08-10BioResources

The effects of partial replacement of rattan powder (RP) by carbon black (CB), mica, and calcium carbonate (CaCO 3 ) on the curing characteristics, tensile properties, rubber-filler interaction, and morphological studies of natural rubber (NR) composites were investigated. Rattan powder with an average particle size o…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesTribology and Wear Analysis

Exploring Mesoscopic Physics of Vacancy-Ordered Systems through Atomic Scale Observations of Topological Defects

Albina Y. Borisevich、Anna N. Morozovska、Young‐Min Kim 等 8 位作者2012-08-10Physical Review Letters

Vacancy-ordered transition metal oxides have multiple similarities to classical ferroic systems including ferroelectrics and ferroelastics. The expansion coefficients for corresponding Ginzburg-Landau-type free energies are readily accessible from bulk phase diagrams. Here, we demonstrate that the gradient and interfa…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides