Materials Literature
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The effect of localized electric fields on the photocurrent responses of phthalocyanine that was self-assembled on a gold nanoparticle film was investigated by comparing the conventional and the total internal reflection (TIR) experimental systems. In the case of photocurrent measurements, self-assembled monolayers (S…
The influence of the demagnetizing factor (N) on the magnetic entropy change (ΔSM) curves is studied for materials with a second order phase transition. For this purpose, a soft magnetic amorphous ribbon is measured for different orientations of the magnetic field with respect to the plane of the sample. For temperatu…
Nd–Fe–B nanoparticles have been obtained by using surfactant-assisted ball milling and subsequent size-selection technique. Structural analyses show that nanoparticles with two particle sizes around 10 and 100nm were obtained. The partially amorphous Nd–Fe–B nanoparticles give their room-temperature coercivities aroun…
Surface chemistry of wood is based on the exposed surface that is the combination of the intact and cut cellular wall material. It is inherently complex and changes with processing history. Modification of wood surfaces through noncovalent attachment of amine containing water soluble polyelectrolytes provides a path t…
Hierarchical structured ZnO nanorods have been fabricated via a wet-chemical approach for the development of multifunctional ZnO materials possessing excellent optical and gas sensing properties simultaneously, which was a great challenge because of their opposite requirements on morphology and structure. On the surfa…
Magnetically hard Sm2(Co0.8Fe0.2)17 and SmCo5 nanoparticles have been produced by using surfactant-assisted low- and high-energy ball milling techniques. Surfactants prevent the rewelding of the crashed particles during the milling process. Heptane was used as the milling medium and oleic acid as the surfactant. High-…
Self-assembled, one-dimensional nanostructures of N, N ′-bis(2-(trimethylammonium iodide)ethylene)perylene-3,4,9,10-tetracarboxyldiimide (PTCDI-I) with tunable morphologies were successfully prepared by a facile evaporation method. PTCDI-I nanotubes with diameters of approximately 100−300 nm were obtained by the evapo…
The goal of this work was to elaborate a model describing the effective longitudinal relaxation rate constant R(1) for (1)H(2)O in three cellular compartments experiencing possible equilibrium water exchange, and to apply this model to explain the effective R(1) dependence on the overall concentration of a cell-intern…
Abstract The aim of this work was to develop well dispersed nanocomposites, in a non water soluble polymer using a non aqueous, low polarity solvent as a dispersion medium. The nanoreinforcements were cellulose whiskers and layered silicates (LSs) and matrix was cellulose acetate butyrate (CAB). Before nanocomposite p…
We investigate the Brownian motion of hard-sphere colloids near a solid wall by Evanescent Wave Dynamic Light Scattering (EWDLS). We carried out measurements for various volume fractions of sterically stabilized poly(methyl methacrylate) (PMMA) particles over a range of scattering wave vectors, q. While in the dilute…
A new experimental method taking advantage of the sensitivity of dielectric spectroscopy (DS) and being able to probe the segmental dynamics of freely standing ultrathin polymer layers over a broad frequency range without altering or eliminating their two free surfaces, was studied. The polymer films were suspended ov…
The authors report new calculations of mean escape depths (MEDs), information depths (IDs), and effective attenuation lengths (EALs) for 16 photoelectron lines and 9 Auger-electron lines of five elemental solids (Si, Cu, Ag, W, and Au) and four inorganic compounds (ZrO2, ZrSiO4, HfO2, and HfSiO4). These calculations w…
Blue-green upconverted emission from 2-chloro-bis-phenylethynylanthracene (2CBPEA) sensitized by the red-absorbing platinum(II)tetraphenyltetrabenzoporphyrin (PtTPBP) has been investigated in N,N-dimethylformamide (DMF). The upconverted singlet fluorescence of 2CBPEA resulting from its sensitized triplet-triplet annih…
A series of biscobalt cofacial porphyrin-corrole dyads bearing mesityl substituents at the meso positions of the corrole ring were investigated as to their electrochemistry, spectroelectrochemistry, and CO binding properties in nonaqueous media and then applied to the surface of a graphite electrode and tested as elec…
New macromolecular self-assembling building blocks, polyhedral oligo- silsesquioxane (POSS)-helical polypeptide copolymers, have been synthesized through the ring-opening polymerization (ROP) of γ-benzyl- l -glutamate N -carboxyanhydride (γ-Bn-Glu NCA) using aminopropyl isobutyl-POSS as a macroinitiator. The incorpora…
Material failure by crack propagation essentially involves a concentration of large displacement-gradients near a crack's tip, even at scales where no irreversible deformation and energy dissipation occurs. This physical situation provides the motivation for a systematic gradient expansion of general nonlinear elastic…
Abstract The high brittleness of Poly(lactic acid) is a major drawback for flexible food packaging applications. The aim of this work is to evaluate the potential use of commercial adipates as PLA plasticizers to obtain transparent films with enhanced mechanical properties. Processing conditions were optimized. The ef…
Using the Arrott–Noakes equation of state it is shown that the Curie point (TC) and the temperature where the magnetic entropy change is maximum (Tpeak) coincide only in the mean field approximation, but the Heisenberg model implies that Tpeak>TC even for homogeneous materials. The distance between Tpeak and TC…
A nanostructured signal-responsive thin hydrogel membrane was coupled with enzyme-based systems to yield "smart" multisignal-responsive hybrid systems with built-in "logic". The enzyme systems transduce biochemical input signals into structural changes of the membrane, thus resulting in the amplification of the bioche…
We report the results from a computational study of the self-assembly of amphiphilic ditethered nanospheres using molecular simulation. As a function of the interaction strength and directionality of the tether-tether interactions, we predict the formation of four highly ordered phases not previously reported for nano…